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Highly charged ions (HCIs) are insensitive to external perturbations and are attractive for the development of ultrastable clocks. However, only a few HCI candidates are known to provide optical clock transitions. In this Letter, we show…

Atomic Physics · Physics 2025-01-07 Chunhai Lyu , Christoph H. Keitel , Zoltán Harman

Optical atomic clocks using highly-charged ions hold an intriguing promise of metrology at the 19th significant figure. Here we study transitions within the $4f^{12}$ ground-state electronic configuration of highly charged ions. We consider…

Atomic Physics · Physics 2015-06-11 V. A. Dzuba , A. Derevianko , V. V. Flambaum

Attempts are made to unify gravity with the other three fundamental forces of nature. As suggested by higher dimensional models, this unification may require space and time variation of some dimensionless fundamental constants. In this…

Atomic Physics · Physics 2023-02-15 Yan-Mei Yu , B. K. Sahoo , Bing-Bing Suo

Optical atomic clocks are the most accurate measurement devices ever constructed and have found many applications in fundamental science and technology. The use of highly charged ions (HCI) as a new class of references for highest accuracy…

We propose here a few selective highly charged ions (HCIs), namely Ni$^{12+}$ and Cu$^{13+}$, Pd$^{12+}$ and Ag$^{13+}$, that not only promise to be very high accurate optical clocks below $10^{-19}$ uncertainties, but also offer quality…

Atomic Physics · Physics 2018-04-25 Yan-mei Yu , B. K. Sahoo

We study a wide range of neutral atoms and ions suitable for ultra-precise atomic optical clocks with naturally suppressed black body radiation shift of clock transition frequency. Calculations show that scalar polarizabilities of clock…

Atomic Physics · Physics 2015-06-22 Alexander Kozlov , Vladimir Dzuba , Victor Flambaum

We identify laser-accessible transitions in group 16-like highly charged ions as candidates for high-accuracy optical clocks, including S-, Se-, and Te-like systems. For this class of ions, the ground $^{3}P_{J}$ fine structure manifold…

Atomic Physics · Physics 2022-10-06 Saleh O. Allehabi , S. M. Brewer , V. A. Dzuba , V. V. Flambaum , K. Beloy

Recent experimental progress in cooling, trapping, and quantum logic spectroscopy of highly-charged ions (HCIs) made HCIs accessible for high resolution spectroscopy and precision fundamental studies. Based on these achievements, we explore…

A new method for examining the possible space-time variation of the fine structure constant ($\alpha$) is proposed. The technique uses a relatively simple measurement with an optical resonator to compare atom-stabilized optical frequency…

Atomic Physics · Physics 2007-05-23 J. R. Torgerson

We identify Ba$^{4+}$ (Te-like) as a promising candidate for a high-accuracy optical clock. The lowest-lying electronic states are part of a $^3P_J$ fine structure manifold with anomalous energy ordering, being non-monotonic in $J$. We…

Atomic Physics · Physics 2020-10-26 Kyle Beloy , Vladimir A. Dzuba , Samuel M. Brewer

An active optical clock based on highly charged Nd$^{9+}$ ion is proposed for the first time. The clock can offer ultra-narrow linewidth at the $\upmu$Hz-level which is more than two-order of magnitude below the currently recorded laser…

Atomic Physics · Physics 2021-07-23 Yan-mei Yu , Duo Pan , Shaolong Chen , Hua Guan , Kelin Gao , Jingbiao Chen

Numerous few-electron atomic systems are considered which can be used effectively for observing a potential variation of the fine-structure constant $\alpha$ and the electron-proton mass ratio $m_e/m_p$. We examine optical magnetic dipole…

Divalent atoms and ions with a singlet $S$ ground state and triplet $P$ excited state form the basis of many high-precision optical atomic clocks. Along with the metastable $^{3}\mathrm{P}_{0}$ clock state, these atomic systems also have a…

Sensitivity to temporal variation of the fundamental constants may be strongly enhanced in transitions between narrow close levels of different nature. This enhancement may be realized in a large number of molecules due to cancelation…

Atomic Physics · Physics 2008-11-26 V. V. Flambaum , M. G. Kozlov

A high-precision relativistic calculations of Cd-like Nd$^{12+}$, Sm$^{14+}$ and Sn-like Pr$^{9+}$, Nd$^{10+}$ atomic properties is carried out using an approach that combines configuration interaction and a linearized coupled-cluster…

Atomic Physics · Physics 2015-06-22 M. S. Safronova , V. A. Dzuba , V. V. Flambaum , U. I. Safronova , S. G. Porsev , M. G. Kozlov

Quasi-forbidden electronic transitions in atoms and quasi-degenerate vibronic transitions in molecules serve as powerful probes of hypothetical temporal variations of fundamental constants. Computation of the sensitivity of a transition to…

Chemical Physics · Physics 2025-11-17 Carsten Zülch , Konstantin Gaul , Robert Berger

We present a review of recent works devoted to the variation of the fine structure constant alpha, strong interaction and fundamental masses. There are some hints for the variation in quasar absorption spectra, Big Bang nucleosynthesis, and…

Atomic Physics · Physics 2009-08-18 V. V. Flambaum

We have determined the frequency shift that blackbody radiation is inducing on the $5s^2$ $^1$S$_0$ -- $5s5p$ $^3$P$_0$ clock transition in strontium. Previously its uncertainty limited the uncertainty of strontium lattice clocks to…

Atomic Physics · Physics 2013-01-01 Thomas Middelmann , Stephan Falke , Christian Lisdat , Uwe Sterr

The comparison of different atomic transition frequencies over time can be used to determine the present value of the temporal derivative of the fine structure constant alpha in a model-independent way without assumptions on constancy or…

Atomic Physics · Physics 2009-11-10 E. Peik , B. Lipphardt , H. Schnatz , T. Schneider , Chr. Tamm , S. G. Karshenboim

We have developed a broadly-applicable approach that drastically increases the ability to accurately predict properties of complex atoms. We applied it to the case of Ir$^{17+}$, which is of particular interest for the development of novel…

Atomic Physics · Physics 2020-04-29 C. Cheung , M. S. Safronova , S. G. Porsev , M. G. Kozlov , I. I. Tupitsyn , A. I. Bondarev