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We demonstrate a new type of transition within the strong coupling regime, which alters the coupling mechanism in multimode cavities. We show that this transition drastically modifies the Hamiltonian describing the polaritons, such that…

Mesoscale and Nanoscale Physics · Physics 2021-06-16 M. Balasubrahmaniyam , C. Genet , T. Schwartz

We show that when following a simple cavity design metric, a quantum well exciton-microcavity photon coupling constant can be larger than the exciton binding energy in GaAs based optical microcavities. Such a very strong coupling…

Quantum Physics · Physics 2018-06-25 H. Zhang , N. Y. Kim , Y. Yamamoto , N. Na

Intermolecular bonds are weak compared to covalent bonds, but they are strong enough to influence the properties of large molecular systems. In this work, we investigate how strong light-matter coupling inside an optical cavity can modify…

Chemical Physics · Physics 2021-03-17 Tor S. Haugland , Christian Schäfer , Enrico Ronca , Angel Rubio , Henrik Koch

Several years ago, it was shown that strong coupling between an electronic transition in organic molecules and a resonant photonic structure can modify the electronic landscape of the molecules and affect their chemical behavior. Since…

Understanding the radiative decay of exciton-polaritons is essential for achieving long-lived polaritons - a key prerequisite for enhancing nonlinear and quantum polaritonic effects. However, conventional wisdom - the coupled oscillator…

Optics · Physics 2025-09-01 Jiaxun Song , Li He , Bo Zhen

Molecular polaritons arise when molecules interact so strongly with light that they become entangled with each other. This light-matter hybridization alters the chemical and physical properties of the molecular system and allows chemical…

Chemical Physics · Physics 2023-07-28 Tor S. Haugland , John P. Philbin , Tushar K. Ghosh , Ming Chen , Henrik Koch , Prineha Narang

Strong light-matter coupling provides a versatile and novel means to manipulate chemical processes. Here we develop a theoretical framework to investigate the spectroscopy and dynamics of a molecular ensemble embedded in an optical cavity…

Quantum Physics · Physics 2023-06-16 Bing Gu

Microcavity polaritons are light-matter quasiparticles that arise from the strong coupling between excitons and photons confined in a semiconductor microcavity. They typically operate at visible or near visible wavelengths. They combine the…

Mesoscale and Nanoscale Physics · Physics 2020-11-06 Dmitry D. Solnyshkov , Guillaume Malpuech , Philippe St-Jean , Sylvain Ravets , Jacqueline Bloch , Alberto Amo

Recent experiments and theory demonstrate that the the ground state properties and chemical reactivity of molecules can be modified inside an optical cavity. The vibrational strong or ultrastrong coupling results in the formation of…

Chemical Physics · Physics 2022-12-01 Qi Yu

The strong coupling between molecules and photonic modes in a Fabry-P\'{e}rot optical cavity, which forms hybrid light-matter states called polaritons, has been demonstrated as a promising route to control the rates of chemical reactions.…

Quantum Physics · Physics 2025-05-22 Kunyang Sun , Matthew Du , Joel Yuen-Zhou

Light-matter interactions are known to lead to the formation of polariton states through what is called strong coupling, leading to the formation of two hybrid states usually tagged as Upper and Lower Polaritons. Here, we consider a similar…

Strong coupling between light and matter is possible with a variety of organic materials. In contrast to the simpler inorganic case, organic materials often have a complicated spectrum, with vibrationally dressed electronic transitions.…

Mesoscale and Nanoscale Physics · Physics 2018-02-02 M. Ahsan Zeb , Peter G. Kirton , Jonathan Keeling

Exciton-polaritons in semiconductor microcavities generate fascinating effects such as long-range spatial coherence and Bose-Einstein Condensation (BEC), which are attractive for their potential use in low threshold lasers, vortices and…

Mesoscale and Nanoscale Physics · Physics 2017-09-27 Shuai Zhang , Qiuyu Shang , Wenna Du , Jia Shi , Yang Mi , Jie Chen , Zhiyong Wu , Yuanzheng Li , Mei Liu , Qing Zhang , Xinfeng Liu

Band engineering stands as an efficient route to induce strongly correlated quantum many-body phenomena. Besides inspiring analogies among diverse physical fields, tuning on demand the group velocity is highly attractive in photonics…

We demonstrate that collective vibrational strong coupling of molecules in thermal equilibrium can give rise to significant local electronic polarizations in the thermodynamic limit. We do so by first showing that the full non-relativistic…

Recent years have seen significant developments in the study of strong light-matter coupling including the control of chemical reactions by altering the vibrational normal modes of molecules. In the vibrational strong coupling regime the…

Quantum Physics · Physics 2021-08-27 John Bonini , Johannes Flick

We present multi-mode deep-strong coupling in a multi-quantum well (N=166) heterostructure. The heterostructure itself acts as a Fabry-Perot cavity, for which the even cavity modes strongly couple to the cyclotron resonance to form Landau…

Synthetic materials are obtained by assembling atoms or artificial atoms into regular arrays, thereby forming artificial crystals that offer powerful platforms to emulate and explore condensed-matter phenomena in highly controlled settings.…

Mesoscale and Nanoscale Physics · Physics 2026-04-29 Sylvain Ravets

The experimental realization of strong light-matter coupling with molecules initiated the rapidly evolving field of molecular polaritonics. Most studies focus on how exciton polaritons, which combine electronic excitations with confined…

Chemical Physics · Physics 2025-09-10 Lucas Borges , Thomas Schnappinger , Markus Kowalewski

Engineering the properties of quantum materials via strong light-matter coupling is a compelling research direction with a multiplicity of modern applications. Those range from modifying charge transport in organic molecules, steering…