Related papers: A Possible Additional Formation Pathway for the In…
As many organic molecules, formic acid (HCOOH) has two conformers (trans and cis). The energy barrier to internal conversion from trans to cis is much higher than the thermal energy available in molecular clouds. Thus, only the most stable…
Context. The chemistry of the diffuse interstellar medium rests upon three pillars: exothermic ion-neutral reactions (" cold chemistry "), endothermic neutral-neutral reactions with significant activation barriers (" warm chemistry "), and…
Methanol and its precursor formaldehyde are among the most studied organic molecules in the interstellar medium and are abundant in the gaseous and solid phases. We recently developed a model to simulate CO hydrogenation via H atoms on…
We present a 3d code for the dynamical evolution of a multi-phase interstellar medium (ISM) coupled to stars via star formation (SF) and feedback processes. The multi-phase ISM consists of clouds (sticky particles) and diffuse gas (SPH):…
We propose and experimentally demonstrate that the trihydrogen cation (H$_3^+$) can be produced via single photoionization of the molecular hydrogen dimer (H$_4$). Using near-infrared, femtosecond laser pulses and coincidence momentum…
Hydroxylamine, NH2OH, is one of the already detected interstellar molecules with the highest prebiotic potential. Yet, the abundance of this molecule found by astronomical observations is rather low for a relatively simple molecule, $\sim$…
We studied theoretically the cis-trans isomerization reactions of two astrophysically relevant acids, formic acid (HCOOH) and thioformic acid (HC(O)SH), where the latter has recently been discovered in space. We also searched for these…
Because chemical reactions on/in cosmic ice dust grains covered by amorphous solid water (ASW) play important roles in generating a variety of molecules, many experimental and theoretical studies have focused on the chemical processes…
Acetaldehyde (CH$_3$CHO) is one of the most detected interstellar Complex Organic Molecule (iCOM) in the interstellar medium (ISM). These species have a potential biological relevance, as they can be precursors of more complex species from…
We studied sulfur chemistry of massive star-forming regions through single-dish submillimeter spectroscopy. OCS, O13CS, 13CS, H2S and SO transitions were observed toward a sample of massive star-forming regions with embedded UCH II or CH II…
Recently, an atomic-scale two-dimensional silicon carbide monolayer has been synthesized {[}Polley \emph{et al., }Phys. Rev. Lett. \textbf{130},076203 (2023){]} which opens up new possibilities for developing next-generation electronic and…
Water is the main component of interstellar ice mantles, is abundant in the solar system and is a crucial ingredient for life. The formation of this molecule in the interstellar medium cannot be explained by gas-phase chemistry only and its…
This study focuses on the formation of two molecules of astrobiological importance - glycolaldehyde (HC(O)CH2OH) and ethylene glycol (H2C(OH)CH2OH) - by surface hydrogenation of CO molecules. Our experiments aim at simulating the CO…
The role of large-scale stellar feedback in the formation of molecular clouds has been investigated observationally by examining the relationship between HI and 12CO(J=1-0) in supershells. Detailed parsec-resolution case studies of two…
Selective laser reaction sintering techniques (SLRS) techniques were investigated for the production of near net-shape non-oxide ceramics including SiC, Si$_3$N$_4$, and HfC/SiC composites that might be compatible with prevailing powder bed…
Ions and electrons play an important role in various stages of the star formation process. By following the magnetic field of their environment and interacting with neutral species, they slow down the gravitational collapse of the…
While the abundances of Be and B observed in metal-poor halo stars are well explained as resulting from spallation of CNO-enriched cosmic rays (CRs) accelerated by supernova shocks, accounting for the observed $^6$Li in such stars with…
Cosmological N-body hydrodynamic computations following atomic and molecular chemistry (e$^-$, H, H$^+$, H$^-$, He, He$^+$, He$^{++}$, D, D$^+$, H$_2$, H$_2^+$, HD, HeH$^+$), gas cooling, star formation and production of heavy elements (C,…
Observations towards IRC +10216 of CS, SiO, SiS, NaCl, KCl, AlCl, AlF, and NaCN have been carried out with the IRAM 30-m telescope in the 80-357.5 GHz frequency range. A large number of rotational transitions covering a wide range of energy…
Gas-phase processes were long thought to be the key formation mechanisms for complex organic molecules in star-forming regions. However, recent experimental and theoretical evidence has cast doubt on the efficiency of such processes.…