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We demonstrate, on the basis of molecular dynamics simulations, the possibility of an efficient water-ethanol separation using nanoporous carbon membranes, namely carbon nanotube membranes, nanoporous graphene sheets, and multilayer…

Soft Condensed Matter · Physics 2016-09-28 Simon Gravelle , Hiroaki Yoshida , Laurent Joly , Christophe Ybert , Lydéric Bocquet

Electrochemical conversion of CO2 (CO2R) into fuels and chemicals can both reduce CO2 emissions and allow for clean manufacturing in the scenario of significant expansion of renewable power generation. However, large-scale process…

Chemical Physics · Physics 2021-02-17 Magda H. Barecka , Joel W. Ager , Alexei A. Lapkin

Development of highly sensitive, portable and low-cost sensors for the evaluation of ethanol content in liquid is particularly important in several process monitoring, from food to pharmaceutical industry. In this respect, here we report on…

Materials Science · Physics 2021-10-27 Angelo Leo , Anna Grazia Monteduro , Silvia Rizzato , Angelo Milone , Giuseppe Maruccio

Electrochemical CO2 reduction offers a method to use renewable electricity to convert CO2 into CO and other carbon-based chemical building blocks. While nearly all studies rely on a CO2 feed, we show herein that aqueous bicarbonate…

The process of CO2 valorization, all the way from capture of CO2 to its electrochemical upgrade, requires significant inputs in each of the capture, upgrade, and separation steps. The gas phase CO2 feed following the capture-and-release…

The search for earth abundant, efficient and stable electrocatalysts that can enable the chemical reduction of CO2 to value-added chemicals and fuels at an industrially relevant scale, is a high priority for the development of a global…

We analyse a device aimed at the conversion of heat into electrical energy, based on a closed cycle in which a distiller generates two solutions at different concentrations, and an electrochemical cell consumes the concentration difference,…

Chemical Physics · Physics 2022-09-14 Andrea Carati , Massimo Marino , Doriano Brogioli

Determination of the volume content of ethanol in the alcohol products in practice is usually determined by pycnometry, electronic densimetry, or densimetry using a hydrostatic balance in accordance with Commission Regulation No 2870/2000.…

Chemical Physics · Physics 2014-01-23 Siarhei Charapitsa , Nikita Kulevich , Svetlana Sytova , Yurii Yakuba

Results of systematic molecular dynamics studies of ethanol-water mixtures, over the entire concentration range, were reported previously to agree with experimental X-ray diffraction data. These simulated systems are analyzed in this work…

Soft Condensed Matter · Physics 2017-09-14 Orsolya Gereben , László Pusztai

The use of aqueous electrolytes in energy storage devices is traditionally limited by the voltage stability window of water at 1.23 V. We present the use of a microemulsion based electrolyte which, although mostly water by mass, has a…

Chemical Physics · Physics 2020-11-10 Fraser R. Hughson , Rohan Borah , Thomas Nann

Effective water management is essential for the optimal performance of PEM fuel cells. We have developed an impedance model for liquid water transport through the membrane and coupled it with the two-phase model for cathode side impedance.…

Chemical Physics · Physics 2026-01-16 Andrei Kulikovsky , Tatyana Reshetenko

Here we design, construct, and characterize a compact Raman-spectroscopy-based sensor that measures the concentration of a water-methanol mixture. The sensor measures the concentration with an accuracy of 0.5% and a precision of 0.2% with a…

Instrumentation and Detectors · Physics 2018-08-16 Daniel D. Hickstein , Russell Goldfarmmuren , Jack Darrah , Luke Erickson , Laura A. Johnson

A continuous CO2 vapor-fed electrochemical cell prototype that performs CO2R with high faradaic efficiency for desired carbon products for up to 72 hours of operation is presented. The cell design facilitates a flow through configuration,…

Materials Science · Physics 2020-10-23 Ashley Cronk , David Larson , Francesca M. Toma

Electrochemical CO2 reduction (CO2R) offers a promising approach to decarbonize chemical manufacturing through production of carbon-neutral fuels. However, insufficient performance and instability of membrane electrode assembly (MEA)…

An extremely efficient ethanol fuel cell electrode is produced by combining the large surface area of vertically oriented and highly conductive few-layer graphene sheets with electrochemically deposited palladium nanoparticles. The…

Chemical Physics · Physics 2016-10-18 Michael Höltig , Charlotte Ruhmlieb , Tobias Kipp , Alf Mews

Efficient and sustainable techniques for separating water-methanol mixtures are in high demand in the industry. Recent studies have revealed that membranes and 2D materials could achieve such separation. In our research, we explore the…

Soft Condensed Matter · Physics 2023-06-28 Roger Bellido-Peralta , Fabio Leoni , Carles Calero , Giancarlo Franzese

This study investigates the behavior of microbubbles generated by the local heating of an ethanol/water mixture and the surrounding flow. The mixture is photothermally heated by focusing a continuous-wave laser on a FeSi$_2$ thin film.…

Fluid Dynamics · Physics 2024-05-21 Mizuki Kato , Kyoko Namura , Shinya Kawai , Samir Kumar , Kaoru Nakajima , Motofumi Suzuki

Dissociation of CO$_2$ on copper surfaces, a model system for understanding the elementary steps in catalytic conversion of CO$_2$ to methanol has been extensively studied in the past. It is thought to be reasonably well-understood from…

Chemical Physics · Physics 2024-01-30 Saurabh Kumar Singh , Pranav R. Shirhatti

Underground carbon dioxide ($CO_2$) sequestration is considered to be one of the main methods to mitigate greenhouse gas (GHG) emissions. In this technology, pure $CO_2$ is injected into an underground geological formation and since it is…

Fluid Dynamics · Physics 2019-12-24 Federico Cao , Dmitry Eskin , Yuri Leonenko

Membrane-based CO$_2$ removal from exhaust streams has recently gained much attention as a means of reducing emissions and limiting climate change. Novel membranes for CO$_2$ removal include so called facilitated transport membranes (FTMs),…

Soft Condensed Matter · Physics 2023-08-02 M. Logemann , J. Gujt , T. Harhues , T. D. Kühne , M. Wessling
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