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As an essential attribute of organic compounds, polarity has a profound influence on many molecular properties such as solubility and phase transition temperature. Thin layer chromatography (TLC) represents a commonly used technique for…

We present a new method to couple the Direct Simulation Monte Carlo (DSMC) algorithm with molecular dynamics (MD). The coupling approach generalizes prior coupling methods using a cell-based decision. The approach is supported by a lifting…

Computational Physics · Physics 2025-06-03 Tim Linke , Dane Sterbentz , Niels Grønbech-Jensen , Jean-Pierre Delplanque , Jonathan Belof

Ab initio methods based on the second-order and higher connected moments, or cumulants, of a reference function have seen limited use in the determination of correlation energies of chemical systems throughout the years. Moment-based…

Chemical Physics · Physics 2023-08-25 Brad Ganoe , Martin Head-Gordon

We present an ab initio approach to solve the time-dependent Schr\"odinger equation to treat electron and photon impact multiple ionization of atoms or molecules. It combines the already known time scaled coordinate method with a new high…

The dynamics of a core-shell structured ionized particle between two parallel conductor plates, which is biased with a direct current (DC) voltage, have been investigated. It has been found that an ionized particle oscillates rapidly…

Classical Physics · Physics 2012-05-14 Sung Nae Cho

We investigate molecular dynamics of multiple ionization in N2 through multiple core-level photoabsorption and subsequent Auger decay processes induced by intense, short X-ray free electron laser pulses. The timing dynamics of the…

We theoretically investigate time-dependent resonant tunneling via two discrete states in an experimentally relevant setup. Our results show that the dc transport through the system can be controled by applying irradiation with a frequency…

Condensed Matter · Physics 2009-10-28 T. H. Stoof , Yu. V. Nazarov

The ion channel laser (ICL) is a plasma-based alternative to the free electron laser (FEL) that uses the electric field of a uniform-density ion channel rather than the magnetic field of an undulator to induce transverse oscillations of…

Accelerator Physics · Physics 2025-10-29 Claire Hansel , Agostino Marinelli , Zhirong Huang , Michael Litos

We present some approaches to the computation of ultra-fast laser pulses capable of selectively breaking molecular bonds. The calculations are based on a mixed quantum-classical description: The electrons are treated quantum mechanically…

Atomic and Molecular Clusters · Physics 2015-05-27 Kevin Krieger , Alberto Castro , E. K. U. Gross

An implementation of the generalized time-dependent generator coordinated method (TD-GCM) is developed, that can be applied to the dynamics of small- and large-amplitude collective motion of atomic nuclei. Both the generator states and…

Nuclear Theory · Physics 2023-07-28 B. Li , D. Vretenar , T. Nikšić , P. W. Zhao , J. Meng

Long range electrostatic, induction and dispersion coefficients including terms of order $R^{-8}$ have been calculated by the sum over states method using time dependent density functional theory. We also computed electrostatic moments and…

Chemical Physics · Physics 2015-06-05 Jason N. Byrd , John A. Montgomery , Robin Côté

We formulate a time-dependent Fluctuating Local Field (TD-FLF) method for correlated fermion dynamics, extending the stationary FLF approach. The wavefunction is approximated as an ensemble of non-interacting states subject to a classical…

Strongly Correlated Electrons · Physics 2026-04-30 L. D. Silakov , Ya. S. Lyakhova , A. N. Rubtsov

Atomic ions, confined in radio-frequency Paul ion traps, are a promising candidate to host a future quantum information processor. In this letter, we demonstrate a method to couple two motional modes of a single trapped ion, where the…

Time-dependent plasma codes are a natural extension of static nonequilibrium plasma codes. Comparing relevant timescales will determine whether or not time-dependent treatment is necessary. In this article I outline the ingredients for a…

Astrophysics · Physics 2007-05-23 S. Seager

We consider the time delay of electron detachment from a Coulomb center and two-center systems in the process of ionization. It is shown that the attosecond streaking, most usual method of time delay measure, can be formally described by…

Atomic Physics · Physics 2015-06-15 Vladislav V. Serov , Vladimir L. Derbov , Tatyana A. Sergeeva

Approximate scaling laws with respect to the nuclear charge are introduced for the time-dependent Dirac equation describing hydrogen-like ions subject to laser fields within the dipole approximation. In particular, scaling relations with…

Atomic Physics · Physics 2018-12-12 I. V. Ivanova , V. M. Shabaev , Dmitry A. Telnov , Alejandro Saenz

Attosecond pump-probe ionization process can be used to prepare atomic ions in the coherent superposition of states with opposite parity. The multiphoton shake-up ionization of Helium, in particular, generates ions with same principal…

Atomic Physics · Physics 2019-12-12 Saad Mehmood , Eva Lindroth , Luca Argenti

Quantum embedding methods have recently developed significantly to model large molecular structures. This work proposes a novel wave function theory in density functional theory (WTF-in-DFT) embedding scheme based on pair-coupled cluster…

Chemical Physics · Physics 2024-01-10 Rahul Chakraborty , Katharina Boguslawski , Paweł Tecmer

We present the numerical implementation of the time-dependent complete-active-space self-consistent-field (TD-CASSCF) method [Phys. Rev. A, 88, 023402 (2013)] for atoms driven by a strong linearly polarized laser pulse. The present…

We propose a new scalable architecture for trapped ion quantum computing that combines optical tweezers delivering qubit state-dependent local potentials with oscillating electric fields. Since the electric field allows for long-range…

Quantum Physics · Physics 2022-01-05 M. Mazzanti , R. X. Schüssler , J. D. Arias Espinoza , Z. Wu , R. Gerritsma , A. Safavi-Naini