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The power conversion efficiencies (PCEs) of organic solar cells (OSCs) using non-fullerene acceptors (NFAs) have now reached 18%. However, this is still lower than inorganic solar cells, for which PCEs >20% are commonplace. A key reason is…
The Shockley-Queisser (S-Q) theory defines the thermodynamic upper limits for Jsc, Voc, FF, and efficiency of a solar cell. The classical calculation assumes an abrupt onset of absorption at the band-edge, perfect absorption for all…
A one-dimensional many-body model is established to mimic the charge distribution and dynamics in nonfullerene organic solar cells. Two essential issues are taken into account in the model: The alternating donor and acceptor structure and…
We re-examine solar emission of hidden photons gamma' (mass m) caused by kinetic mixing. We calculate the emission rate with thermal field theory methods and with a kinetic equation that includes "flavor oscillations" and photon absorption…
In polymer:fullerene solar cells, the origin of the losses in the field-dependent photocurrent is still controversially debated. We contribute to the ongoing discussion by performing photo-induced charge extraction measurements on…
We study the nonequilibrium steady state thermodynamics of a photodevice which can operate as a solar cell or a photoconductor, depending on the degree of asymmetry of the junction. The thermodynamic efficiency is captured by a single…
Photovoltaic energy conversion in photovoltaic cells has been analyzed by the detailed balance approach or by thermodynamic arguments. Here we introduce a network representation to analyze the performance of such systems once a suitable…
The efficiency of a solar cell is often limited by electron-hole recombination mediated by defect states within the band gap of the photovoltaic (PV) semiconductor. The Shockley-Read-Hall (SRH) model considers a static trap that can…
We present analytical relations for the dark recombination current of a $pn^+$ junction with positively charged columnar grain boundaries in the high defect density regime. We consider two defect state configurations relevant for positively…
We systematically investigate PM6:Y12 bulk-heterojunction solar cells with donor fractions ranging from 1% to 45%, linking morphology, charge transport, and recombination to device performance. Complementary structural and spectroscopic…
Many advanced solar cell concepts propose surpassing the Shockley Queisser (SQ) limit by introducing multiple quasi-Fermi level separations that are arranged in series and/or in parallel. Exceeding the SQ limit with any parallel arrangement…
Among silicon-based solar cells, heterojunction cells hold the world efficiency record. However, their market acceptance is hindered by an initial 0.5\% per year degradation of their open circuit voltage which doubles the overall cell…
We analysed self-consistently photoconversion efficiency of direct-gap A3B5 semicon-ductors based solar cells and optimised their main physical characteristics. Using gallium ar-senide (GaAs) as the example and new efficient optimization…
A 2-D photonic crystal was integrated experimentally into a thin-film crystalline-silicon solar cell of 1-{\mu}m thickness, after numerical optimization maximizing light absorption in the active material. The photonic crystal boosted the…
Selenium, the world's oldest photovoltaic material, has experienced a renaissance in research over the past decade, with certified solar cell efficiencies climbing from the historical record of 5% to breaking the 10% barrier. Its wide…
This paper addresses the influence of III-V nucleation routines on Ge substrates for the growth of high efficiency multijunction solar cells. Three exemplary nucleation routines with differences in thickness and temperature were evaluated.…
Solar cells are semiconductor devices that generate electricity through charge generation upon illumination. For optimal device efficiency, the photo-generated carriers must reach the electrical contact layers before they recombine. A deep…
Numerical simulation of a solar cell can provide various information that can be useful to maximize its power conversion efficiency (PCE). In that respect we carried out a set of numerical simulation using AFORS-HET simulation program.…
Although the power conversion efficiencies of organic solar cells (OSCs) have surpassed 20%, they still lag behind commercial inorganic solar cells and emerging perovskite solar cells. To bridge this efficiency gap, improving the fill…
Non-planar solar-cell devices have been promoted as a means to enhance current collection in absorber materials with charge-transport limitations. This work presents an analytical framework for assessing the ultimate performance of…