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The effect of elastic strains on the catalytic activity for the hydrogen evolution reaction (HER) and the oxygen reduction reaction (ORR) was analyzed on thirteen late transition metals: eight (111) surfaces of fcc metals (Ni, Cu, Pd, Ag,…

Materials Science · Physics 2022-03-09 Carmen Martínez-Alonso , José Manuel Guevara-Vela , Javier LLorca

MXenes are a class of 2D/layered materials which are highly conductive, hydrophilic, have a large electrochemical surface area and are easily processible into electrodes for energy applications. Since the discovery of MXenes over ten years…

Chemical Physics · Physics 2022-12-22 Michelle P. Browne , Daire Tyndall , Valeria Nicolosi

Development of cost-effective hydrogen evolution reaction (HER) catalysts with outstanding catalytic activity, replacing cost-prohibitive noble metal-based catalysts, is critical for practical green hydrogen production. A popular strategy…

A comprehensive understanding of the electrode-electrolyte interface in energy conversion systems remains challenging due to the complex and multifaceted nature of interfacial processes. This complexity hinders the development of more…

Chemical Physics · Physics 2024-10-23 Ben Wang , Tomohiro Fukushima , Hiro Minamimoto , Andrey Lyalin , Kei Murakoshi , Tetsuya Taketsugu

Single-atom catalysts are considered as a promising method for efficient energy conversion, owing to their advantages of high atom utilization and low catalyst cost. However, finding a stable two-dimensional structure and high hydrogen…

Materials Science · Physics 2023-09-08 Wei Xun , Xin Liu , Qing-Song Jiang , Xiao Yang , Yin-Zhong Wu , Ping Li

The development of efficient and cost-effective catalysts for clean energy conversion remains a central challenge in materials science. Although platinum serves as the benchmark catalyst, its scarcity and high cost hinder large-scale…

We present a density functional theory study of the oxygen reduction reaction (ORR) on a single atom catalyst embedded in graphene, namely, TM-N$_{4}$-C (TM = Fe and Co), using the effective screening medium method combined with the…

Materials Science · Physics 2024-02-28 Azim Fitri Zainul Abidin , Ikutaro Hamada

Single-atom catalysts (SACs) have emerged as frontiers for catalyzing chemical reactions, yet the diverse combinations of active elements and support materials, the nature of coordination environments, elude traditional methodologies in…

Materials Science · Physics 2024-02-07 Haoyu Yang , Juanli Zhao , Qiankun Wang , Bin Liu , Wei Luo , Ziqi Sun , Ting Liao

Hydrogen production via the Hydrogen Evolution Reaction (HER) is critical for sustainable energy solutions, yet the reliance on expensive platinum (Pt) catalysts limits scalability. Zirconium-doped (\ce{Zr}-doped) MXenes, such as \ce{Ti3C2}…

Materials Science · Physics 2025-01-28 Shrestha Dutta , Rudra Banerjee

Electrochemical water splitting is an environmentally friendly technology to store renewable energy in the form of chemical fuels. Among the earth-abundant first-row transition metal-based catalysts, mixed Ni-Fe oxides have shown promising…

The correlation between ex situ electronic conductivity, oxygen vacancy content, flat-band potential (Efb), and the oxygen evolution reaction (OER) activity for a wide range of perovskite compositions are investigated experimentally and…

MXenes with versatile chemistry and superior electrical conductivity are prevalent candidate materials for energy storage and catalysts. Inspired by recent experiments of hybridizing MXenes with carbon materials, here we theoretically…

Materials Science · Physics 2018-05-14 Si Zhou , Xiaowei Yang , Wei Pei , Nanshu Liu , Jijun Zhao

Electrocatalytic water splitting, which produces hydrogen and oxygen through water electrolysis, is a promising method for generating renewable, carbon-free alternative fuels. However, its widespread adoption is hindered by the high costs…

Materials Science · Physics 2024-12-23 Kajjana Boonpalit , Nongnuch Artrith

The field of single atom catalysis (SAC) has expanded greatly in recent years. While there has been much success developing new synthesis methods, a fundamental disconnect exists between most experiments and the theoretical computations…

Materials Science · Physics 2022-09-12 Florian Kraushofer , Gareth S. Parkinson

The rational design of bifunctional electrocatalysts for the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is essential for achieving efficient and cost-effective overall water splitting. Atomically dispersed…

Materials Science · Physics 2026-05-04 Jiahang Li , Suhang Li , Chong Yan , Jiajun Yu , Qinzhuang Liu , Ruo-Ya Wang , Dongwei Ma

The electrocatalytic CO2 reduction reaction (CO2RR) is a complex multi-proton-electron transfer process that generates a vast network of reaction intermediates. Accurate prediction of free energy changes (G) of these intermediates and…

Chemical Physics · Physics 2025-04-23 Xuxin Kang , Wenjing Zhou , Ziyuan Li , Zhaoqin Chu , Hanqin Yin , Shan Gao , Aijun Du , Xiangmei Duan

The efficiency of $H_2$ production via water electrolysis is typically limited to the sluggish oxygen evolution reaction (OER). As such, significant emphasis has been placed upon improving the rate of OER through the anode catalyst. More…

Although rutile RuO2 has been a well-known and almost the best oxygen evolution reaction (OER) catalyst, the OER properties for the similar rutile oxide OsO2 with the same group element with Ru have been unknown, mainly due to long-standing…

Efficient and selective CO2 electroreduction into value-added chemicals and fuels emerged as a significant approach for CO2 conversion, however, it relies on catalysts with controllable product selectivity and reaction paths. In this work,…

Mesoscale and Nanoscale Physics · Physics 2022-10-26 Wei Xun , Xiao Yang , Qing-Song Jiang , Ming-Jun Wang , Yin-Zhong Wu , Ping Li

Inter-site interactions between single atom catalysts (SACs) in the high loading regime are critical to tuning the catalytic performance. However, the understanding on such interactions and their distance dependent effects remains elusive,…

Chemical Physics · Physics 2022-01-19 Tong Yang , Jun Zhou , Xiaoyang Ma , Keda Ding , Kay Chen Tan , Ge Wang , Haitao Huang , Ming Yang