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In this work we report on the role of ion transport for the dynamic behavior of a double barrier quantum mechanical Al/Al$_2$O$_3$/Nb$_{\text{x}}$O$_{\text{y}}$/Au memristive device based on numerical simulations in conjunction with…

Materials Science · Physics 2016-05-31 Sven Dirkmann , Mirko Hansen , Martin Ziegler , Hermann Kohlstedt , Thomas Mussenbrock

Ion flow in charged nanopores is strongly influenced by the ratio of the Debye length to the pore radius. We investigate the asymptotic behaviour of solutions to the Poisson-Nernst-Planck (PNP) system in narrow pore like geometries and…

Analysis of PDEs · Mathematics 2019-04-10 B. Matejczyk , J. -F. Pietschmann , G. Richardson , M. -T. Wolfram

The Bragg-Williams free energy is used to incorporate nearest-neighbor interactions into the lattice gas model of a solvent-free ionic liquid near a planar electrode. We calculate the differential capacitance from solutions of the…

Chemical Physics · Physics 2018-12-04 Rachel Downing , Bjorn K. Berntson , Guilherme V. Bossa , Sylvio May

The description of a conducting medium in thermal equilibrium, such as an electrolyte solution or a plasma, involves nonlinear electrostatics, a subject rarely discussed in the standard electricity and magnetism textbooks. We consider in…

Chemical Physics · Physics 2018-08-01 C. G. Gray , P. J. Stiles

A nonlinear phase-field model is developed to simulate corrosion damage. The motion of the electrode$-$ electrolyte interface follows the usual kinetic rate theory for chemical reactions based on the Butler-Volmer equation. The model links…

Chemical Physics · Physics 2024-08-28 M. Makuch , S. Kovacevic , M. R. Wenman , E. Martínez-Pañeda

Recent advances in nanofluidics have enabled the confinement of water down to a single molecular layer. Such monolayer electrolytes show promise in achieving bio-inspired functionalities through molecular control of ion transport. However,…

Soft Condensed Matter · Physics 2021-09-08 Paul Robin , Nikita Kavokine , Lydéric Bocquet

The work develops the structure-dynamic approach in nanoionics for detailed description of non-stationary ion-transport processes in irregular potential relief (direct problem) and interpretation of ionic properties and characteristics of…

Materials Science · Physics 2013-11-15 Alexandr Despotuli , Alexandra Andreeva

An approximate analytical solution to the fluctuation potential problem in the modified Poisson-Boltzmann theory of electrolyte solutions in the restricted primitive model is presented. The solution is valid for all inter-ionic distances,…

Statistical Mechanics · Physics 2017-12-15 E. O. Ulloa-Dávila , L. B. Bhuiyan

The Poisson Nernst-Planck equations for charge concentration and electric potential in a ball is a model of electro-diffusion of ions in the head of a neuronal dendritic spine. We study the relaxation and the steady state when an initial…

Classical Physics · Physics 2015-05-12 Z. Schuss J. Cartailler , D. Holcman

The stability of molecular junctions under transport is of the utmost importance for the field of molecular electronics. This question is often addressed within the paradigm of current-induced heating of nuclear degrees of freedom or…

Mesoscale and Nanoscale Physics · Physics 2022-12-26 André Erpenbeck , Yaling Ke , Uri Peskin , Michael Thoss

The electron and current density distributions in the close proximity of quantum point contacts (QPCs) are investigated. A three dimensional Poisson equation is solved self-consistently to obtain the electron density and potential profile…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 S. Arslan , E. Cicek , D. Eksi , S. Aktas , A. Weichselbaum , A. Siddiki

We demonstrate the role of selectivity variation in the structure of the non-equilibrium extended space-charge using 1D analytic and 2D numerical Poisson-Nernst-Planck models for the electro- diffusive transport of a symmetric electrolyte.…

Soft Condensed Matter · Physics 2015-03-25 Jarrod Schiffbauer , Neta Leibowitz , Gilad Yossifon

In this paper, we study effects of permanent charges on ion flows through membrane channels via a quasi-one-dimensional classical Poisson-Nernst-Planck system. This system includes three ion species, two cations with different valences and…

Soft Condensed Matter · Physics 2023-12-07 Ning Sun , Weishi Liu

High-quality N-polar GaN p-n diodes are realized on single-crystal N-polar GaN bulk substrate by plasma-assisted molecular beam epitaxy. The room-temperature current-voltage characteristics reveal a high on/off current ratio of 10^11 at 4 V…

Materials Science · Physics 2022-05-24 Kazuki Nomoto , Huili Grace Xing , Debdeep Jena , YongJin Cho

We build a new mathematical model of shape optimization for maximizing ionic concentration governed by the multi-physical coupling steady-state Poisson-Nernst-Planck system. Shape sensitivity analysis is performed to obtain the Eulerian…

Optimization and Control · Mathematics 2025-05-13 Jiajie Li , Shenggao Zhou , Shengfeng Zhu

It is expected that the introduction of a viscosity gradient across a nanofluidic system will drastically vary its current-voltage response, $i-V$. However, to date, there is no self-consistent theoretical model that can be used to fully…

Mesoscale and Nanoscale Physics · Physics 2025-06-17 Ramadan Abu-Rjal , Zuzanna S. Siwy , Yoav Green

This paper presents the current state of mathematical modelling of the electrochemical behaviour of lithium-ion batteries as they are charged and discharged. It reviews the models developed by Newman and co-workers, both in the cases of…

Chemical Physics · Physics 2020-02-04 Giles W Richardson , Jamie M Foster , Rahifa Ranom , Colin P Please , Angel M Ramos

A consistent device model to describe current-voltage characteristics of metal/insulator/metal systems is developed. In this model the insulator and the metal electrodes are described within the same theoretical framework by using density…

Materials Science · Physics 2015-05-13 F. Neumann , Y. A. Genenko , C. Melzer , H. von Seggern

Ion migration in perovskite solar cells is usually analyzed and understood in terms of charge neutrality condition. However, several recent reports indicate possibility of ionic imbalance in the active layer due to external ion migration…

Materials Science · Physics 2023-01-27 Dhyana Sivadas , Abhimanyu Singareddy , Chittiboina vinod , Pradeep Nair

The strongly interacting system created in ultrarelativistic nuclear collisions behaves almost as an ideal fluid with rich patterns of the velocity field exhibiting strong vortical structure. Vorticity of the fluid, via spin-orbit coupling,…

Nuclear Experiment · Physics 2024-10-30 Takafumi Niida , Sergei A. Voloshin