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A new process for obtaining the ethyl esters of volatile fatty acids with ethanol by using aluminium chloride hexahydrate as a catalyst is proposed. Aluminium chloride not only exhibits good activity, composition equilibrium is achieved…

Chemical Physics · Physics 2020-03-18 Luigi di Bitonto , Sandro Menegatti , Carlo Pastore

The evaporation of a binary sessile ethanol-water droplet on an inclined substrate is studied experimentally just below the critical sliding angles for different substrate temperatures. A customized goniometer equipped with a CMOS camera…

Although photoelectrochemical water splitting is likely to be an important and powerful tool to provide environmentally friendly hydrogen, most developments in this field have been conducted on a laboratory scale so far. In order for the…

An extensive series of neutron diffraction experiments and molecular dynamics simulations has shown that mixtures of methanol and water exhibit extended structures in solution despite the components being fully miscible in all proportions.…

Soft Condensed Matter · Physics 2009-11-10 L. Dougan , S. P. Bates , R. Hargreaves , J. P. Fox , J. Crain , J. L. Finney , V. Reat , A. K. Soper

Cobalt-porphyrin catalyzed reductive decomposition of CO2 to CO is investigated based on Koper's water facilitated CO2 reduction mechanism using a simple but accurate protocol based on thermodynamics. In our protocol, accurate predictions…

Mesoscale and Nanoscale Physics · Physics 2019-05-06 Kaito Miyamoto , Ryoji Asahi

Electro-oxidation of ethanol represents a key process in fuel-cells technology. We introduce a generalization of the random sequential adsorption model to study the long timescale and large length scale properties of the electro-oxidation…

Statistical Mechanics · Physics 2012-05-15 Cristóvão S. Dias , Nuno A. M. Araújo , António Cadilhe

As pretrained transformer language models continue to achieve state-of-the-art performance, the Natural Language Processing community has pushed for advances in model compression and efficient attention mechanisms to address high…

Computation and Language · Computer Science 2023-11-27 Nathan Brown , Ashton Williamson , Tahj Anderson , Logan Lawrence

In the study, the evaporation of ethanol-water binary mixture within heated capillary is experimentally and numerically investigated. It was found that the ratio of the evaporation rates of ethanol and water equals the ratio of their…

Fluid Dynamics · Physics 2024-01-17 Jialing Yu , Zhenhai Pan

Wicking is a widely studied process in both natural and artificial systems. In many industrial applications, such as heat pipes, the wicking liquid evaporates to regulate temperature effectively. This study focuses on a simpler scenario…

Fluid Dynamics · Physics 2025-02-19 Rampally Srirama Chandra Murthy , Navneet Kumar

The efficiency of the conversion of CO$_2$ into CO with nanosecond repetitively pulsed discharges (NRP) is investigated in a high pressure batch reactor. Stable discharges are obtained at up to 12~bar. By-products of CO$_2$ splitting are…

Plasma Physics · Physics 2022-11-02 Erwan pannier , Taemin Yong , Christophe Laux , Mark A. Cappelli

Electrochemical water splitting technology for producing "green hydrogen" is important for the global mission of carbon neutrality. Electrocatalysts with decent performance at high current densities play a central role in the industrial…

Chemical Physics · Physics 2022-02-16 Yuting Luo , Zhiyuan Zhang , Manish Chhowalla , Bilu Liu

Water electrolysis is promising for industrial hydrogen production to achieve a sustainable and green hydrogen economy, but the high cost of the technology limits its market share. Developing efficient yet economic electrocatalysts is…

Alcohol Use Disorder (AUD) is a prevalent addictive disorder affecting an estimated 29.5 million Americans. It is characterized by impaired control over alcohol consumption despite negative consequences. The number of diagnostic criteria…

Quantitative Methods · Quantitative Biology 2026-05-21 Alexander Pozhitkov , Douglas Ramsay , Peter A Noble

Environmental molecular beam experiments are used to examine water interactions with liquid methanol films at temperatures from 170 K to 190 K. We find that water molecules with 0.32 eV incident kinetic energy are efficiently trapped by the…

Photoelectrochemical (PEC) water splitting offers an elegant approach for solar energy conversion into hydrogen fuel. Large-scale hydrogen production requires stable and efficient photoelectrodes and scalable PEC cells that are fitted for…

Due to the low conductivity of pure water, using an electrolyte is common for achieving efficient water electrolysis. In this paper, we have broken through this common sense by using deep-sub-Debye-length nanogap electrochemical cells for…

Chemical Physics · Physics 2016-11-16 Yifei Wang , S. R. Narayanan , Wei Wu

We apply first principles computational techniques to analyze the two-electron, multi-step, electrochemical reduction of CO2 to CO in water using cobalt porphyrin as a catalyst. Density Functional Theory calculations with hybrid functionals…

Chemical Physics · Physics 2011-01-06 Kevin Leung , Ida M. B. Nielsen , Na Sai , Craig J. Medforth , J. A. Shelnutt

The renewable energy sector critically needs low-cost and environmentally neutral energy storage solutions throughout the entire device life cycle. However, the limited performance of standard water-based electrochemical systems prevents…

Dataset distillation compresses the original data into compact synthetic datasets, reducing training time and storage while retaining model performance, enabling deployment under limited resources. Although recent decoupling-based…

Computer Vision and Pattern Recognition · Computer Science 2026-02-20 Muhammad J. Alahmadi , Peng Gao , Feiyi Wang , Dongkuan Xu

The structure and dynamics of aqueous solvation of ethanol and ethylene are studied by DFT-based Car-Parrinello molecular dynamics. We did not find an enhancement of the structure of the hydrogen bonded network of hydrating water molecules.…

Chemical Physics · Physics 2009-11-07 Titus S. van Erp , Evert Jan Meijer