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We utilized a simple, robust, first principle method, based on basis set optimization with the BZW-EF method, to study the electronic and related properties of transition metal mono-nitrides: ScN and YN. We solved the KS system of equations…

Materials Science · Physics 2012-09-04 C. E. Ekuma , D. Bagayoko , M. Jarrell , J. Moreno

The strongly constrained and appropriately normed (SCAN) meta-generalized gradient approximation (meta-GGA) functional is a milestone achievement of electronic structure theory. Recently, a revised and restored form (r$^2$SCAN) has been…

Materials Science · Physics 2026-03-18 Adonis Haxhijaj , Stefan Riemelmoser , Alfredo Pasquarello

Using density functional theory, we study the influence of hydrostatic pressure on the crystal structure of lanthanide monoxides, focusing on the monoxides formed by the fifteen elements of the lanthanide series, from La to Lu. Calculations…

Materials Science · Physics 2026-04-14 Sergio Ferrari , Daniel Errandonea

We have investigated the electronic structures of various potentially half-metallic Heusler compounds with the Tran-Blaha modified Becke-Johnson (TB-mBJLDA) potential within the density functional theory. The half-metallic gaps are…

Materials Science · Physics 2013-05-30 Markus Meinert

We have performed x-ray absorption spectroscopy (XAS) and x-ray photoemission spectroscopy (XPS) studies of single crystal Ba_{1-x}K_{x}BiO_{3} (BKBO) covering the whole composition range $0 \leq x \leq 0.60$. Several features in the oxygen…

Superconductivity · Physics 2009-10-31 K. Kobayashi , T. Mizokawa , A. Ino , J. Matsuno , A. Fujimori , H. Samata , A. Mishiro , Y. Nagata , F. M. F. de Groot

Two Dimensional (2D) Transition Metal Dichalcogenides (TMDs) possess a large direct band gap which has been experimentally observed to shrink with increasing charge carrier density (doping). The effect has been the subject of theoretical…

Mesoscale and Nanoscale Physics · Physics 2025-01-16 Jack N. Engdahl , Harley D. Scammell , Dmitry K. Efimkin , Oleg P. Sushkov

We report the computational investigation of a series of ternary X$_4$Y$_2$Z and X$_5$Y$_2$Z$_2$ compounds with X={Mg, Ca, Sr, Ba}, Y={P, As, Sb, Bi}, and Z={S, Se, Te}. The compositions for these materials were predicted through a search…

Materials Science · Physics 2019-04-03 Maximilian Amsler , Logan Ward , Vinay I. Hegde , Maarten G. Goesten , Xia Yi , Chris Wolverton

We discuss possible topological phase transitions in Ge-based thin films of Ge(Bi$_x$Sb$_{1-x}$)$_2$Te$_4$ as a function of layer thickness and Bi concentration $x$ using the first principles density functional theory framework. The bulk…

Mesoscale and Nanoscale Physics · Physics 2014-02-12 Bahadur Singh , Hsin Lin , R. Prasad , A. Bansil

Optical measurements under externally applied stresses allow us to study the materials' electronic structure by comparing the pressure evolution of optical peaks obtained from experiments and theoretical calculations. We examine the…

We report density-functional-theory calculations of the electronic band structures and optical absorption spectra of two-dimensional crystals of Ga$_2$X$_2$ (X=S, Se, and Te). Our calculations show that all three two-dimensional materials…

Mesoscale and Nanoscale Physics · Physics 2018-01-09 V. Zólyomi , N. D. Drummond , V. I. Fal'ko

The electronic structure of the zincblende $\beta$-HgS is not well understood. Previous first-principles calculations using fully-relativistic density functional theory and many-body perturbation theory in the fully-relativistic $GW$…

Materials Science · Physics 2022-03-31 Bradford A. Barker , Steven G. Louie

Computationally-efficient semilocal approximations of density functional theory at the level of the local spin density approximation (LSDA) or generalized gradient approximation (GGA) poorly describe weak interactions. We show improved…

In this work, the energy band structures of BGaN and BAlN alloys are systematically studied through first-principles calculation using HSE hybrid density functional theory by MedeA-VASP. Direct-indirect bandgap transition of BGaN alloys at…

Applied Physics · Physics 2020-05-19 Che-Hao Liao , Feras AlQatari , Xiaohang Li

Mn3TeO6 (MTO) has been experimentally found to adopt a P21/n structure under high pressure, which exhibits a significantly smaller band gap compared to the atmospheric R-3 phase. In this study, we systematically investigate the magnetism,…

Materials Science · Physics 2024-07-23 Xiao-Long Pan , Hao Wang , Lei Liu , Xiang-Rong Chen , Hua Y. Geng

Using first-principles calculations we show that the band gap of bilayer sheets of semiconducting transition metal dichalcogenides (TMDs) can be reduced smoothly by applying vertical compressive pressure. These materials undergo a universal…

Materials Science · Physics 2015-06-04 Swastibrata Bhattacharyya , Abhishek K. Singh

Transition metal monochalcogenides comprise a class of two-dimensional materials with electronic band gaps that are highly sensitive to material thickness and chemical composition. Here, we explore the tunability of the electronic…

The ground state equilibrium properties of copper-gold alloys have been explored with the state of art random phase approximation (RPA). Our estimated lattice constants agree with the experiment within a mean absolute percentage error…

Materials Science · Physics 2019-07-31 Niraj K. Nepal , Santosh Adhikari , Jefferson E. Bates , Adrienn Ruzsinszky

The electronic band structures of two-dimensional materials are significantly different from those of their bulk counterparts, due to quantum confinement and strong modifications of electronic screening. An accurate determination of…

Mesoscale and Nanoscale Physics · Physics 2020-07-08 Tomáš Rauch , Miguel A. L. Marques , Silvana Botti

The band alignment in ZnO/GaN and related heterostructures are crucial for the uses in solar harvesting technology. Here, we report our density functional calculations of the band alignment and optical properties of ZnO/GaN and…

Materials Science · Physics 2017-08-23 Zhenhai Wang , Mingwen Zhao , Xiaopeng Wang , Yan Xi , Xiujie He , Xiangdong Liu , Shishen Yan

We construct a Laplacian-level meta-generalized gradient approximation (meta-GGA) for the non-interacting (Kohn-Sham orbital) positive kinetic energy density $\tau$ of an electronic ground state of density $n$. This meta-GGA is designed to…

Materials Science · Physics 2015-06-25 John P. Perdew , Lucian A. Constantin
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