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We present a unified ab-initio study of electronic and optical properties of TiO2 rutile and anatase phases, with a combination of Density Functional Theory and Many Body Perturbation Theory techniques. The consistent treatment of…

Spectroscopic techniques, including photoelectron spectroscopy, diffuse reflectance, and x-ray absorption, are used to investigate the electronic structure and the local structure of LaOBiS$_{2-x}$Se$_x$ thermoelectric material. It is found…

Materials Science · Physics 2019-04-15 K. Terashima , Y. Yano , E. Paris , Y. Goto , Y. Mizuguchi , Y. Kamihara , T. Wakita , Y. Muraoka , N. L. Saini , T. Yokoya

Black TiO2 with/without noble metal has been proposed for visible photocatalyst, still leaving poor catalyst efficiency. Alternatively, phase-mixed TiO2 such as anatase and rutile has been commonly used for visible catalysts with the…

Two-dimensional electron gases (2DEGs) on the SrTiO3 (STO) surface or in STO-based heterostructures have exhibited many intriguing phenomena, which are strongly dependent on the 2DEG-carrier density. We report that the tunability of the…

Strongly Correlated Electrons · Physics 2021-05-14 Hyang Keun Yoo , Luca Moreschini , Andrew L. Walter , Aaron Bostwick , Karsten Horn , Eli Rotenberg , Young Jun Chang

Dye Sensitized Solar Cells (DSSCs) have recently regained attention for indoor light harvesting and powering wireless devices. Advantages such as cost-effectiveness, flexibility, wide angular response, and lightweight design have driven the…

Spatial light modulators have desirable applications in sensing and free space communication because they create an interface between the optical and electronic realms. Electro-optic modulators allow for high-speed intensity manipulation of…

Optics · Physics 2023-09-01 Sydney Mason , Ileana-Cristina Benea-Chelmus

In the present work we investigate the photocatalytic hydrogen production (water splitting) activity of different Pt loaded TiO2 nanotube layers. Therefore, we fabricate free standing membranes and fix them in four different configurations:…

Materials Science · Physics 2016-10-14 Gihoon Cha , Kiyoung Lee , JeongEun Yoo , Manuela S. Killian , Patrik Schmuki

Using density-functional theory calculations within the generalized gradient corrected approximation, the models that nonmetallic impurities X substituted for O or Ti sites in anatase TiO2 were investigated. The conclusion of the valence…

Materials Science · Physics 2013-12-03 Pengyu Dong , Huanhuan Pei , Qinfang Zhang , Yuhua Wang

We report the experimental realization of a LiNbO3 metasurface for electro-optic modulation of light polarization in the telecommunication band. High-Q quasi-bound states in the continuum are emploied to enhance the modulation of amplitude…

We apply high-energy proton ion-implantation to modify TiO2 nanotubes selectively at their tops. In the proton-implanted region we observe the creation of intrinsic co-catalytic centers for photocatalytic H2-evolution. We find proton…

The simultaneous condensation of electronic and structural degrees of freedom gives rise to new states of matter, including superconductivity and charge-density-wave formation. When exciting such a condensed system, it is commonly assumed…

We compute the electronic structure of two-dimensional (2D) materials decorated with self-assembled organic monolayers using density functional theory. We find that 2D materials are strongly impacted by near-field electrostatic effects…

Materials Science · Physics 2021-09-22 Qunfei Zhou , Bukuru Anaclet , Trevor Steiner , Michele Kotiuga , Pierre Darancet

Understanding the mechanism and developing strategies toward efficient electrocatalysis at gas-liquidsolid interfaces are important yet challenging. In the past decades, researchers have devoted many efforts to improving catalyst activity…

Applied Physics · Physics 2021-02-22 Yuting Luo , Sum Wai Chiang , Lei Tang , Zhiyuan Zhang , Fengning Yang , Qiangmin Yu , Baofu Ding , Bilu Liu

Substitutional doping with transition metals is carried out in the Lepidocrocite phase - the stable monolayer geometry of TiO$_2$, using density functional theory (DFT) methods. The doping is carried out at the differently coordinated O…

Materials Science · Physics 2024-10-14 Kati Asikainen , Matti Alatalo , Marko Huttula , S. Assa Aravindh

Titanium dioxide materials have been studied intensively and extensively due to photocatalytic applications. A long-standing open question is the energy band alignment of rutile and anatase TiO2 phases, which can affect the photocatalytic…

Materials Science · Physics 2015-11-10 Daoyu Zhang , Minnan Yang , Shuai Dong

Plasmonic metasurfaces play a crucial role in resonance-driven photocatalytic reactions by effectively enhancing reactivity via localized surface plasmon resonances. Catalytic activity can be selectively modulated by tuning the strength of…

Two-dimensional ferroelectrics with robust polarization offer promising opportunities for non-volatile memory, field-effect transistors, and optoelectronic devices. However, the impact of lattice deformation on polarization and photoinduced…

Materials Science · Physics 2025-06-02 Kun Yang , Jianxin Yu , Jia Zhang , Sheng Meng , Jin Zhang

Electric and thermoelectric properties of strictly monolayer MoS$_2$ films, which are grown using a novel micro-cavity based CVD growth technique, have been studied under diverse environmental and annealing conditions. Resistance of a…

Mesoscale and Nanoscale Physics · Physics 2020-09-16 Swarup Deb , Pritam Bhattacharyya , Poulab Chakrabarti , Himadri Chakraborti , Kantimay Das Gupta , Alok Shukla , Subhabrata Dhar

In this paper, density functional theory calculations are used to explore the electronic and atomic reconstruction at interfaces between III-III/I-V oxides. In particular, at these interfaces, two dimensional electron gases (2DEGs) with…

Materials Science · Physics 2012-06-06 Valentino R. Cooper

The full monolayer of pentacene adsorbed on rutile TiO$_2$(110) provides an intriguing model to study charge-transfer excitations where the optically excited electrons and holes reside on different sides of the internal interface between…

Materials Science · Physics 2016-10-07 M. P. Ljungberg , O. Vänskä , P. Koval , S. W. Koch , M. Kira , D. Sánchez-Portal