Approximate exchange-correlation functionals built by modeling in a non-linear way the adiabatic connection (AC) integrand of density functional theory have many attractive features, being virtually parameters-free and satisfying different exact properties, but they also have a fundamental flaw: they violate the size-consistency condition, crucial to evaluate interaction energies of molecular systems. We show that size consistency in the AC-based functionals can be restored in a very simple way at no extra computational cost. Results on a large set of benchmark molecular interaction energies show that functionals based on the interaction strength interpolation approximations are significantly more accurate than the second-order perturbation theory.
@article{arxiv.1802.02144,
title = {Restoring size consistency of approximate functionals constructed from the adiabatic connection},
author = {S. Vuckovic and P. Gori-Giorgi and F. Della Sala and E. Fabiano},
journal= {arXiv preprint arXiv:1802.02144},
year = {2018}
}