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We propose a model to explain the reduced bimolecular recombination rate found in state-of-the-art bulk heterojunction solar cells. When compared to the Langevin recombination, the experimentally observed rate is one to four orders of…

Materials Science · Physics 2009-08-09 C. Deibel , A. Wagenpfahl , V. Dyakonov

III-V materials show a wide range of gaps making them ideal for the design of high efficiency solar cells. This chapter reviews relevant growth methods and material properties of these materials and discusses methods of combining…

Materials Science · Physics 2013-01-08 James P. Connolly , Denis Mencaraglia

The analytical modelling of bulk and quantum well solar cells is reviewed. The analytical approach allows explicit estimates of dominant generation and recombination mechanisms at work in charge neutral and space charge layers of the cells.…

Mesoscale and Nanoscale Physics · Physics 2012-04-25 James P. Connolly

Solar cells are crucial for addressing global energy issues, with research focused on improving their efficiency. This study examines the impact of doping concentration gradients on solar cell performance. Doping involves adding impurities…

Applied Physics · Physics 2024-07-18 Jeonggyu Hwang

Suppressing charge recombination is key for organic solar cells to become commercial reality. However, there is still no conclusive picture of how recombination losses are influenced by the complex nanoscale morphology. Here, new insight is…

In photovoltaic diodes recombination of photogenerated electrons and holes is a major loss process. Biological light harvesting complexes (LHCs) prevent recombination via the use of cascade structures, which lead to spatial separation of…

Thin-film solar cells suffer from various types of recombination, of which leakage current usually dominates at lower voltages. Herein, we demonstrate first a three-order reduction of the shunt loss mechanism in planar methylammonium lead…

Photon recycling is required for a solar cell to achieve an open-circuit voltage ($V_{OC}$) and power conversion efficiency (PCE) approaching the Shockley-Queisser theoretical limit. In metal halide perovskite solar cells, the achievable…

Applied Physics · Physics 2019-07-17 Roberto Brenes , Madeleine Laitz , Joel Jean , Dane W. deQuilettes , Vladimir Bulovic

The Shockley equation (SE), originally derived to describe a p--n junction, was frequently used in the past to simulate current--voltage (j/V) characteristics of organic solar cells (OSC). In order to gain a more detailed understanding of…

Materials Science · Physics 2012-09-06 A. Foertig , J. Rauh , V. Dyakonov , C. Deibel

Ever science the invention of solar cells, thermodynamics has been used to assess their performance limits, guiding advances in materials science and photovoltaic technology to reduce the gap between the practical efficiencies and the…

Applied Physics · Physics 2023-06-07 Like Huang

The thermodynamic limit for the efficiency of solar cells is predominantly defined by the energy bandgap of the used semiconductor. In case of organic solar cells both energetics and kinetics of three different species play role: excitons,…

Applied Physics · Physics 2021-07-02 Oskar J Sandberg , Ardalan Armin

Reverse biasing triple-junction GaInP/Ga(In)As/Ge solar cells may affect their performance by the formation of permanent shunts even if the reverse breakdown voltage is not reached. In previous works, it was observed that, amid the three…

Due to their tailorable optical properties, organic semiconductors show considerable promise for use in indoor photovoltaics (IPVs), which present a sustainable route for powering ubiquitous "Internet-of-Things" devices in the coming…

Understanding and quantifying the main loss factors affecting the power conversion efficiency of perovskite solar cells are urgently needed. In this work, based on semiconductor physics, the expressions of bulk and surface recombination…

Mesoscale and Nanoscale Physics · Physics 2021-03-23 Ting Xu , Zi-Shuai Wang , Xuan-Hua Li , Wei E. I. Sha

A modified detailed balance model is built to understand and quantify efficiency loss of perovskite solar cells. The modified model captures the light-absorption dependent short-circuit current, contact and transport-layer modified carrier…

The results of our researches of the influence of exponentially distributed surface centers on the effective surface recombination rate and the parameters of silicon solar cells (SCs) are reported. In our calculations, we assumed the…

Materials Science · Physics 2013-04-30 V. P. Kostylyov , A. V. Sachenko , I. O. Sokolovskyi , V. V. Chernenko , T. V. Slusar , A. V. Sushyi

Hot carrier solar cells promise theoretical power conversion efficiencies far beyond the single junction limit. However, practical implementations of hot carrier solar cells have lagged far behind those theoretical predictions. Reciprocity…

The theoretical maximum efficiency of a solar cell is typically characterized by a detailed balance of optical absorption and emission for a semiconductor in the limit of unity radiative efficiency and an ideal step-function response for…

Applied Physics · Physics 2021-03-09 Joeson Wong , Stefan T. Omelchenko , Harry A. Atwater

Electric coupling between subcells of a monolithically grown multijunction solar cell in short circuit allows their simultaneous and independent characterization by means of photo- and electroreflectance. The photovoltage generated by…

Applied Physics · Physics 2019-04-11 D. Fuertes Marrón , E. Barrigón , M. Ochoa , I. Artacho

Organic photovoltaics are a promising solar cell technology well-suited to mass production using roll-to-roll processes. The efficiency of lab-scale solar cells has exceeded 20% and considerable attention is currently being given to…