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Highly charged ions (HCIs) are insensitive to external perturbations and are attractive for the development of ultrastable clocks. However, only a few HCI candidates are known to provide optical clock transitions. In this Letter, we show…

Atomic Physics · Physics 2025-01-07 Chunhai Lyu , Christoph H. Keitel , Zoltán Harman

We perform calculations of electronic structure of Cm$^{15+}$ and Bk$^{16+}$ ions and demonstrate that they have transitions which combine the features of atomic optical clocks with the enhanced sensitivity to the variations of the fine…

Atomic Physics · Physics 2024-02-21 V. A. Dzuba , V. V. Flambaum

We perform detailed calculations of the electronic structure of the Os$^{16+}$ ion and demonstrate that it has several metastable states which can be used for very accurate optical clocks. The clocks are highly sensitive to manifestations…

Atomic Physics · Physics 2024-02-21 V. A. Dzuba , V. V. Flambaum

The Ni$^{12+}$ ion features an electronic transition with a natural width of only 8 mHz, allowing for a highly stable optical clock. We predict that the energy of this strongly forbidden $3s^2 3p^4\, ^3\!P_2 \rightarrow 3s^2 3p^4 \,…

We compare two optical clocks based on the $^2$S$_{1/2}(F=0)\to {}^2$D$_{3/2}(F=2)$ electric quadrupole (E2) and the $^2$S$_{1/2}(F=0)\to {}^2$F$_{7/2}(F=3)$ electric octupole (E3) transition of $^{171}$Yb$^{+}$ and measure the frequency…

Atomic Physics · Physics 2021-01-08 R. Lange , N. Huntemann , J. M. Rahm , C. Sanner , H. Shao , B. Lipphardt , Chr. Tamm , S. Weyers , E. Peik

We present measurements of three distinctive state-(in)dependent wavelengths for the $^1\text{S}_{0}-^3\text{P}_{0}$ clock transition in $^{174}\text{Yb}$ atoms. Specifically, we determine two magic wavelengths at $652.281(21)\,$THz and…

We describe an optical atomic clock based on quantum-logic spectroscopy of the $^1$S$_0$ $\leftrightarrow$ $^3$P$_0$ transition in $^{27}$Al$^{+}$ with a systematic uncertainty of ${9.4 \times 10^{-19}}$ and a frequency stability of…

Optical lattice clocks are the prospective devices that can probe many subtle physics including temporal variation of the fine structure constant ($\alpha_e$). These studies necessitate high-precision measurements of atomic clock frequency…

Atomic Physics · Physics 2023-09-28 Zhi-Ming Tang , Yan-mei Yu , B. K. Sahoo , Chen-Zhong Dong , Yang Yang , Yaming Zou

Static dipole polarizabilities are calculated in the ground and metastable states of Sr$^+$, Ba$^+$ and Ra$^+$ using the relativistic coupled-cluster method. Trends of the electron correlation effects are investigated in these atomic ions.…

Atomic Physics · Physics 2015-05-14 B. K. Sahoo , R. G. E. Timmermans , B. P. Das , D. Mukherjee

We have calculated static and dynamic electric dipole (E1) polarizabilities ($\alpha_F$) of the hyperfine levels of the clock transition precisely in $^{133}$Cs. The scalar, vector, and tensor components of $\alpha_F$ are estimated by…

Atomic Physics · Physics 2024-02-09 A. Chakraborty , B. K. Sahoo

Peik and Tamm [Europhys. Lett. 61, 181 (2003)] proposed a nuclear clock based on the isomeric transition between the ground state and the first excited state of thorium-229. This transition was recognized as a potentially sensitive probe of…

Atomic Physics · Physics 2021-01-19 Pavel Fadeev , Julian C. Berengut , Victor V. Flambaum

We examine energy level-crossings of fine-structure (FS) levels in the heavier highly charged ions (HCIs) with $d^6$ and $d^8$ configurations. From the analysis, we find that some of these HCIs are tailor-made for atomic clocks with quality…

Atomic Physics · Physics 2023-07-28 Yan-mei Yu , B. K. Sahoo

We carry out relativistic many-body calculations of the static and dynamic dipole polarizabilities of the ground $6s^2 ^1S_0$ and the first excited $6s6p ^3P^o_0$ states of Yb. With these polarizabilities, we compute several properties of…

Atomic Physics · Physics 2015-05-13 V. A. Dzuba , A. Derevianko

In this work, the $4D_{3/2}|3,\pm2\rangle \rightarrow 4D_{5/2}|3,\pm2\rangle$ transition in the Nb$^{4+}$ ion is identified as a promising candidate for a terahertz (THz) atomic clock, with the transition frequency occurring at 56.0224 THz.…

Atomic Physics · Physics 2025-04-23 Jyoti , A. Chakraborty , Zhiyang Wang , Jia Zhang , Jingbiao Chen , Bindiya Arora , B. K. Sahoo

Motivated by the ideas of using cold alkaline earth atoms trapped in an optical lattice for realization of optical atomic clocks, we investigate theoretically the perturbative effects of atom-atom interactions on a clock transition…

Quantum Physics · Physics 2009-11-10 D. E. Chang , Jun Ye , M. D. Lukin

Optical clocks based on atoms and ions probe relativistic effects with unprecedented sensitivity by resolving time dilation due to atom motion or different positions in the gravitational potential through frequency shifts. However, all…

Quantum Physics · Physics 2026-04-22 Gabriel Sorci , Joshua Foo , Dietrich Leibfried , Christian Sanner , Igor Pikovski

In heavy atoms and ions, nuclear structure effects are significantly enhanced due to the overlap of the electron wave functions with the nucleus. This overlap rapidly increases with the nuclear charge $Z$. We study the energy level shifts…

Atomic Physics · Physics 2021-03-17 V. V. Flambaum , I. B. Samsonov , H. B. Tran Tan , A. V. Viatkina

Iridium ions near $4f$-$5s$ level crossings are the leading candidates for a new type of atomic clocks with a high projected accuracy and a very high sensitivity to the temporal variation of the fine structure constant $\alpha$. To identify…

Atomic Physics · Physics 2015-08-12 U. I. Safronova , V. V. Flambaum , M. S. Safronova

Spherically-symmetric ground states of alkali-metal atoms do not posses electric quadrupole moments. However, the hyperfine interaction between nuclear moments and atomic electrons distorts the spherical symmetry of electronic clouds and…

Atomic Physics · Physics 2016-01-13 Andrei Derevianko

We report on spectroscopy of the low-lying electronic transitions in $^{224}$Ra$^+$. The ion's low charge to mass ratio and convenient wavelengths make $^{224}$Ra$^+$ a promising optical clock candidate. We measured the frequencies of the…