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Molecular complexes are held together via a variety of bonds, but they all share the common feature that their individual entities are in contact. In this work, we introduce and demonstrate the concept of a \textit{molecular optical bond},…

Mesoscale and Nanoscale Physics · Physics 2025-01-03 Jahangir Nobakht , André Pscherer , Jan Renger , Stephan Götzinger , Vahid Sandoghdar

Polaritons are quasiparticles resulting from strong quantum coupling of light and matter. Peculiar properties of polaritons are a mixture of physics usually restricted to one of these realms, making them interesting for study not only from…

Quantum Gases · Physics 2023-08-14 Andrzej Opala , Michał Matuszewski

Exciton-polaritons are hybrid elementary excitations of light and matter that, thanks to their nonlinear properties, enable a plethora of physical phenomena ranging from room temperature condensation to superfluidity. While polaritons are…

Mesoscale and Nanoscale Physics · Physics 2022-03-23 Davide Nigro , Vincenzo D'Ambrosio , Daniele Sanvitto , Dario Gerace

Strong light-matter coupling occurs when the coupling strength between a confined electromagnetic mode and a molecular resonance exceeds losses to the environment. The study of strong coupling has been motivated by applications such as…

Mesoscale and Nanoscale Physics · Physics 2022-04-27 Philip A. Thomas , Kishan S. Menghrajani , William L. Barnes

Cavity quantum electrodynamics advances the coherent control of a single quantum emitter with a quantized radiation field mode, typically piecewise engineered for the highest finesse and confinement in the cavity field. This enables the…

The central theme of cavity quantum electrodynamics is the coupling of a single optical mode with a single matter excitation, leading to a doublet of cavity polaritons which govern the optical properties of the coupled structure. Especially…

Exciton transport can be enhanced in the strong coupling regime where excitons hybridise with confined light modes to form polaritons. Because polaritons have group velocity, their propagation should be ballistic and long-ranged. However,…

Chemical Physics · Physics 2024-03-20 Ilia Sokolovskii , Ruth H. Tichauer , Dmitry Morozov , Johannes Feist , Gerrit Groenhof

In most theoretical descriptions of collective strong coupling of organic molecules to a cavity mode, the molecules are modeled as simple two-level systems. This picture fails to describe the rich structure provided by their internal…

Quantum Physics · Physics 2015-11-11 Javier Galego , Francisco J. Garcia-Vidal , Johannes Feist

We investigate the conditions yielding plasmon-exciton strong coupling at the single emitter level in the gap between two metal nanoparticles. A quasi-analytical transformation optics approach is developed that makes possible a thorough…

Mesoscale and Nanoscale Physics · Physics 2016-09-07 Rui-Qi Li , D. Hernangómez-Pérez , F. J. García-Vidal , A. I. Fernández-Domínguez

Plasmonic nanocavities enable the confinement of molecules and electromagnetic fields within nano-metric volumes. As a consequence, the molecules experience a remarkably strong interaction with the electromagnetic field, to such an extent…

Chemical Physics · Physics 2021-09-01 Jacopo Fregoni , Tor S. Haugland , Silvio Pipolo , Tommaso Giovannini , Henrik Koch , Stefano Corni

Recently, we predicted theoretically that in cavities that support several longitudinal modes, strong coupling can occur in very different manners, depending on the system parameters. Distinct longitudinal cavity modes are either entangled…

Quantum Physics · Physics 2023-10-10 M. Godsi , A. Golombek , M. Balasubrahmaniyam , T. Schwartz

Exciton-polaritons are quasiparticles with mixed photon and exciton character that demonstrate rich quantum phenomena, novel optoelectronic devices and the potential to modify chemical properties of materials. Organic semiconductors are of…

The concept of modifying molecular dynamics in strongly coupled exciton-polariton systems is an emerging topic in photonics due to its potential to produce customized chemical systems with tailored photophysical properties. However, before…

Materials Science · Physics 2020-10-09 Bin Liu , Vinod M. Menon , Matthew Y. Sfeir

We provide a simple method that enables readily acquired experimental data to be used to predict whether or not a candidate molecular material may exhibit strong coupling. Specifically, we explore the relationship between the hybrid…

Light-matter interactions can occur when an ensemble of molecular resonators is placed in a confined electromagnetic field. In the strong coupling regime the rapid exchange of energy between the molecules and the electromagnetic field…

Mesoscale and Nanoscale Physics · Physics 2020-08-10 Philip A. Thomas , Wai Jue Tan , Henry A. Fernandez , William L. Barnes

Cavity-polaritons in semiconductor photonic structures have emerged as a test bed for exploring non-equilibrium dynamics of quantum fluids in an integrated solid-state device setting. Several recent experiments demonstrated the potential of…

Mesoscale and Nanoscale Physics · Physics 2013-12-04 Benjamin Besga , Cyril Vaneph , Jakob Reichel , Jerome Esteve , Andreas Reinhard , Javier Miguel-Sanchez , Atac Imamoglu , Thomas Volz

Polariton chemistry has been hailed as a potential new route to direct molecular processes with electromagnetic fields. To make further strides, it is essential for the community to clarify which unusual polaritonic phenomena are true…

Chemical Physics · Physics 2025-11-19 Alexander M. McKillop , Marissa L. Weichman

Strong coupling between electronic excitations in materials and photon modes results in the formation of polaritons, which display larger nonlinearities than their photonic counterparts due to their material component. We theoretically…

Chemical Physics · Physics 2023-08-29 Sindhana Pannir-Sivajothi , Nathaniel P. Stern , Joel Yuen-Zhou

Strong light-matter interactions in both the single-emitter and collective strong coupling regimes attract significant attention due to emerging quantum and nonlinear optics applications, as well as opportunities for modifying…

Mesoscale and Nanoscale Physics · Physics 2019-09-11 Tuomas P. Rossi , Timur Shegai , Paul Erhart , Tomasz J. Antosiewicz

A light-matter hybrid quasiparticle, called a polariton, is formed when molecules are strongly coupled to an optical cavity. Recent experiments have shown that polariton chemistry can manipulate chemical reactions. Polariton chemistry is a…

Chemical Physics · Physics 2024-01-11 Xinyang Li , Nicholas Lubbers , Sergei Tretiak , Kipton Barros , Yu Zhang