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Absorbed sunlight in a solar cell produces electrons and holes. But, at the open circuit condition, the carriers have no place to go. They build up in density and, ideally, they emit external fluorescence that exactly balances the incoming…

Optics · Physics 2013-08-02 Owen D. Miller , Eli Yablonovitch , Sarah R. Kurtz

The mechanism of electron-hole separation in organic solar cells is currently hotly debated. Recent experimental work suggests that these charges can separate on extremely short timescales (<100 fs). This can be understood in terms of…

Materials Science · Physics 2014-06-05 Samuel L Smith , Alex W Chin

Electrodeposited thin film cells have been fabricated with record-breaking efficiencies of 11.4%. This presentation examines conversion mechanisms in cells with a focus on the effect of CdS buffer layers using a range of complementary…

Mesoscale and Nanoscale Physics · Physics 2010-06-10 J. P. Connolly , Z. Djebbour , A. Darga , C. Bazin , D. Mencaraglia , M. Benosman , N. Bodereau , JF Guillemoles , D. Lincot , J. Kessler , N. Naghavi , J. Kurdi , O. Kerrec

Multiple exciton generation solar cells (MEGSCs) undergo low efficiency due to material imperfections such as nonradiative recombination This paper introduces alternative approaches for realizing photovoltaic (PV) devices similar to MEGSCs.…

Applied Physics · Physics 2021-04-15 Jongwon Lee

This paper proposes an analytical framework describing how initial capacity and resistance variability in parallel-connected battery cells may inflict additional variability or reduce variability while the cells age. We derive closed-form…

Systems and Control · Electrical Eng. & Systems 2023-10-17 Andrew Weng , Hamidreza Movahedi , Clement Wong , Jason B. Siegel , Anna Stefanopoulou

Two reciprocity theorems are important for fundamental understanding of the solar cell operation and applications to device evaluation: (1) the carrier-transport reciprocity connecting the dark-carrier injection with the short-circuit…

We report negative capacitance at low frequencies in organic semiconductor based diodes and show that it appears only under bipolar injection conditions. We account quantitatively for this phenomenon by the recombination current due to…

Chemical Physics · Physics 2007-07-07 E. Ehrenfreund , C. Lungenschmied , G. Dennler , H. Neugebauer , N. S. Sariciftci

With the rising demand for solar energy installation, there is a pressing need for utilities to regulate the voltages at the distribution level. In grids with high penetration of photovoltaic (PV) systems, voltage fluctuations can occur at…

Systems and Control · Computer Science 2016-12-08 Katherine Hughes

Photovoltaic (PV) cells have become one of the most promising renewable energy technologies. To make PV more competitive with incumbent technologies, higher power output densities are needed. One promising approach is to add bifaciality to…

Applied Physics · Physics 2019-03-25 Yubo Sun , Zhiguang Zhou , Reza Asadpour , Muhammad A. Alam , Peter Bermel

A design tool was formulated for optimizing the efficiency of inorganic, thin-film, photovoltaic solar cells. The solar cell can have multiple semiconductor layers in addition to antireflection coatings, passivation layers, and buffer…

Numerical Analysis · Mathematics 2024-09-23 Tom H. Anderson , Benjamin J. Civiletti , Peter Monk , Akhlesh Lakhtakia

The importance of considering near-field effects on photon recycling and spontaneous emission in a thermophotovoltaic device is investigated. Fluctuational electrodynamics is used to calculate external luminescence from a photovoltaic cell…

Optics · Physics 2017-08-02 John DeSutter , Rodolphe Vaillon , Mathieu Francoeur

Space charge effects can significantly degrade charge collection in organic photovoltaics (OPVs), especially in thick-film devices. The two main causes of space charge are doping and imbalanced transport. Although these are completely…

Applied Physics · Physics 2020-04-22 Sebastian Wilken , Oskar J. Sandberg , Dorothea Scheunemann , Ronald Österbacka

In this article, we investigate the effect of prolonged light exposure on silicon heterojunction solar cells. We show that, although light exposure systematicallyimproves solar cell efficiency in the case of devices using intrinsic and…

The physics of organic bulk heterojunction solar cells is studied within a six state model, which is used to analyze the factors that affect current-voltage characteristics, power-voltage properties and efficiency, and their dependence on…

Materials Science · Physics 2015-06-18 Mario Einax , Marcel Dierl , Philip R. Schiff , Abraham Nitzan

Interface recombination at the absorber buffer interface impedes the efficiency of a solar cell with an otherwise excellent absorber. The internal voltage or the quasi-Fermi level splitting (qFLs) measures the quality of the absorber.…

Efficient semi-transparent solar cells can trigger the adoption of building integrated photovoltaics. Halide perovskites are particularly suitable in this respect owing to their tunable bandgap. Main drawbacks in the development of…

Ternary organic solar cells (TOSC) are currently under intensive investigation, recently reaching a record efficiency of 17.1%. The origin of the device open-circuit voltage (VOC), already a multifaceted issue in binary OSC, is even more…

Applied Physics · Physics 2020-08-03 Vincent Lami , Yvonne J. Hofstetter , Julian F. Butscher , Yana Vaynzof

An isolated single-junction solar cell's temperature in outer space depends only on its radiation exchange with its environment. We consider a cell with zero emissivity below its bandgap and unity above it -- an idealization so far…

Applied Physics · Physics 2021-01-07 Ido Frenkel , Avi Niv

Organic solar cells (OSCs) are uniquely suited for semitransparent applications due to their adjustable absorption spectrum. However, most high-performance semitransparent cells reported to date are based on materials that have shown high…

Recently, significant progress in the development of III-V/Si dual-junction solar cells has been achieved. This not only boosts the efficiency of Si-based photovoltaic solar cells, but also offers the possibility of highly efficient green…

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