Related papers: Enhancing Divalent Optical Atomic Clocks with the …

Accurate measurements of different transition frequencies between atomic levels of the electronic and hyperfine structure over time are used to investigate temporal variations of the fine structure constant $\alpha$ and the…

We apply relativistic many-body methods to compute static differential polarizabilities for transitions inside the ground-state hyperfine manifolds of monovalent atoms and ions. Knowing this transition polarizability is required in a number…

A theoretical study is performed for the excitation of a single atom localized in the center of twisted light modes. Here we present the explicit dependence of excitation rates on critical parameters, such as the polarization of light, its…

Optical atomic clocks using highly-charged ions hold an intriguing promise of metrology at the 19th significant figure. Here we study transitions within the $4f^{12}$ ground-state electronic configuration of highly charged ions. We consider…

In neutral atom optical clocks, the higher-order atomic polarizability terms lead to the clock transition frequency shift which is motion-state dependent and nonlinear with the optical lattice depth. We propose to use an auxiliary optical…

We investigate the leading systematic effects in ro-vibrational spectroscopy of the molecular hydrogen ions H2+ and HD+, in order to assess their potential for the realization of optical clocks that would be sensitive to possible variations…

By employing singles, doubles, and triples excitations within the relativistic coupled-cluster framework, we perform comprehensive calculations of a wide range of atomic properties for the Th$^{3+}$ ion. These properties are essential for…

We study the prospects of using the electric quadrupole transitions from the ground states of Cu, Ag and Au to the metastable state $^2{\rm D}_{5/2}$ as clock transitions in optical lattice clocks. We calculate lifetimes, transition rates,…

The influence of oscillating quadrupole fields on atomic energy levels is examined theoretically and general expressions for the quadrupole matrix elements are given. The results are relevant to any ion-based clock in which one of the clock…

We have developed a broadly-applicable approach that drastically increases the ability to accurately predict properties of complex atoms. We applied it to the case of Ir$^{17+}$, which is of particular interest for the development of novel…

We study the prospects of using transitions from the ytterbium ground state to metastable states $^3{\rm P}^{\rm o}_2$ at $E=19\,710.388~$cm$^{-1}$ and $4f^{13}5d6s^2\,(J=2)$ at $E=23\,188.518~$cm$^{-1}$ as clock transitions in an optical…

We propose a high-performance atomic clock based on the 1.81 PHz transition between the ground and first-excited state of doubly ionized lead. Utilizing an even isotope of lead, both clock states have $I=J=F=0$, where $I$, $J$, and $F$ are…

Level crossings in the ground state of ions occur when the nuclear charge Z and ion charge Z_ion are varied along an isoelectronic sequence until the two outermost shells are nearly degenerate. We examine all available level crossings in…

For the isotope $^{229}$Th we investigate the possibility of two-photon laser spectroscopy of the nuclear clock transition (148.38 nm) using intense monochromatic laser field at twice the wavelength (296.76 nm). Our estimates show that due…

Highly charged ions (HCIs) are promising candidates for the next generation of atomic clocks, owing to their tightly bound electron cloud, which significantly suppresses the common environmental disturbances to the quantum oscillator. Here…

There have been concerted efforts in recent years to realize the next generation of clocks using alkaline earth atoms in an optical lattice. Assuming that the atoms are independent, such a clock would benefit from a $\sqrt{N}$ enhancement…

Black-body radiation (BBR) shifts of $^3\!P_0-^1\!S_0$ clock transition in divalent atoms Cd and Zn are evaluated using accurate relativistic many-body techniques of atomic structure. Static polarizabilities of the clock levels and relevant…

Atomic quadrupole moments and hyperfine constants of the metastable $^2 D_{3/2, 5/2}$ states of Ca$^+$, Sr$^+$, Ba$^+$, Yb$^+$, and Hg$^+$ are calculated by the multiconfiguration Dirac-Hartree-Fock and relativistic…

We report here oscillator strengths, transition rates, branching ratios and lifetimes due to allowed transitions in potassium (K) atom. We evaluate electric dipole (E1) amplitudes using an all order relativistic many-body perturbation…

We propose 10 highly-charged ions as candidates for the development of next generation atomic clocks, quantum information, and search for $\alpha$-variation. They have long-lived metastable states with transition frequencies to the ground…