Related papers: Laser-induced fragmentation of coronene cations
Pure carbon clusters have received considerable attention for a long time. However, fundamental questions such as what the smallest stable carbon cluster dication is remain unclear. Here, we investigated the stability and fragmentation…
Tracing dust in small dense molecular cores is a powerful tool to study the conditions required for ices to form during the pre-stellar phase. To study these environments, five molecular cores were observed: three with ongoing low-mass star…
Understanding how the $\mathrm{H}_2$ molecule is formed under the chemical conditions of the interstellar media (ISM) is critical to the whole chemistry of it. Formation of $\mathrm{H}_2$ in the ISM requires a third body acting as a…
Young massive stars produce Far-UV photons which dissociate the molecular gas on the surfaces of their parent molecular clouds. Of the many dissociation products which result from this ``back-reaction'', atomic hydrogen \HI is one of the…
The formation and evolution mechanism of fullerenes in the planetary nebula or in the interstellar medium are still not understood. Here we present the study on the cluster formation and the relative reactivity of fullerene cations (from…
In the interstellar medium carbon exists in the form of two stable isotopes $^{12}$C and $^{13}$C and their ratio is a good indicator of nucleosynthesis in galaxies. However, chemical fractionation can potentially significantly alter this…
We study the isomer-specific photoionization and photofragmentation of 1,2- dibromoethene (DBE) under strong-field fs-laser irradiation in the gas phase complementing previous studies utilising ns- and ps-laser excitation. Our findings are…
The detection of fullerene molecules in a variety of astrophysical environments suggests that smaller dehydrogenated carbon molecules may also be present in these sources. One of these is planar C24 which has been shown to be more stable…
Experimental and theoretical investigation of the fragmentation reaction in Fermi-energy domain is currently of particular importance for not only the nuclear physics but also some interdisciplinary fields. In the present work, neutron-rich…
The fragmentation times corresponding to the loss of the chromophore (C$\alpha$-- C$\beta$ bond dissociation channel) after photoexcitation at 263 nm have been investigated for several small peptides containing tryptophan or tyrosine. For…
In 2015, Campbell et al. (Nature 523, 322) presented spectroscopic laboratory gas phase data for the fullerene cation, C$_{60}^+$, that coincide with reported astronomical spectra of two diffuse interstellar band (DIB) features at 9633 and…
Coronene molecules have been bombarded with protons of energy ranging from 100 to 300 keV. The time of flight mass spectra have been recorded using a two stage Wiley McLaren type spectrometer. A significant enhancement in the yields of…
The photodissociation of the HD+ molecular ion in intense short- pulsed linearly polarized laser fields is studied using a time- dependent wave-packet approach where molecular rotation is fully included. We show that applying a coherent…
Ultraviolet (UV) processing in the insterstellar medium (ISM) induces the dehydrogenation of hydrocarbons. Aliphatics, including alkanes, are present in different interstellar environments, being prevalently formed in evolved stars; thus,…
Isotopologue abundance ratios are important to understand the evolution of astrophysical objects and ultimately the origins of a planetary system like our own. Being nitrogen a fundamental ingredient of pre-biotic material, understanding…
Photodissociation of 14N2 and 14N15N occurs in interstellar clouds, circumstellar envelopes, protoplanetary discs, and other environments due to UV radiation from stellar sources and the presence of cosmic rays. This source of N atoms…
We present an observational and theoretical study of the ionization fraction in several massive cores located in regions that are currently forming stellar clusters. Maps of the emission from the J = 1-> O transitions of C18O, DCO+, N2H+,…
We aim to reveal the chemistry of carbon-chain molecules in high-mass star-forming regions from molecular level to chemical evolution, applying the methods established in low-mass star-forming regions. In this proceeding, we summarize the…
By means of quantum-dynamical and classical trajectory calculations of H2+ photodissociation in strong laser fields, it is shown that for certain combinations of pulse durations and intensities the rotational dynamics can lead to…
Astrochemical evolution step of polycyclic aromatic hydrocarbon (PAH) around a Herbig Ae young star was analyzed using the first principles quantum chemical calculation. For simplicity, model molecule was selected to be acenaphthylene…