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The interaction between excited states of a molecule and excited states of metal nanostructure (e.g. plasmons) leads to hybrid states with modified optical properties. When plasmon resonance is swept through molecular transition frequency…

Chemical Physics · Physics 2022-05-04 Monosij Mondal , Maicol A. Ochoa , Maxim Sukharev , Abraham Nitzan

Polaritonic states arise when a bright optical transition of a molecular ensemble is resonantly matched to an optical cavity mode frequency. Here, we lay the groundwork to study the behavior of polaritons in clean, isolated systems by…

Chemical Physics · Physics 2023-10-20 Adam D. Wright , Jane C. Nelson , Marissa L. Weichman

Strong light-matter interactions in both the single-emitter and collective strong coupling regimes attract significant attention due to emerging quantum and nonlinear optics applications, as well as opportunities for modifying…

Mesoscale and Nanoscale Physics · Physics 2019-09-11 Tuomas P. Rossi , Timur Shegai , Paul Erhart , Tomasz J. Antosiewicz

We investigate cooperative fluorescence in a dilute cloud of strongly driven two-level emitters. Starting from the Heisenberg equations of motion, we compute the first-order scattering corrections to the saturation of the excited-state…

Atomic Physics · Physics 2013-06-06 J. R. Ott , M. Wubs , P. Lodahl , N. A. Mortensen , R. Kaiser

Plasmonic nanocavities enable the confinement of molecules and electromagnetic fields within nano-metric volumes. As a consequence, the molecules experience a remarkably strong interaction with the electromagnetic field, to such an extent…

Chemical Physics · Physics 2021-09-01 Jacopo Fregoni , Tor S. Haugland , Silvio Pipolo , Tommaso Giovannini , Henrik Koch , Stefano Corni

The effect of optical radiation on the rate of aggregation of nanoscopic particles is studied in metal aerosols. It has been shown that under light exposure, polydisperse metal aerosols can aggregate up to two orders faster due to the size…

Chemical Physics · Physics 2010-10-07 Sergei V. Karpov , Ivan L. Isaev

Strong light-matter coupling provides a versatile and novel means to manipulate chemical processes. Here we develop a theoretical framework to investigate the spectroscopy and dynamics of a molecular ensemble embedded in an optical cavity…

Quantum Physics · Physics 2023-06-16 Bing Gu

We study the polaritonic states and dynamics of multiple Jahn-Teller (JT) active molecules coupled to the modes of a Fabry-Perot cavity. We find that collective effects dramatically alter the interplay of electronic, vibrational and cavity…

Quantum Physics · Physics 2025-11-12 Suraj Kumar Pandit , Abhinay Pandey , Athreya Shankar , Krishna R. Nandipati

We present an analytical and numerical study of the coherent exciton polarization including exciton-exciton correlation. The time evolution after excitation with ultrashort optical pulses can be divided into a slowly varying polarization…

Condensed Matter · Physics 2009-10-31 Th. Oestreich , L. J. Sham

Collective excited states form in organic two-dimensional layers through the Coulomb coupling of the molecular transition dipole moments. They manifest as characteristic strong and narrow peaks in the excitation and emission spectra that…

A mixture of solvent particles with short-range, directional interactions and solute particles with short-range, isotropic interactions that can bond multiple times is of fundamental interest in understanding liquids and colloidal mixtures.…

Soft Condensed Matter · Physics 2016-09-21 Artee Bansal , D. Asthagiri , Kenneth R. Cox , Walter G. Chapman

In this paper we develop quantum dynamical methods capable of treating the dynamics of chemically reacting systems in an optical cavity in the vibrationally strong-coupling (VSC) limit at finite temperatures and in the presence of a…

Quantum Physics · Physics 2025-02-11 Lachlan P. Lindoy , Arkajit Mandal , David R. Reichman

Polaritons - hybrid light-matter states formed from the strong coupling of a bright molecular transition with a confined photonic mode - may offer new opportunities for optical control of molecular behavior. Vibrational strong coupling…

Chemical Physics · Physics 2025-11-19 Liying Chen , Alexander M. McKillop , Ashley P. Fidler , Marissa L. Weichman

We introduce a new dynamic light scattering method, termed photon correlation imaging, which enables us to resolve the dynamics of soft matter in space and time. We demonstrate photon correlation imaging by investigating the slow dynamics…

Soft Condensed Matter · Physics 2009-03-02 Agnes Duri , David A. Sessoms , Veronique Trappe , Luca Cipelletti

Strong light-matter coupling occurs when the coupling strength between a confined electromagnetic mode and a molecular resonance exceeds losses to the environment. The study of strong coupling has been motivated by applications such as…

Mesoscale and Nanoscale Physics · Physics 2022-04-27 Philip A. Thomas , Kishan S. Menghrajani , William L. Barnes

We present a personal view on the current state of statistical mechanics of Coulomb fluids with special emphasis on the interactions between macromolecular surfaces, concentrating on the weak and the strong coupling limits. Both are…

Soft Condensed Matter · Physics 2015-06-16 Ali Naji , Matej Kanduč , Jan Forsman , Rudolf Podgornik

Polaritons, formed as a result of strong hybridization of matter with light, are promising for important applications including organic solar cells, optical logic gates, and qubits. Owing to large binding energies of Frenkel excitons…

Nonperturbative coupling of light with condensed matter in an optical cavity is expected to reveal a host of coherent many-body phenomena and states. In addition, strong coherent light-matter interaction in a solid-state environment is of…

We report, for the first time, some experimental observations regarding a new type of long range interaction between rigid particles that prevails when they are suspended in an soft elastic gel. A denser particle submerges itself to a…

Soft Condensed Matter · Physics 2014-01-29 Aditi Chakrabarti , Manoj K. Chaudhury

We investigate the control of interacting matter through strong coupling to a single electromagnetic mode, such as the photon mode in a Fabry-Perot or split-ring cavity. For this purpose, we analyze the exact effective theory for the…

Strongly Correlated Electrons · Physics 2022-05-12 Katharina Lenk , Jiajun Li , Philipp Werner , Martin Eckstein