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In ab initio pseudopotential calculations within density-functional theory the nonlinear exchange-correlation interaction between valence and core electrons is often treated linearly through the pseudopotential. We discuss the accuracy and…

Materials Science · Physics 2009-10-30 Martin Fuchs , Michel Bockstedte , Eckhard Pehlke , Matthias Scheffler

The existence of global weak solutions to a parabolic energy-transport system in a bounded domain with no-flux boundary conditions is proved. The model can be derived in the diffusion limit from a kinetic equation with a linear collision…

Analysis of PDEs · Mathematics 2023-07-18 Gianluca Favre , Ansgar Jüngel , Christian Schmeiser , Nicola Zamponi

The structural and energetic properties of layered materials propose a challenge to density functional theory with common semilocal approximations to the exchange-correlation. By combining the most-widely used semilocal generalized gradient…

Materials Science · Physics 2017-02-22 Haowei Peng , John P. Perdew

Approximate exchange-correlation functionals built by modeling in a non-linear way the adiabatic connection (AC) integrand of density functional theory have many attractive features, being virtually parameters-free and satisfying different…

Chemical Physics · Physics 2018-05-25 S. Vuckovic , P. Gori-Giorgi , F. Della Sala , E. Fabiano

A density-matrix formalism is developed based on the one-particle density-matrix of a single-determinantal reference-state. The v-representable problem does not appear in the proposed method, nor the need to introduce functionals defined by…

Chemical Physics · Physics 2009-11-10 James P. Finley

A new model with a new Hamiltonian is offered as the means for studying properties of a system of strongly correlated electrons. Consideration of the simplest possible situation, namely a system on non-interacting electrons in a two-leg…

General Physics · Physics 2018-01-30 Valentin Voroshilov

To address the impact of electron correlations in the linear and non-linear response regimes of interacting many-electron systems exposed to time-dependent external fields, we study one-dimensional (1D) systems where the interacting problem…

Other Condensed Matter · Physics 2011-08-17 N. Helbig , J. I. Fuks , I. V. Tokatly , H. Appel , E. K. U. Gross , A. Rubio

In this work we have studied a new functional for the correlation energy obtained from the exact-exchange (EXX) approximation within time-dependent density functional theory (TDDFT). Correlation energies have been calculated for a number of…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 Maria Hellgren , Ulf von Barth

The systematic analysis of non-adiabatic effect on convective mode has been conducted using wave energy relation. In the adiabatic analysis, the "propagation diagram" for convective mode is proposed as a useful tool to see its behavior. In…

Solar and Stellar Astrophysics · Physics 2026-03-12 Hiroyasu Ando

In this paper we study a system of variational inequalities where the operator is non-local, possibly degenerate and of second order. A special case of this type of problem occurs in the context of optimal switching problems when the…

Optimization and Control · Mathematics 2013-07-09 Niklas L. P. LundstrÖm , Kaj NystrÖm , Marcus Olofsson

Combinatorial Levy processes evolve on general state spaces of countable combinatorial structures. In this setting, the usual Levy process properties of stationary, independent increments are defined in an unconventional way in terms of the…

Probability · Mathematics 2016-12-20 Harry Crane

We consider a finite region of a $d$-dimensional lattice, $d\in\mathbb{N}$, of weakly coupled harmonic oscillators. The coupling is provided by a nearest-neighbour potential (harmonic or not) of size $\varepsilon$. Each oscillator weakly…

Mathematical Physics · Physics 2016-06-29 A. Dymov

The correlation energy in density functional theory can be expressed exactly in terms of the change in the probability of finding two electrons at a given distance $r_{12}$ (intracule density) when the electron-electron interaction is…

Other Condensed Matter · Physics 2017-08-23 Paola Gori-Giorgi , Michael Seidl , Andreas Savin

We develop relativistic short-range exchange energy functionals for four-component relativistic range-separated density-functional theory using a Dirac-Coulomb Hamiltonian in the no-pair approximation. We show how to improve the short-range…

Chemical Physics · Physics 2020-06-24 Julien Paquier , Emmanuel Giner , Julien Toulouse

A process of energy transfer is demonstrated in non-equilibrium charged particle beams with anisotropy and space charge. Equipartitioning of energy between available degrees of freedom occurs in just a few betatron wavelengths, without halo…

Accelerator Physics · Physics 2007-05-23 R. A. Kishek , P. G. O'Shea , M. Reiser

We investigate the existence and properties of effective potentials in time-dependent density functional theory. We outline conditions for a general solution of the corresponding Sturm-Liouville boundary value problems. We define the set of…

Mathematical Physics · Physics 2009-11-11 M. Ruggenthaler , M. Penz , D. Bauer

One-dimensional, boundary-driven lattice gases with local interactions are studied in the weakly interacting limit. The density profiles and the correlation functions are calculated to first order in the interaction strength for zero-range…

Statistical Mechanics · Physics 2015-06-24 Frederic van Wijland , Zoltan Racz

Bounded weak solutions to a particular class of degenerate parabolic cross-diffusion systems are shown to coincide with the unique strong solution determined by the same initial condition on the maximal existence interval of the latter. The…

Analysis of PDEs · Mathematics 2022-07-04 Philippe Laurençot , Bogdan-Vasile Matioc

We introduce a new paradigm for finite and infinite strict-one-dimensional uniform electron gases. In this model, $n$ electrons are confined to a ring and interact via a bare Coulomb operator. In the high-density limit (small-$r_s$, where…

Strongly Correlated Electrons · Physics 2012-08-15 Pierre-François Loos , Peter M. W. Gill

Linearized elasticity models are derived, via Gamma-convergence, from suitably rescaled nonlinear energies when the corresponding energy densities have a multiwell structure and satisfy a weak coercivity condition, in the sense that the…

Analysis of PDEs · Mathematics 2014-03-12 Virginia Agostiniani , Timothy Blass , Konstantinos Koumatos