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Controlling polymorphism in molecular crystals is crucial in the pharmaceutical, dye, and pesticide industries. However, its theoretical description is extremely challenging, due to the associated long timescales ($ > 1 \, \mu s$). We…

Chemical Physics · Physics 2023-02-09 Oren Elishav , Roy Podgaetsky , Olga Meikler , Barak Hirshberg

Collective optical excitations, such as localized surface plasmons in metallic nanoparticles and Mie resonances in high-index dielectrics, play a central role in nanoscale light--matter interactions. When such optical modes interact with…

We demonstrate that a ionising transition can be strongly coupled to a photonic resonance. The strong coupling manifests itself with the appearance of a narrow optically active resonance below the ionisation threshold. Such a resonance is…

The collapse and swelling behavior of a generic homopolymer is studied using implicit-solvent, explicit-cosolvent Langevin dynamics computer simulations for varying interaction strengths. The systematic investigation reveals that polymer…

Soft Condensed Matter · Physics 2012-11-06 Anja Muzdalo , Jan Heyda , Joachim Dzubiella

The interplay between static and dynamic disorder and collective optical response in molecular ensembles is an important characteristic of nanoplasmonic and nanophotonic molecular systems. Here we investigate the cooperative superradiant…

Prolific interactions of nonlinear waves on a plane-wave background in an erbium-doped fiber system are unveiled, based on explicit coexistence conditions extracting from the general higher-order solution of a coupled nonlinear…

Pattern Formation and Solitons · Physics 2016-01-21 Liang Duan , Zhan-Ying Yang , Chong Liu , Wen-Li Yang

Optomechanical devices have been cooled to ground-state and genuine quantum features, as well as long-predicted nonlinear phenomena, have been observed. When packing close enough more than one optomechanical unit in the same substrate the…

Quantum Physics · Physics 2017-11-08 Albert Cabot , Fernando Galve , Roberta Zambrini

We present a model for molecular materials made up of polar and polarizable molecular units. A simple two state model is adopted for each molecular site and only classical intermolecular interactions are accounted for, neglecting any…

Materials Science · Physics 2009-11-10 Francesca Terenziani , Anna Painelli

In this work, we provide an overview of how well-established concepts in the fields of quantum chemistry and material sciences have to be adapted when the quantum nature of light becomes important in correlated matter-photon problems.…

Quantum Physics · Physics 2017-04-12 Johannes Flick , Michael Ruggenthaler , Heiko Appel , Angel Rubio

We show that atoms or molecules subject to fields that couple their internal and translational (momentum) states may undergo a crossover from randomization (diffusion) to strong localization (sharpening) of their momentum distribution. The…

Soft Condensed Matter · Physics 2013-05-29 Nir Bar-Gill , Gershon Kurizki

We investigate the statistical mechanics of an inhomogeneous Coulomb fluid composed of charged particles with static polarizability. We derive the weak- and the strong-coupling approximations and evaluate the partition function in a planar…

Soft Condensed Matter · Physics 2013-04-22 Vincent Démery , David S. Dean , Rudolf Podgornik

Following experimental evidence that vibrational polaritons, formed from collective vibrational strong coupling (VSC) in optical microcavities, can modify ground-state reaction rates, a spate of theoretical explanations relying on…

Chemical Physics · Physics 2023-04-14 Matthew Du , Yong Rui Poh , Joel Yuen-Zhou

Intermixed light-matter quasiparticles - polaritons - possess unique optical properties owned to their compositional nature. These intriguing hybrid states have been extensively studied over the past decades in a wide range of realizations…

One of the most popular subjects now being researched in molecular science is strong light-matter coupling. The introduction of vibrational strong coupling and the formation vibro-polaritonic states tend to modify chemical reactivity,…

Chemical Physics · Physics 2023-08-10 Akhila Kadyan , Monu P. Suresh , Ben Johns , Jino George

We study the capacitance spectra of artificial molecules consisting of two and three coupled quantum dots from an extended Hubbard Hamiltonian model that takes into account quantum confinement, intra- and inter-dot Coulomb interaction and…

Condensed Matter · Physics 2009-10-28 F. Ramirez , E. Cota , S. E. Ulloa

Many-body Coulomb interactions drastically modify the optical response of highly doped semiconductor quantum wells leading to a merger of all intersubband transition resonances into one sharp peak at the frequency substantially higher than…

Mesoscale and Nanoscale Physics · Physics 2023-06-14 Mikhail Tokman , Maria Erukhimova , Yongrui Wang , Alexey Belyanin

The first-principles simulation of the electronic structure of organic semiconductors in solution poses a number of challenges that are not trivial to address simultaneously. In this work, we investigate the effects and the mutual interplay…

Materials Science · Physics 2021-03-08 Jannis Krumland , Ana M. Valencia , Caterina Cocchi

Room temperature cavity quantum electrodynamics with molecular materials in optical cavities offers exciting prospects for controlling electronic, nuclear and photonic degrees of freedom for applications in physics, chemistry and materials…

Quantum Physics · Physics 2025-01-15 Felipe Herrera , William L. Barnes

A hidden local symmetry formalism with a two-photon counterterm approach is performed based on the relativistic continuum quantum many-body theory. The underlying electromagnetic under-screening as well as screening effects between the…

Nuclear Theory · Physics 2007-05-23 Ji-sheng Chen

The strong coupling between molecules and photons in resonant cavities offers a new toolbox to manipulate photochemical reactions. While the quenching of photochemical reactions in the strong coupling regime has been demonstrated before,…

Mesoscale and Nanoscale Physics · Physics 2019-12-24 Jacop Fregoni , Giovanni Granucci , Maurizio Persico , Stefano Corni