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Collectively coupling molecular ensembles to a cavity has been demonstrated to modify chemical reactions akin to catalysis. Theoretically understanding this experimental finding remains to be an important challenge. In particular the role…

Quantum Physics · Physics 2022-06-16 David Wellnitz , Guido Pupillo , Johannes Schachenmayer

Achieving control over chemical reaction's rate and stereoselectivity realizes one of the Holy Grails in chemistry that can revolutionize chemical and pharmaceutical industries. Strong light-matter interaction in optical or nanoplasmonic…

Chemical Physics · Physics 2022-11-29 Fabijan Pavošević , Robert L. Smith , Angel Rubio

Intermolecular van der Waals interactions are central to chemical and physical phenomena ranging from biomolecule binding to soft-matter phase transitions. However, there are currently very limited approaches to manipulate van der Waals…

In this work we look at the quantum dynamics of the process known as either transport without transit (TWT), or coherent transfer of atomic population (CTAP), of a Bose-Einstein condensate from one well of a lattice potential to another,…

Quantum Physics · Physics 2015-06-18 M. K. Olsen

We propose an optomechanical scheme for reaching quantum entanglement in vibration polaritons. The system involves $N$ molecules, whose vibrations can be fairly entangled with plasmonic cavities. We find that the vibration-photon…

Quantum Physics · Physics 2024-05-28 Jian Huang , Dangyuan Lei , Girish S. Agarwal , Zhedong Zhang

Dynamic coupling of cavities to a quantum network is of major interest to distributed quantum information processing schemes based on cavity quantum electrodynamics. This can be achieved by active tuning a mediating atom-cavity system. In…

Quantum Physics · Physics 2013-05-29 Chun-Hsu Su , Andrew D. Greentree , William J. Munro , Kae Nemoto , Lloyd C. L. Hollenberg

We study the dynamics of a quantum dot embedded in a three-dimensional microcavity in the strong coupling regime in which the quantum dot exciton has an energy close to the frequency of a confined cavity mode. Under the continuous pumping…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 J. I. Perea , D. Porras , C. Tejedor

In this paper we study the dynamics in the general case for a Tavis Cummings atom in a non-uniform cavity. In addition to the dynamical Stark shift, the center-of-mass motion of the atom and the recoil effect are considered in both - the…

Quantum Physics · Physics 2015-05-28 L. Chotorlishvili , Z. Toklikishvili , S. Wimberger , J. Berakdar

Cavity quantum electrodynamics (cavity QED) describes the coherent interaction between matter and an electromagnetic field confined within a resonator structure, and is providing a useful platform for developing concepts in quantum…

We report on the fast excitation of a single atom coupled to an optical cavity using laser pulses that are much shorter than all other relevant processes. The cavity frequency constitutes a control parameter that allows the creation of…

Quantum Physics · Physics 2008-12-03 J. Bochmann , M. Muecke , G. Langfahl-Klabes , C. Erbel , B. Weber , H. P. Specht , D. L. Moehring , G. Rempe

While the emerging field of vibrational polariton chemistry has the potential to overcome traditional limitations of synthetic chemistry, the underlying mechanism is not yet well understood. Here, we explore how the dynamics of unimolecular…

Chemical Physics · Physics 2021-11-16 Derek S Wang , Tomáš Neuman , Susanne F Yelin , Johannes Flick

We propose a scheme of enhancement of Rabi coupling between two identical atomic ensembles trapped inside an optical cavity in a membrane-in-the-middle set up. The cavity modes dispersively interact with the ensembles and the effective…

Quantum Physics · Physics 2017-03-08 Anil K. Chauhan , Asoka Biswas

Dressing quantum states of matter with virtual photons can create exotic effects ranging from vacuum-field modified transport to polaritonic chemistry, and may drive strong squeezing or entanglement of light and matter modes. The…

Quantum Physics · Physics 2023-09-14 J. Mornhinweg , L. Diebel , M. Halbhuber , M. Prager , J. Riepl , T. Inzenhofer , D. Bougeard , R. Huber , C. Lange

An optical cavity enhances the interaction between atoms and light, and the rate of coherent atom-photon coupling can be made larger than all decoherence rates of the system. For single atoms, this strong coupling regime of cavity quantum…

Quantum Physics · Physics 2007-11-10 Yves Colombe , Tilo Steinmetz , Guilhem Dubois , Felix Linke , David Hunger , Jakob Reichel

We show here that the photonic states emitted by ensembles of multilevel atoms via a superradiance process exhibit entanglement in the modal (frequency) degree of freedom, making this collective emission process a favorable candidate for a…

Quantum Physics · Physics 2025-07-01 Amir Sivan , Meir Orenstein

In the regime of ensemble vibrational strong coupling (VSC), a macroscopic number $N$ of molecular transitions couple to each resonant cavity mode, yielding two hybrid light-matter (polariton) modes, and a reservoir of $N-1$ dark states…

Chemical Physics · Physics 2020-04-03 Jorge Campos-Gonzalez-Angulo , Raphael F. Ribeiro , Joel Yuen-Zhou

We show that two qubits can be entangled by local interactions with an entangled two-mode continuous variable state. This is illustrated by the evolution of two two-level atoms interacting with a two-mode squeezed state. Two modes of the…

Quantum Physics · Physics 2009-11-07 W. Son , M. S. Kim , Jinhyoung Lee , D. Ahn

We prepare a maximally entangled state of two ions and couple both ions to the mode of an optical cavity. The phase of the entangled state determines the collective interaction of the ions with the cavity mode, that is, whether the emission…

Quantum Physics · Physics 2015-03-19 B. Casabone , K. Friebe , B. Brandstätter , K. Schüppert , R. Blatt , T. E. Northup

Collective strong coupling of molecular ensembles to optical cavities opens a route to modifying matter through genuinely collective electronic correlations. Yet even in the absence of a cavity, Coulomb correlations are notoriously…

Quantum Physics · Physics 2026-05-05 Dominik Sidler , Michael Ruggenthaler , Angel Rubio

When molecular transitions strongly couple to photon modes, they form hybrid light-matter modes called polaritons. Collective vibrational strong coupling is a promising avenue for control of chemistry, but this can be deterred by the large…

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