Related papers: A Possible Additional Formation Pathway for the In…
We study the formation of chemical sequences in the stellar disc of Milky Way (MW)-mass galaxies in a full cosmological context with the auriga simulations. We focus on the conditions giving rise to bi-modal $\alpha$-chemistry in the MW…
Stars form in the dense interiors of molecular clouds. The dynamics and physical properties of the atomic interstellar medium (ISM) set the conditions under which molecular clouds and eventually stars will form. It is, therefore, critical…
Despite its biogeneic and astrochemical importance, sulfur (S), the 10th most abundant element in the interstellar medium (ISM) with a total abundance of S/H~2.2E-5, largely remains undetected in molecular clouds. Even in the diffuse ISM…
We report the first detection in the interstellar medium of a C$_2$H$_5$O$_2$N isomer: $syn$-glycolamide (NH$_2$C(O)CH$_2$OH). The exquisite sensitivity at sub-mK levels of an ultra-deep spectral survey carried out with the Yebes 40m and…
The application of silicon monoxide (SiO) as a shock tracer arises from its propensity to occur in the gas phase as a result of shock-induced phenomena, including outflow activity and interactions between molecular clouds and expanding HII…
We report the detection in TMC-1 of the protonated form of C3S. The discovery of the cation HC3S+ was carried through the observation of four harmonically related lines in the Q band using the Yebes 40m radiotelescope, and is supported by…
We revise the rates of reactions CH + S -> CS + H and C_2 + S -> CS + C, important CS formation routes in dark and diffuse warm gas. We performed ab initio calculations to characterize the main features of all the electronic states…
The abundance and distribution of sulfur-bearing molecules in protoplanetary disks directly influences the composition and potential habitability of nascent planets in addition to providing powerful probes of the physical gas conditions in…
The fundamental process of star formation in galaxies involves the interplay between the fueling of star formation via molecular gas and the feedback from recently formed massive stars. This process, by which galaxies evolve, is also…
(Abridged) In the low-mass star formation process, theoretical models predict that material from the infalling envelope could be shocked as it encounters the outer regions of the disk. Nevertheless, only a few protostars show evidence of…
The chemistry of the diffuse interstellar medium is driven by the combined influences of cosmic rays, ultraviolet (UV) radiation, and turbulence. Previously detected at the outer edges of photodissociation regions (PDRs) and formed from the…
Recent laboratory measurements for the S^+2 + H2 reaction find a total rate coefficient significantly larger than previously used in theoretical models of X-ray dominated regions (XDRs). While the branching ratio of the products is unknown,…
The study of hexagonal silicon polytypes attracts special attention due to their unique physical properties compared to the traditional cubic phase of Si. Thus, for some hexagonal phases, a significant improvement in the emission properties…
Methods: The microscopic equations of H2-formation and protonation are integrated numerically over time in such a manner that the overall structures evolve self-consistently under benign conditions. Results: The equilibrium H2 formation…
I discuss various proposed formation scenarios for the metal-poor components of the Milky Way Galaxy, emphasising the stellar halo and the thick disk. Interactions and accretion played a significant role in Galactic evolution, in particular…
In analogy to III-V compounds, which have significantly broadened the scope of group IV semiconductors, we propose IV-VI compounds as isoelectronic counterparts to layered group V semiconductors. Using {\em ab initio} density functional…
Wet chemistry C-S-H precipitation experiments were performed under controlled conditions of solution supersaturation in the presence and absence of gluconate and three hexitol molecules. Characterization of the precipitates with SAXS and…
Young stars in the disks of galaxies produce HI from their parent H2 clouds by photodissociation. This paper describes the observational evidence for and the morphology of such HI. Simple estimates of the amount of dissociated gas lead to…
Formamide has a key role in prebiotic chemistry as it is the simplest molecule containing the four most important atoms from a biological point of view: hydrogen, carbon, nitrogen and oxygen. Due to its importance, the formation of this…
Molecular clouds (MCs) are the birthplaces of new stars in galaxies. A key component of MCs are photodissociation regions (PDRs), where far-ultraviolet radiation plays a crucial role in determining the gas's physical and chemical state.…