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Surface-enhanced Raman spectroscopy (SERS) demands reliable, high enhancement substrates in order to be used in different fields of application. Here, we introduce freestanding porous gold membranes (PAuM) as easy to produce, scalable,…

Nanofibers functionalized by metal nanostructures and particles are exploited as effective flexible substrates for SERS analysis. Their complex three-dimensional structure may provide Raman signals enhanced by orders of magnitude compared…

Materials Science · Physics 2016-03-16 A. Camposeo , D. Spadaro , D. Magrì , M. Moffa , P. G. Gucciardi , L. Persano , O. M. Maragò , D. Pisignano

Regular arrays of metal nanoparticles on metal films have tuneable optical resonances that can be applied for surface enhanced Raman scattering or biosensing. With the aim of developing more surface selective geometries we investigate…

Mesoscale and Nanoscale Physics · Physics 2012-09-13 Andreas Hohenau , Joachim R. Krenn

Integrating graphene with plasmonic nanostructures results in multifunctional hybrid systems with enhanced performance for numerous applications. In this work, we take advantage of the remarkable mechanical properties of graphene to combine…

We report plasmon-enhanced Raman scattering in graphene coupled to a single plasmonic hotspot measured as a function of laser energy. The enhancement profiles of the G peak show strong enhancement (up to $10^5$) and narrow resonances (30…

The scattering of lattice excitations (phonons) with the photoexcited charge carriers is of a major concern in optoelectronic devices. Here, the resonant Raman scattering will be utilized to study an exciton-phonon interaction in GaN…

Engineered electromagnetic fields in plasmonic nanopores enable enhanced optical detection and their use in single molecule sequencing. Here, a plasmonic nanopore prepared in a thick nanoporous film is used to investigate the interaction…

Surface Plasmon Resonance sensors are a well-established class of sensors which includes a very large variety of materials and detection schemes. However, the development of portable devices is still challenging as due to the intrinsic…

Graphene covered metal nanoparticles constitute a novel type of hybrid materials, which provide a unique platform to study plasmonic effects, surface-enhanced Raman scattering (SERS), and metal-graphene interactions at the nanoscale. Such a…

Low-frequency Raman scattering experiments have been performed on thin films consisting of nickel-silver composite nanoparticles embedded in alumina matrix. It is observed that the Raman scattering by the quadrupolar modes, strongly…

Condensed Matter · Physics 2007-05-23 H. Portales , L. Saviot , E. Duval , M. Gaudry , E. Cottancin , M. Pellarin , J. Lerme , M. Broyer

Surface enhanced Raman spectroscopy, is a technique of fundamental importance to analytical science and technology where the amplified Raman spectrum of analytes is used for chemical fingerprinting. Here, we showcase an engineered…

Applied Physics · Physics 2021-06-08 K N Prajapati , Anoop A Nair , S Ravi P Silva , J Mitra

We theoretically investigate several types of plasmonic slot waveguides for enhancing the measured signal in Raman spectroscopy, which is a consequence of electric field and Purcell factor enhancements, as well as an increase in…

Raman scattering is a chemically selective probing mechanism with diverse applications in industry and clinical settings. Yet, most samples are optically opaque limiting the applicability of Raman probing at depth. Here, we demonstrate…

This study examines the Raman scattering and charge transfer properties of molecules adsorbed on the surface of a tetrahedral Au$_{120}$ nanoparticle based on the time-dependent density functional tight-binding (TD-DFTB) method. We study…

Chemical Physics · Physics 2024-09-18 Sajal Kumar Giri , George C. Schatz

The use of graphene in surface plasmon resonance sensors, covering a metallic (plasmonic) film, has a number of demonstrated advantages, such protecting the film against corrosion/oxidation and facilitating the introduction of functional…

Mesoscale and Nanoscale Physics · Physics 2022-10-26 Aline dos S. Almeida , D. A. Bahamon , Nuno M. R. Peres , Christiano J. S. de Matos

We study Raman scattering in active media placed in proximity of different types of metal nanostructures, at wavelengths that display either Fabry-Perot or plasmonic resonances, or a combination of both. We use a semi-classical approach to…

Optics · Physics 2015-06-05 M. Scalora , M. A. Vincenti , D. de Ceglia , M. Grande , J. W. Haus

Generalizing recent work, the Raman scattering intensity from a semi-infinite superconducting superlattice is calculated taking into account the surface contribution to the density response functions. Our work makes use of the formalism of…

Condensed Matter · Physics 2009-10-28 W. C. Wu , A. Griffin

Tunability of the surface plasmon resonance wavelength is demonstrated by varying the thickness of Al2O3 spacer layer inserted between the graphene and nanoparticles. By varying the spacer layer thickness from 0.3 to 1.8 nm, the resonance…

Materials Science · Physics 2015-06-11 Jing Niu , Young Jun Shin , Youngbin Lee , Jong-Hyun Ahn , Hyunsoo Yang

We have investigated the effects of tuning the localized surface plasmon resonances (LSPRs) of silver nanoparticles on the fluorescence intensity, lifetime, and Raman signal from nearby fluorophores. The presence of a metallic structure can…

Other Condensed Matter · Physics 2009-11-13 N. I. Cade , T. Ritman-Meer , D. Richards

In this paper we theoretically show that the Raman scattering by a core-shell micron or submicron particle with epsilon-near-zero metamaterial shell and silica spherical or cylindrical core can combine useful features of cavity-enhanced and…

Optics · Physics 2013-05-29 Constantin R. Simovski
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