Related papers: Laser-induced fragmentation of coronene cations
Together with the second generation REBO reactive potential, replica-exchange molecular dynamics simulations coupled with systematic quenching were used to generate a broad set of isomers for neutral C$_n$ clusters with $n=24$, 42, and 60.…
Carbon monoxide (CO) is the most abundant molecule after molecular hydrogen and is important for the chemistry in circumstellar envelopes around evolved stars. When modelling the strength and shape of molecular lines, the size of the CO…
Straight-chain (normal-propyl cyanide, n - C3H7CN) and branched-chain (iso-propyl cyanide, i - C3H7CN) alkyl cyanides are recently identified in the massive star-forming regions (Sgr B2(N) and Orion). These branched-chain molecules indicate…
The multiphoton ionization of the simplest aromatic amine, aniline, was examined utilizing a kinetic energy-correlated time-of-flight mass spectrometer at a wavelength of 266 nm. The primary and secondary fragment channels have been…
Coronene, a polyaromatic hydrocarbon, has been crystallized for the first time in a different polymorph using a crystal growth method that utilizes magnetic fields to access a unit cell configuration that was hitherto unknown. Crystals…
The infrared signature of polycyclic aromatic hydrocarbons (PAHs) are present in many protostellar disks and these speciesare thought to play an important role in heating of the gas in the photosphere. We aim to consider PAH cluster…
Branching ratios for fragmentation channels of important meta- and unstable species are essential for a molecular-level characterization of atmospheric chemistry. Here, the molecular product channels for the decomposition dynamics of the…
Molecular emission is a powerful tool for studying the physical and chemical structures of dense cores. The distribution and abundance of different molecules provide information on the chemical composition and physical properties in these…
The presence of small amounts of atomic hydrogen, detected as absorption dips in the 21 cm line spectrum, is a well-known characteristic of dark clouds. The abundance of hydrogen atoms measured in the densest regions of molecular clouds can…
It is very important to identify carrier molecules of astronomical interstellar infrared spectrum (IR) to understand chemical evolution step of polycyclic aromatic hydrocarbon (PAH) in the universe. In our previous study, it was suggested…
We present ten new Spitzer detections of fullerenes in Magellanic Cloud Planetary Nebulae, including the first extragalactic detections of the C70 molecule. These new fullerene detections together with the most recent laboratory data permit…
The cumulene carbenes are important components of hydrocarbon chemistry in low mass star forming cores. Here we report the first astronomical detection of the long chain cumulene carbene H_2C_6 in the interstellar cloud TMC1, from…
The physical and chemical properties of cold and dense molecular clouds are key to understanding how stars form. Using the IRAM 30 m and NRO 45 m telescopes, we carried out a Multiwavelength line-Imaging survey of the 70 $\mu$m dark and…
This work presents a photodissociation study of the diamondoid adamantane using extreme ultraviolet femtosecond pulses. The fragmentation dynamics of the dication is unraveled by the use of advanced ion and electron spectroscopy giving…
We present a model for the hydrogenation states of Polycyclic Aromatic Hydrocarbons (PAHs) in the diffuse interstellar medium. First, we study the abundance of hydrogenation and charge states of PAHs due to photo-ionization,…
Sufficiently massive clumps of molecular gas collapse under self-gravity and fragment to spawn a cluster of stars that have a range of masses. We investigate observationally the early stages of formation of a stellar cluster in a massive…
Photodissociation by ultraviolet radiation is the key destruction pathway for CS in photon-dominated regions, such as diffuse clouds. However, the large uncertainties of photodissociation cross sections and rates of CS, resulting from a…
Ultraviolet absorption from interstellar 12CO and 13CO was detected toward rho Oph A and chi Oph. The measurements were obtained at medium resolution with the Goddard High Resolution Spectrograph on the Hubble Space Telescope. Column…
Context. Low-mass star-forming cores differ from their surrounding molecular cloud in turbulence, shape, and density structure. Aims. We aim to understand how dense cores form out of the less dense cloud material by studying the connection…
The formation of Polycyclic Aromatic Hydrocarbons in the circumstellar outflows of evolved stars is reviewed, with an emphasis on carbon stars on the Asymptotic Giant Branch. Evidence for PAHs present in their winds is provided by…