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A theoretical study of the intense-field single ionization of molecular hydrogen or deuterium oriented either parallel or perpendicular to a linear polarized laser pulse (400 nm) is performed for different internuclear separations and pulse…

Quantum Physics · Physics 2015-05-14 Yulian V. Vanne , Alejandro Saenz

We develop a time-dependent theory to investigate electron dynamics and photoionization processes of diatomic molecules interacting with strong laser fields including electron-electron correlation effects. We combine the recently formulated…

Chemical Physics · Physics 2016-02-02 Henrik R. Larsson , Sebastian Bauch , Lasse Kragh Sørensen , Michael Bonitz

Study on ionization process of molecules in an intense infrared laser field is of paramount interest in strong-field physics and constitutes the foundation of imaging of molecular valence orbitals and attosecond science. We show measurement…

A time-dependent equation of motion coupled cluster singles and doubles (TD-EOM-CCSD) method is implemented, which uses a reduced basis calculated with the asymmetric band Lanczos algorithm. The approach is used to study weak-field…

In conditions where the interaction betweeen an atom and a short high-frequency extreme ultraviolet laser pulse is a perturbation, we show that a simple theoretical approach, based on Coulomb-Volkov-type states, can make reliable…

Atomic Physics · Physics 2009-11-07 Guillaume Duchateau , Eric Cormier , Robert Gayet

By simulating the real-time multielectron wavefunction with the multi-configurational time-dependent Hartree-Fock (MCTDHF) approach, we conduct an \textit{ab initio} study of the single-photon ionization process of a body-fixed water…

Atomic Physics · Physics 2026-01-14 Zhao-Han Zhang , Yang Li , Himadri Pathak , Takeshi Sato , Kenichi L. Ishikawa , Feng He

The electron dynamics of rare gas clusters in laser fields is investigated quantum mechanically by means of time-dependent density functional theory. The mechanism of early inner and outer ionization is revealed. The formation of an…

Atomic Physics · Physics 2009-11-10 D. Bauer , A. Macchi

While providing a highly accurate framework for simulating laser-induced many-electron dynamics in atom and molecules, including linear and nonlinear steady-state and transient absorption spectra, time-dependent coupled-cluster theory does…

Localized molecular orbitals are often used for the analysis of chemical bonds, but they can also serve to efficiently and comprehensibly compute linear response properties. While conventional canonical molecular orbitals provide an…

Chemical Physics · Physics 2023-02-08 Souloke Sen , Bruno Senjean , Lucas Visscher

We consider correlation-assisted tunnel ionization of a small molecule by an intense low-frequency laser pulse. In this mechanism, the departing electron excites the state of the ion via a Coulomb interaction. We show that the angular…

Atomic Physics · Physics 2014-04-25 Emilio Pisanty , Misha Ivanov

Laser ablation is often explained by a two-temperature model (TTM) with different electron and lattice temperatures. To realize a classical molecular dynamics simulation of the TTM, we propose an extension of the embedded atom method to…

Materials Science · Physics 2022-03-09 Yuta Tanaka , Shinji Tsuneyuki

The molecular polarizability describes the tendency of a molecule to deform or polarize in response to an applied electric field. As such, this quantity governs key intra- and inter-molecular interactions such as induction and dispersion,…

Chemical Physics · Physics 2025-10-06 David M. Wilkins , Andrea Grisafi , Yang Yang , Ka Un Lao , Robert A. DiStasio , Michele Ceriotti

We describe an ab initio and non-perturbative $R$-matrix with time-dependence theory for ultrafast atomic processes in light fields of arbitrary polarization. The theory is applicable to complex, multielectron atoms and atomic ions subject…

Atomic Physics · Physics 2018-12-04 D. D. A. Clarke , G. S. J. Armstrong , A. C. Brown , H. W. van der Hart

In this paper we apply the time-dependent quantum Monte Carlo (TDQMC) method to explore a midified single- and double-slit diffraction of matter waves. By using a simplified model of two electrons prepared in the ground state of an atom…

Quantum Physics · Physics 2025-02-07 Ivan P. Christov

We present a new formulation of the time-dependent self-interaction correction (TDSIC). It is derived variationally obeying explicitly the constraints on orthonormality of the occupied single-particle orbitals. The thus emerging rather…

Quantum Physics · Physics 2009-03-02 J. Messud , P. M. Dinh , P. -G. Reinhard , E. Suraud

We present total cross sections for single and double ionization of helium by antiproton impact over a wide range of impact energies from 10 keV/amu to 1 MeV/amu. A non-perturbative time-dependent close-coupling method (TDCC) is applied to…

Atomic Physics · Physics 2008-11-26 M. Foster , J. Colgan , M. S. Pindzola

We present the extension of the time-dependent configuration interaction singles (TDCIS) method to the computation of the electron kinetic-energy spectrum in photoionization processes. Especially for strong and long ionizing light pulses…

Atomic Physics · Physics 2014-04-17 Antonia Karamatskou , Stefan Pabst , Yi-Jen Chen , Robin Santra

The article deals with the extension of the relativistic double-ionization equation-of-motion coupled-cluster (DI-EOMCC) method [H. Pathak et al. Phys. Rev. A 90, 010501(R) (2014)] for the molecular systems. The Dirac-Coulomb (DC)…

Chemical Physics · Physics 2020-04-22 Himadri Pathak , Sudip Sasmal , Kaushik Talukdar , Malaya K. Nayak , Nayana Vaval , Sourav Pal

Self-trapping and acceleration of ions in laser-driven relativistically transparent plasma are investigated with the help of particle-in-cell simulations. A theoretical model based on ion wave breaking is established in describing ion…

Plasma Physics · Physics 2019-04-02 B. Liu , J. Meyer-ter-Vehn , H. Ruhl

We report our successful implementation of the full fledged relativistic equation of motion coupled cluster (EOMCC) method. This method is employed to compute the principal ionization potentials (IPs) of closed-shell rare gas atoms, He-like…

Atomic Physics · Physics 2014-04-24 Himadri Pathak , B. K. Sahoo , B. P. Das , Nayana Vaval , Sourav Pal
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