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We prove the Jarzynski relation for general stochastic processes including non-Markovian systems with memory. The only requirement for our proof is the existence of a stationary state, therefore excluding non-ergodic systems. We then show…

Statistical Mechanics · Physics 2007-09-27 Thomas Speck , Udo Seifert

In classical Markov jump processes, current fluctuations can only be reduced at the cost of increased dissipation. To explore how quantum effects influence this trade-off, we analyze the uncertainty of steady-state currents in Markovian…

Statistical Mechanics · Physics 2021-07-09 Paul Menczel , Eetu Loisa , Kay Brandner , Christian Flindt

We study work fluctuation theorems for oscillators in non-Markovian heat baths. By calculating the work distribution function for a harmonic oscillator with motion described by the generalized Langevin equation, the Jarzynski equality (JE),…

Statistical Mechanics · Physics 2009-11-11 Trieu Mai , Abhishek Dhar

The thermodynamic and kinetic uncertainty relations indicate trade-offs between the relative fluctuation of observables and thermodynamic quantities such as dissipation and dynamical activity. Although these relations have been well studied…

Statistical Mechanics · Physics 2022-04-12 Tan Van Vu , Keiji Saito

Jarzynski's equality [1] allows us to investigate free energy landscapes (FELs) by constructing distributions of work performed on a system from an initial ensemble of states to final states. This work is experimentally measured by…

Biological Physics · Physics 2011-05-24 Van Ngo

The work fluctuations of a harmonic oscillator in contact with a thermostat and driven out of equilibrium by an external force are studied experimentally. For the work both the transient and stationary state fluctuation theorems hold. The…

Statistical Mechanics · Physics 2016-08-14 Sylvain Joubaud , Nicolas Garnier , Frédéric Douarche , Artem Petrosyan , Sergio Ciliberto

Recently there has been growing interest in extending the thermodynamic method from static configurations to dynamical trajectories. In this approach, ensembles of trajectories are treated in an analogous manner to ensembles of…

Statistical Mechanics · Physics 2016-08-23 Robert M. Turner , Thomas Speck , Juan P. Garrahan

Jarzynski equality [Phys. Rev. E {\bf 56}, 5018 (1997)] is found to be valid with slight modefication for the transitions between nonequilibrium stationary states, as well as the one between equilibrium states. Also numerical results…

Statistical Mechanics · Physics 2007-05-23 Takahiro Hatano

Recent advances in experimental techniques allow one to measure and control systems at the level of single molecules and atoms. Here gaining information about fluctuating thermodynamic quantities is crucial for understanding nonequilibrium…

Statistical Mechanics · Physics 2019-05-01 Ken Funo , Masahito Ueda , Takahiro Sagawa

In this paper, we derive the Jarzynski equality (JE) for an isolated quantum system in three different cases: (i) the full evolution is unitary with no intermediate measurements, (ii) with intermediate measurements of arbitrary observables…

Statistical Mechanics · Physics 2015-06-03 Shubhashis Rana , Sourabh Lahiri , A. M. Jayannavar

The Fluctuation Theorem describes the probability ratio of observing trajectories that satisfy or violate the second law of thermodynamics. It has been proved in a number of different ways for thermostatted deterministic nonequilibrium…

Statistical Mechanics · Physics 2009-10-31 Debra J. Searles , Denis J. Evans

Quantum work is usually determined from two projective measurements of the energy at the beginning and at the end of a thermodynamic process. However, this paradigm cannot be considered thermodynamically consistent as it does not account…

Quantum Physics · Physics 2016-07-13 Sebastian Deffner , Juan Pablo Paz , Wojciech H. Zurek

There is evidence that taking the time average of the work performed by a thermally isolated system effectively "transforms" the adiabatic process into an isothermal one. This approach allows inherent quantities of adiabatic processes to be…

Statistical Mechanics · Physics 2025-10-03 Pierre Nazé

It is shown that the work fluctuations and work distribution functions are fundamentally different in systems with short-range versus long-range correlations. The two cases considered with long- range correlations are magnetic work…

Statistical Mechanics · Physics 2017-07-26 T. R. Kirkpatrick , J. K. Bhattacherjee , J. V. Sengers

To define the work performed on a driven quantum system in a physically sound way has turned out to be a truly non-trivial task, except in some special cases of limited applicability. This topic has been in a focus of intense research…

Statistical Mechanics · Physics 2012-12-27 Jukka P. Pekola , Paolo Solinas , Alexander Shnirman , Dmitri V. Averin

Estimating free-energy differences using nonequilibrium work relations, such as the Jarzynski equality, is hindered by poor convergence when work fluctuations are large. For systems governed by overdamped Langevin dynamics, we propose the…

Statistical Mechanics · Physics 2025-08-14 Stephen Whitelam

The work is a concept of fundamental importance in thermodynamics. An open question is how to describe the work fluctuation for quantum coherent processes in the presence of initial quantum coherence in the energy basis. With the aim of…

Quantum Physics · Physics 2022-01-05 Gianluca Francica

We investigate thermodynamics of general nonequilibrium processes stopped at stochastic times. We propose a systematic strategy for constructing fluctuation-theorem-like martingales for each thermodynamic functional, yielding a family of…

Statistical Mechanics · Physics 2023-06-02 Haoran Yang , Hao Ge

We derive the differential equation describing the time evolution of the work probability distribution function of a stochastic system which is driven out of equilibrium by the manipulation of a parameter. We consider both systems described…

Statistical Mechanics · Physics 2007-05-23 A. Imparato , L. Peliti

We present the stochastic thermodynamics analysis of an open quantum system weakly coupled to multiple reservoirs and driven by a rapidly oscillating external field. The analysis is built on a modified stochastic master equation in the…

Statistical Mechanics · Physics 2015-05-12 Gregory Bulnes Cuetara , Andreas Engel , Massimiliano Esposito