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In order to estimate the reactivity of a large number of potentially complex heterogeneous catalysts while searching for novel and more efficient materials, physical as well as data-centric models have been developed for a faster evaluation…

Materials Science · Physics 2021-06-28 Lucas Foppa , Luca M. Ghiringhelli

The development of active catalysts for hydrogen evolution reaction (HER) made from low-cost materials constitutes a crucial challenge in the utilization of hydrogen energy. Earth-abundant molybdenum disulfide (MoS$_2$) has been discovered…

Materials Science · Physics 2021-09-23 S. Wei , S. Baek , H. Yue , S. Yun , S. Park , Y. Lee , J. Zhao , H. Li , K. Reyes , F. Yao

Single-atom catalysts (SACs) with metal-nitrogen-carbon (M-N-C) structures are widely recognized as promising candidates in oxygen reduction reactions (ORR). According to the classical Sabatier principle, optimal 3d metal catalysts, such as…

Chemical Physics · Physics 2026-04-21 Di Zhang , Fangxin She , Jiaxiang Chen , Li Wei , Hao Li

Current research efforts on single-atom catalysts (SACs) exclusively focus on nonmetal or transition-metal atoms as active centers, while employing main-group metal elements is seemingly excluded because their delocalized s/p-bands are…

Materials Science · Physics 2021-11-18 Qian Wu , Baibiao Huang , Ying Dai , Thomas Heine , Yandong Ma

A novel oxygen evolution reaction (OER) catalyst (3D S235-P steel) based on steel S235 substrate has been successfully prepared via a facile one-step surface modification. The standard Carbon Manganese steel was phosphorizated superficially…

NiFe oxyhydroxide is one of the most promising oxygen evolution reaction (OER) catalysts for renewable hydrogen production, and deciphering the identity and reactivity of the oxygen intermediates on its surface is a key challenge but is…

Materials Science · Physics 2020-10-01 Yaming Hao , Yefei Li , Jianxiang Wu , Jinling Wang , Chenglin Jia , Tao Liu , Xuejing Yang , Zhipan Liu , Ming Gong

Molybdenum Disulfide (MoS$_2$) has been recognized as a potential substitution of Platinum (Pt) for electrochemical hydrogen evolution reaction (HER). However, the broad adoption of MoS$_2$ is hindered by its limited number of active sites…

Chemical Physics · Physics 2021-09-27 Sichen Wei , Yu Fu , Huamin Li , Fei Yao

Understanding O2 bubble nucleation and growth during the oxygen evolution reaction (OER) is crucial to comprehend their influences on catalytically active sites in the process. To achieve this goal, mapping the spatial variation of…

Mesoscale and Nanoscale Physics · Physics 2025-11-18 Nataraju Bodappa , Gregory Jerkiewicz , Peter Grutter

Facing with grave climate change and enormous energy demand, catalyzer gets more and more important due to its significant effect on reducing fossil fuels consumption. Hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) by…

Materials Science · Physics 2023-09-07 Yuan Chang , Panlong Zhai , Jungang Hou , Jijun Zhao , Junfeng Gao

The hydrogen evolution reaction (HER) is central to sustainable hydrogen production, and nitrogen coordinated dual atom catalysts (DACs) offer a promising route to noble metal activity at low cost. Yet their vast compositional and…

Perovskite oxides are promising catalysts for oxygen evolution reaction (OER), yet the huge chemical space remains largely unexplored due to the lack of effective approaches. Here, we report the distilling of accurate descriptors from…

Materials Science · Physics 2023-05-26 Jingzhou Wang , Huachao Xie , Yuanqing Wang , Runhai Ouyang

We describe a first-principles statistical mechanics approach enabling us to simulate the steady-state situation of heterogeneous catalysis. In a first step density-functional theory together with transition-state theory is employed to…

Materials Science · Physics 2007-05-23 Karsten Reuter , Matthias Scheffler

The development of machine learning models for electrocatalysts requires a broad set of training data to enable their use across a wide variety of materials. One class of materials that currently lacks sufficient training data is oxides,…

Designing electrocatalysts for HER in alkaline conditions to overcome the sluggish kinetics associated with the additional water dissociation step is a recognized challenge in promoting the hydrogen economy. To this end, delicately tuning…

The exploration of advanced CO-free catalysts and clarifying the ambiguous kinetic origins and governing factors would undoubtedly open up opportunities to overcome the sluggish kinetics of methanol electrooxidation and promote the…

Chemical Physics · Physics 2025-12-15 Lecheng Liang , Hengyu Li , Shao Ye , Peng Li , Kaiyang Xu , Jinhui Liang , Binwen Zeng , Bo Shen , Taisuke Ozaki , Zhiming Cui

The requirements for beneficial materials restructuring into a higher performance OER electrocatalyst are still a largely open question. Here we use Erythrite (Co$_3$(AsO$_4$)$_2\cdot$8H$_2$O) as a Co-based OER electrocatalyst to evaluate…

Electrochemical water electrolysis, which produces clean energy carriers to mitigate carbon emissions, lacks suitable, low-cost electrodes for efficient oxygen evolution reaction (OER) in alkaline water splitting. To address this challenge,…

Few-layered potassium nickel and cobalt oxides show drastic differences in catalytic activity based on metal ion preorganization. Uniform compositions $[(\mathrm{CoO}_2/\mathrm{K})_6$ or $(\mathrm{NiO}_2/\mathrm{K})_6]$ show limited…

Electrocatalysts for the oxygen evolution reaction (OER) are an important component for the transition from fossil to sustainable energy. Commercialization of cost-effective earth-abundant electrocatalysts is in large parts hindered by…

Chemical Physics · Physics 2022-10-31 Marcel Risch

The development of next-generation molecular simulation models requires moving beyond pre-defined functional forms toward machine learning (ML) techniques that directly capture multiscale physics. Here, we demonstrate such an approach using…