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The article explores the ion flux response of a capacitor configuration to an alternating voltage. The model system comprises a symmetric binary electrolyte confined between plan-parallel capacitor plates. The AC response is investigated…

Chemical Physics · Physics 2018-10-03 Sonja Babel , Michael Eikerling , Hartmut Löwen

The case of a non-biased (light excited) p-n photo-voltaic (PV) cell working in a closed circuit with a resistive load is investigated by means of irreversible thermodynamics in the linear range. To our knowledge, this is the first time…

Other Condensed Matter · Physics 2007-05-23 M. Salis , P. C. Ricci , F. Raga , F. Quarati

A novel thermodynamically consistent diffuse interface model is derived for compressible electrolytes with phase transitions. The fluid mixtures may consist of N constituents with the phases liquid and vapor, where both phases may coexist.…

Analysis of PDEs · Mathematics 2014-11-13 Wolfgang Dreyer , Jan Giesselmann , Christiane Kraus

A model describing spin-polarized current via discrete energy levels of a metallic nanoparticle, which has strongly asymmetric tunnel contacts to two ferromagnetic leads, is presented. In absence of spin-relaxation, the model leads to a…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Y. G. Wei , C. E. Malec , D. Davidović

We develop a model for a driven cell- or artificial membrane in an electrolyte. The system is kept far from equilibrium by the application of a DC electric field or by concentration gradients, which causes ions to flow through specific…

Soft Condensed Matter · Physics 2015-06-25 D. Lacoste , M. Cosentino Lagomarsino , JF. Joanny

Polymer electrolytes (PEs) are promising candidates for use in next-generation high-voltage batteries, as they possess advantageous elastic and electrochemical properties. However, PEs still suffer from low ionic conductivity and need to be…

The current voltage (IV) characteristics for perpendicular transport through two sequentially coupled wires of finite length is calculated analytically. The transport within a Coulomb blockade step is assisted by plasmon resonances that…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 A. L. Chudnovskiy

Current-voltage characteristics of a spintromechanical device, in which spin-polarized electrons tunnel between magnetic leads with anti-parallel magnetization through a single level movable quantum dot, are calculated. New exchange- and…

Mesoscale and Nanoscale Physics · Physics 2020-05-20 Olya A. Ilinskaya , Danko Radic , Hee Chul Park , Ilya V. Krive , Robert I. Shekhter , Mats Jonson

This paper is devoted to the homogenization (or upscaling) of a system of partial differential equations describing the non-ideal transport of a N-component electrolyte in a dilute Newtonian solvent through a rigid porous medium. Realistic…

Analysis of PDEs · Mathematics 2014-10-14 Gregoire Allaire , Robert Brizzi , Jean-Francois Dufreche , Andro Mikelic , Andrey Piatnitski

Ionic currents accompanying DNA translocation strongly depend on molarity of the electrolyte solution and the shape and surface charge of the nanopore. By means of the Poisson-Nernst-Planck equations it is shown how conductance is modulated…

Soft Condensed Matter · Physics 2015-07-16 Valerio Mazzone , Simone Melchionna , Umberto Marini Bettolo Marconi

In this paper, we propose and analyze a second order accurate (in both time and space) numerical scheme for the Poisson-Nernst-Planck-Navier-Stokes system, which describes the ion electro-diffusion in fluids. In particular, the…

Numerical Analysis · Mathematics 2025-03-12 Yuzhe Qin , Cheng Wang

Ion transport, often described by the Poisson--Nernst--Planck (PNP) equations, is ubiquitous in electrochemical devices and many biological processes of significance. In this work, we develop conservative, positivity-preserving, energy…

Numerical Analysis · Mathematics 2020-07-15 Jie Ding , Zhongming Wang , Shenggao Zhou

We describe here a model for inelastic collisions for electronic excitation and deexcitation processes in a general, multifluid plasma. The model is derived from kinetic theory, and applicable to any mixture and mass ratio. The principle of…

Plasma Physics · Physics 2015-10-08 H. P. Le , J. -L. Cambier

Conventional lithium-ion batteries, and many next-generation technologies, rely on organic electrolytes with multiple solvents to achieve the desired physicochemical and interfacial properties. The complex interplay between these properties…

Soft Condensed Matter · Physics 2023-03-06 Zachary A. H. Goodwin , Michael McEldrew , Boris Kozinsky , Martin Z. Bazant

In this paper we propose a computational framework for the investigation of the correlated motion between positive and negative ions exposed to the attraction of a bubble surface that mimics the (oscillating) cell membrane. The correlated…

Computational Physics · Physics 2022-03-14 Antonio Raudino , Antonio Grassi , Giuseppe Lombardo , Giovanni Russo , Clarissa Astuto , Mario Corti

Ionic liquids are widely used as electrolytes in electrochemical devices. In this context, many experimental and theoretical approaches have been recently developed for characterizing their interface with electrodes. In this perspective…

Materials Science · Physics 2017-09-13 Céline Merlet , Benjamin Rotenberg , Paul Madden , Mathieu Salanne

Motivated by contact resistance on the front side of a crystalline silicon solar cell, we formulate and analyse a two-dimensional mathematical model for electron flow across a poorly conducting (glass) layer situated between silver…

Analysis of PDEs · Mathematics 2014-12-08 J. P. Black , C. J. W. Breward , P. D. Howell

The methods of Nicholson and Shain and Randles-Sevcik are the paradigms of voltammetry of redox species. However, as they were originally developed for aqueous redox couples, they cannot be directly applied to solid redox films such as…

Chemical Physics · Physics 2025-03-20 Keyvan Malaie

Highly transmissive ballistic junctions are demonstrated between Nb and the two-dimensional electron gas formed at an InAs/AlSb heterojunction. A reproducible fabrication protocol is presented yielding high critical supercurrent values.…

We consider an ionic fluid made with two species of mobile particles carrying either a positive or a negative charge. We derive a sum rule for the fourth moment of equilibrium charge correlations. Our method relies on the study of the…

Statistical Mechanics · Physics 2016-11-30 Angel Alastuey , Riccardo Fantoni
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