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Sulfur-bearing molecules are central to interstellar chemistry, yet their observed abundances in the gas phase remain far below cosmic expectations in dense interstellar regions. Mixed N-S-O species such as thionylimide (HNSO) are…

Astrophysics of Galaxies · Physics 2025-12-01 Valerio Lattanzi , Miguel Sanz-Novo , Víctor M. Rivilla , Izaskun Jiménez-Serra , Paola Caselli

Non-linear absorption phenomena induced by controlled irradiation with a femtosecond laser beam can be used to tailor materials properties within the bulk of substrates. One of the most successful applications of this technique is the…

Both tin monosulfide (SnS) and tin disulfide (SnS2) are thermodynamically stable layered materials with potential for spin-valleytronic devices and photodetectors. Notably, monolayer SnS, owing to its low symmetry, exhibits interesting…

Sulfur is essential for life, but its abundance and distribution in the interstellar medium remain uncertain, with over 90% of sulfur undetected in cold molecular clouds. Sulfur allotropes (S$_{\rm n}$) have been proposed as possible…

Interstellar space is filled with a dilute mixture of charged particles, atoms, molecules and dust grains, called the interstellar medium (ISM). Understanding its physical properties and dynamical behavior is of pivotal importance to many…

Astrophysics of Galaxies · Physics 2014-12-18 Ralf S. Klessen , Simon C. O. Glover

A number of recent experimental studies have shown that solid-state complex organic molecules (COMs) can form under conditions that are relevant to the CO freeze-out stage in dense clouds. In this work, we show that alcohols can be formed…

Astrophysics of Galaxies · Physics 2019-05-16 D. Qasim , G. Fedoseev , T. Lamberts , K. -J. Chuang , J. He , S. Ioppolo , J. Kästner , H. Linnartz

The hydroxyl radical (OH) is found in various environments within the interstellar medium (ISM) of the Milky Way and external galaxies, mostly either in diffuse interstellar clouds or in the warm, dense environments of newly formed low-mass…

Three structural isomers of the C2H4O2 molecule, namely, methyl formate (MF; HCOOCH3), acetic acid (AA; CH3COOH), and glycol aldehyde (GA; HOCH2CHO), have attracted considerable attention as targets for understanding pathways towards…

Astrophysics of Galaxies · Physics 2021-11-17 A. Ishibashi , H. Hidaka , Y. Oba , A. Kouchi , N. Watanabe

The successive addition of H atoms to CO in the solid phase has been hitherto regarded as the primary route to form methanol in dark molecular clouds. However, recent Monte Carlo simulations of interstellar ices alternatively suggested the…

Astrophysics of Galaxies · Physics 2022-06-15 Julia C. Santos , Ko-Ju Chuang , Thanja Lamberts , Gleb Fedoseev , Sergio Ioppolo , Harold Linnartz

Nearby spiral galaxies show an extremely tight correlation between tracers of molecular hydrogen (H_2) in the interstellar medium (ISM) and tracers of recent star formation, but it is unclear whether this correlation is fundamental or…

Cosmology and Nongalactic Astrophysics · Physics 2015-05-20 Mark R. Krumholz , Adam K. Leroy , Christopher F. McKee

Stratospheric aerosol injection (SAI) has been proposed as a geoengineering strategy to mitigate global warming by increasing Earth's albedo. Silica-based materials, such as diamond-doped silica aerogels, have shown promising optical…

Chemical Physics · Physics 2025-12-24 Dennis Lima , Saif Al-Kuwari , Ivan Gladich

The origin of bistable solutions in the kinetic equations describing the chemistry of dense interstellar clouds is explained as being due to the autocatalysis and feedback of oxygen nuclei from the oxygen dimer (O2). We identify four…

Astrophysics of Galaxies · Physics 2020-10-26 G. Dufour , S. B. Charnley

>1A review of meson emission in heavy ion collisions at incident energies from SIS up to collider energies is presented. A statistical model assuming chemical equilibrium and local strangeness conservation (i.e. strangeness conservation per…

Nuclear Experiment · Physics 2008-11-26 H. Oeschler , J. Cleymans , K. Redlich

Context. In dense clouds, hydrogenation reactions on icy dust grains are key in the formation of molecules, like formaldehyde, methanol, and complex organic molecules (COMs). These species form through the sequential hydrogenation of CO…

Solar and Stellar Astrophysics · Physics 2018-09-28 K. -J. Chuang , G. Fedoseev , D. Qasim , S. Ioppolo , E. F. van Dishoeck , H. Linnartz

Experimental results on the formation of molecular hydrogen on amorphous silicate surfaces are presented and analyzed using a rate equation model. The energy barriers for the relevant diffusion and desorption processes are obtained. They…

The disk midplane temperature is potentially affected by the dust traps/rings. The dust depletion beyond the water snowline will cast a shadow. In this study, we adopt a detailed gas-grain chemical reaction network, and investigate the…

Earth and Planetary Astrophysics · Physics 2022-09-21 Shota Notsu , Kazumasa Ohno , Takahiro Ueda , Catherine Walsh , Christian Eistrup , Hideko Nomura

The presence of elemental vacancies in materials is inevitable according to statistical thermodynamics, which will decide the chemical and physical properties of the investigated system. However, the controlled manipulation of vacancies for…

Hydroxylamine (NH2OH) is one of the potential precursors of complex pre-biotic species in space. Here we present a detailed experimental study of hydroxylamine formation through nitric oxide (NO) surface hydrogenation for astronomically…

Astrophysics of Galaxies · Physics 2017-05-26 Gleb Fedoseev , Sergio Ioppolo , Thanja Lamberts , Junfeng Zhen , Herma M. Cuppen , Harold Linnartz

We investigate the formation and evolution of interstellar dust-grain ices under dark-cloud conditions, with a particular emphasis on CO2. We use a three-phase model (gas/surface/mantle) to simulate the coupled gas--grain chemistry,…

Astrophysics of Galaxies · Physics 2015-05-28 Robin T. Garrod , Tyler Pauly

Knowledge of the molecular component of the ISM is fundamental to understand star formation. The H2 component appears to dominate the gas mass in the inner parts of galaxies, while the HI component dominates in the outer parts. Observation…

Astrophysics · Physics 2009-10-31 F. Combes