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We investigate theoretically quantum entanglement of light with the collective spin polarization of a cold atomic ensemble in cavity-assisted Raman schemes. Previous works concentrated mostly on the bad cavity limit where the signals are…

Quantum Physics · Physics 2019-08-21 N. I. Masalaeva , A. N. Vetlugin , I. V. Sokolov

The dynamical behavior of a coupled cavity array is investigated when each cavity contains a three-level atom. For the uniform and staggered intercavity hopping, the whole system Hamiltonian can be analytically diagonalized in the subspace…

Quantum Physics · Physics 2012-02-28 Yu-Li Dong , Shi-Qun Zhu , Wen-Long You

We investigate the entanglement dynamics of two atoms interacting with a single-mode cavity field within the Tavis-Cummings model in the presence of noise. The atoms are initially prepared in either pure Bell states or mixed Werner states,…

Quantum Physics · Physics 2026-01-05 Koushik Mandal , M. V. Satyanarayana

In this work, we propose performing key operations in quantum computation and communication using room-temperature atoms moving across a grid of high-quality-factor, small-mode-volume cavities. These cavities enable high-cooperativity…

Proton transfer is ubiquitous in many fundamental chemical and biological processes, and the ability to modulate and control the proton transfer rate would have a major impact on numerous quantum technological advances. One possibility to…

Chemical Physics · Physics 2021-12-07 Fabijan Pavošević , Sharon Hammes-Schiffer , Angel Rubio , Johannes Flick

We analyze the quantum Zeno dynamics that takes place when a field stored in a cavity undergoes frequent interactions with atoms. We show that repeated measurements or unitary operations performed on the atoms probing the field state…

Recently the quantum nature in the energy transport in solar cell and light-harvesting complexes have attracted much attention, as being triggered by the experimental observations. We model the light-harvesting complex (i.e., PEB50 dimer)…

Chemical Physics · Physics 2015-03-05 Zhedong Zhang , Jin Wang

Molecular complexes are held together via a variety of bonds, but they all share the common feature that their individual entities are in contact. In this work, we introduce and demonstrate the concept of a \textit{molecular optical bond},…

Mesoscale and Nanoscale Physics · Physics 2025-01-03 Jahangir Nobakht , André Pscherer , Jan Renger , Stephan Götzinger , Vahid Sandoghdar

The modification of thermal chemical rates in Fabry-Perot cavities, as observed in experiments, still poses theoretical challenges. While we have a better grasp of how the reactivity of isolated molecules and model systems changes under…

Chemical Physics · Physics 2023-08-08 Jing Sun , Oriol Vendrell

The interaction of an ensemble of $N$ two-level atoms with a single mode electromagnetic field is described by the Tavis-Cummings model. There, the collectively enhanced light-matter coupling strength is given by $g_N = \sqrt{N} \bar{g}_1$,…

Quantum Physics · Physics 2022-02-09 Martin Blaha , Aisling Johnson , Arno Rauschenbeutel , Jürgen Volz

The quantum dynamics of an externally driven ensemble of nuclear two-level systems embedded in a leaky broadband cavity is investigated theoretically. In the considered scenario both the nuclear ensemble and the cavity mode are coherently…

Quantum Physics · Physics 2026-04-14 Mihai A. Macovei , Fabian Richter , Adriana Pálffy

The ability to control chemical reactions by coupling organic molecules to confined light in a cavity has recently attracted much attention. While most previous studies have focused on single-mode photonic or plasmonic cavities, here we…

Chemical Physics · Physics 2025-09-10 Anael Ben-Asher , Thomas Schnappinger , Markus Kowalewski , Johannes Feist

We investigate the energy structures and the dynamics of a Bose-Einstein condensates (BEC) in a triple-well potential coupled a high finesse optical cavity within a mean field approach. Due to the intrinsic atom-cavity field nonlinearity,…

Quantum Gases · Physics 2012-07-13 Lei Tan , Bin Wang , Peter Barker , Wu-Ming Liu

Polaritonic chemistry offers the possibility of modifying molecular properties and even influencing chemical reactivity through strong coupling between vibrational transitions and confined light modes in optical cavities. Despite…

Chemical Physics · Physics 2025-05-16 Thomas Schnappinger , Markus Kowalewski

We consider dissipative atom-cavity systems and show that their collective dynamics leads to the maximization of entanglement for intermediate values of the cavity leakage parameter $\kappa$. We discuss possible ways the reservoir…

Quantum Physics · Physics 2009-11-13 Biplab Ghosh , A. S. Majumdar , N. Nayak

In most theoretical descriptions of collective strong coupling of organic molecules to a cavity mode, the molecules are modeled as simple two-level systems. This picture fails to describe the rich structure provided by their internal…

Quantum Physics · Physics 2015-11-11 Javier Galego , Francisco J. Garcia-Vidal , Johannes Feist

We studied the interaction of a two-level atom with a frequency modulated cavity mode in an ideal optical cavity. The system, described by a Jaynes-Cumming Hamiltonian, gave rise to a set of stiff nonlinear first order equations solved…

Quantum Physics · Physics 2013-01-22 U. Pishipati , I. Almakremi , Amitabh Joshi , Juan D. Serna

We propose a system for observing the correlated phase dynamics of two mesoscopic ensembles of atoms through their collective coupling to an optical cavity. We find a dynamical quantum phase transition induced by pump noise and cavity…

Quantum Physics · Physics 2024-12-02 Minghui Xu , D. A. Tieri , E. C. Fine , James K. Thompson , M. J. Holland

The use of quantum light to probe exciton properties in semiconductor and molecular nanostructures typically occurs in the low-intensity regime. A substantial enhancement of exciton-photon coupling can be achieved with photonic cavities,…

Cavity polaritonics is capturing the imagination of the chemistry community because of the novel opportunities it creates to direct chemistry. Electron transfer (ET) reactions are among the simplest reactions, and they also underpin…

Quantum Physics · Physics 2022-08-12 Sutirtha N. Chowdhury , Peng Zhang , David N. Beratan