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The thorium nucleus with mass number $A=229$ has attracted much interest because its extremely low lying first excited isomeric state at about $8$eV opens the possibility for the development of a nuclear clock. However, neither the exact…

Electronic bridge mechanisms driving the $^{229}$Th nuclear clock transition in the vacuum-ultraviolet-transparent crystals $^{229}$Th:LiCAF (LiCaAlF$_6$) and $^{229}$Th:LiSAF (LiSrAlF$_6$) are investigated theoretically. Due to…

Atomic Physics · Physics 2025-07-08 Tobias Kirschbaum , Martin Pimon , Andreas Grüneis , Thorsten Schumm , Adriana Pálffy

The coherent pulse propagation of a Bessel beam resonant to the 8.4 eV nuclear clock transition in $^{229}$Th-doped crystals is investigated theoretically. Due to the magnetic dipole character of the clock transition, Bessel beams which…

Atomic Physics · Physics 2026-04-10 Alexander Franz , Tobias Kirschbaum , Adriana Pálffy

Excitation of the isomeric nuclear state 229m Th in the process of thorium atom irradiation by two-color femtosecond pulse of Ti: Sa laser at the fundamental wavelength and second harmonic is analyzed. It is shown that the rate of isomeric…

Optics · Physics 2019-01-23 A. V. Andreev , A. B. Savelyev , S. Yu. Stremoukhov , O. A. Shoutova

The electronic defect states resulting from doping $^{229}$Th in CaF$_2$ offer a unique opportunity to excite the nuclear isomeric state $^{229m}$Th at approximately 8 eV via electronic bridge mechanisms. We consider bridge schemes…

A new approach to observe the radiative decay of the $^{229}$Th nuclear isomer, and to determine its energy and radiative lifetime, is presented. Situated at a uniquely low excitation energy, this nuclear state might be a key ingredient for…

We propose a novel class of atomic clocks based on highly charged ions. We consider highly-forbidden laser-accessible transitions within the $4f^{12}$ ground-state configurations of highly charged ions. Our evaluation of systematic effects…

Atomic Physics · Physics 2016-10-05 Andrei Derevianko , V. A. Dzuba , V. V. Flambaum

In this work, the $4D_{3/2}|3,\pm2\rangle \rightarrow 4D_{5/2}|3,\pm2\rangle$ transition in the Nb$^{4+}$ ion is identified as a promising candidate for a terahertz (THz) atomic clock, with the transition frequency occurring at 56.0224 THz.…

Atomic Physics · Physics 2025-04-23 Jyoti , A. Chakraborty , Zhiyang Wang , Jia Zhang , Jingbiao Chen , Bindiya Arora , B. K. Sahoo

The hyperfine structure of $^{229}$Th$^{3+}$ ions in the nuclear ground state is investigated via laser spectroscopy of trapped Th$^{3+}$ ions that are sympathetically cooled by laser-cooled $^{88}$Sr$^+$ ions in a linear Paul trap. The…

Atomic Physics · Physics 2025-04-02 G. Zitzer , J. Tiedau , Ch. E. Düllmann , M. V. Okhapkin , E. Peik

Optical atomic clocks using highly-charged ions hold an intriguing promise of metrology at the 19th significant figure. Here we study transitions within the $4f^{12}$ ground-state electronic configuration of highly charged ions. We consider…

Atomic Physics · Physics 2015-06-11 V. A. Dzuba , A. Derevianko , V. V. Flambaum

A method is proposed to determine the $M1$ nuclear transition amplitude and hence the lifetime of the "nuclear clock transition" between the low-lying ($\sim 8$ eV) first isomeric state and the ground state of $^{229}$Th from a measurement…

We investigate the feasibility of precision frequency metrology with large ion crystals. For clock candidates with a negative differential static polarisability, we show that micromotion effects should not impede the performance of the…

Quantum Physics · Physics 2016-10-25 Kyle Arnold , Elnur Haciyev , Eduardo Paez , Chern Hui Lee , John Bollinger , M. D. Barrett

We present a novel method for engineering an optical clock transition that is robust against external field fluctuations and is able to overcome limits resulting from field inhomogeneities. The technique is based on the application of…

Atomic Physics · Physics 2019-12-03 Nati Aharon , Nicolas Spethmann , Ian D. Leroux , Piet O. Schmidt , Alex Retzker

$^{229}$Th is a promising candidate for developing a nuclear optical clock and searching the new physics beyond the standard model. Accurate knowledge of the nuclear properties of $^{229}$Th is very important. In this work, we calculate…

Atomic Physics · Physics 2022-01-05 Fei-Chen Li , Hao-Xue Qiao , Yong-Bo Tang , Ting-Yun Shi

A comprehensive theoretical study of direct laser excitation of a nuclear state based on the density matrix formalism is presented. The nuclear clock isomer $^{229\text{m}}$Th is discussed in detail, as it could allow for direct laser…

The most probable candidate for the role of a nuclear optical standard is the 8.338-eV isomer of the 229mTh isotope of the thorium nucleus. Ways of using the resonance properties of the electron shell as an optical resonator to create…

Nuclear Theory · Physics 2023-07-19 F. F. Karpeshin , L. F. Vitushkin

We propose to generate continuous-wave vacuum ultraviolet (VUV) laser light at 148.4 nm using four-wave mixing in cadmium vapor for precision spectroscopy of the Th-229 isomer transition. Due to the large transition matrix elements of…

We review a number of highly charged ions which have optical transitions suitable for building extremely accurate atomic clocks. This includes ions from Hf$^{12+}$ to U$^{34+}$, which have the $4f^{12}$ configuration of valence electrons,…

Atomic Physics · Physics 2015-06-23 V. A. Dzuba , V. V. Flambaum

In-source resonance ionization spectroscopy was used to identify an efficient and selective three step excitation/ionization scheme of thorium, suitable for titanium:sapphire (Ti:sa) lasers. The measurements were carried out in preparation…

Optical atomic clocks are the most accurate measurement devices ever constructed and have found many applications in fundamental science and technology. The use of highly charged ions (HCI) as a new class of references for highest accuracy…

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