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Under the local plasmonic excitation, the Raman images of a single molecule can now reach sub-nanometer resolution. We report here a theoretical description of the interaction between a molecule and a highly confined plasmonic field. It is…

Mesoscale and Nanoscale Physics · Physics 2015-08-06 Sai Duan , Guangjun Tian , Yongfei Ji , Jiushu Shao , Zhenchao Dong , Yi Luo

The observation and electrical manipulation of infrared surface plasmons in graphene have triggered a search for similar photonic capabilities in other atomically thin materials that enable electrical modulation of light at visible and…

Mesoscale and Nanoscale Physics · Physics 2017-02-08 F. Javier Garcia de Abajo , Alejandro Manjavacas

Light scattering limits the penetration depth of non-invasive Raman spectroscopy in biological media. While safe levels of irradiation may be adequate to analyze superficial tissue, scattering of the pump beam reduces the Raman signal to…

Transient absorption and Raman scattering measurements on noble metal nanoparticles offer complimentary information on their vibrational modes and mechanical interactions with their surroundings. We have developed a comprehensive modeling…

Mesoscale and Nanoscale Physics · Physics 2024-10-29 Rachel Gelfand , Matthew Pelton

Localized surface plasmon resonances possess very interesting properties for a wide variety of sensing applications. In many of the existing applications only the intensity of the reflected or transmitted signals is taken into account,…

The surface-enhanced Raman scattering in graphene deposited on AlxGa1-xN/GaN axial heterostructure nanowires was investigated. The intensity of graphene Raman spectra was found not to be correlated with aluminium content. Analysis of…

Surface enhanced Raman spectra from molecules (bipyridyl ethylene) adsorbed on gold dumbells are observed to become increasingly asymmetric (Fano-like) at higher incident light intensity. The electronic temperature (inferred from the…

Mesoscale and Nanoscale Physics · Physics 2016-01-12 S. Dey , M. Banik , E. Hulkko , K. Rodriguez , V. A. Apkarian , M. Galperin , A. Nitzan

Raman scattering signal can be enhanced through localization of incident field into sub-wavelength hot-spots through plasmonic nano-structures (Surface-enhanced Raman scattering-SERS). Recently, further enhancement of SERS signal via…

A tri-layer metamaterial perfect absorber of light, consisting of (Al/ZnS/Al) films with the top aluminium layer patterned as an array of circular disk nanoantennas, is investigated for resonantly enhancing Raman scattering from C-60…

Optics · Physics 2018-11-02 Sriram Guddala , Narayanarao Desai , S. Anantha Ramakrishna

We study the role of strong electron confinement in surface-enhanced Raman scattering from molecules adsorbed on small noble-metal particles. We describe a new source of Raman signal enhancement which originates from different behavior of…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Vitaliy N. Pustovit , Tigran V. Shahbazyan

Raman spectroscopy reveals chemically specific information and provides label-free insight into the molecular world. However, the signals are intrinsically weak and call for enhancement techniques. Here, we demonstrate Purcell enhancement…

Raman spectroscopic studies of graphene have attracted much interest. The G-band Raman intensity of a single layer graphene on Si substrate with 300 nm SiO2 capping layer is surprisingly strong and is comparable to that of bulk graphite. To…

Materials Science · Physics 2009-11-13 Yingying Wang , Zhenhua Ni , Zexiang Shen , Haomin Wang , Yihong Wu

The combination of graphene with noble-metal nanostructures is currently being explored for strong light-graphene interaction enhanced by plasmons. We introduce a novel hybrid graphene-metal system for studying light-matter interactions…

Mesoscale and Nanoscale Physics · Physics 2013-10-10 Xiaolong Zhu , Lei Shi , Michael S. Schmidt , Anja Boisen , Ole Hansen , Jian Zi , Sanshui Xiao , N. Asger Mortensen

For distances less 10 nm, a total energy transfer occurs from a quantum emitter to a nearby metallic surface, producing evanescent surface waves that are plasmonic in nature. When investigating a metallic nanohole supported on an optically…

Optics · Physics 2019-07-16 Amir Djalalian-Assl

Nanoporous gold can be exploited as plasmonic material for enhanced spectroscopy both in the visible and in the near infrared spectral regions. In particular, with respect to bulk metal it presents interesting optical properties in the…

Applied Physics · Physics 2019-10-02 Eugenio Calandrini , Giorgia Giovannini , Denis Garoli

We report modifications to the optical properties of fluorophores in the vicinity of noble metal nanotips. The fluorescence from small clusters of quantum dots has been imaged using an apertureless scanning near-field optical microscope.…

Other Condensed Matter · Physics 2008-04-28 N. I. Cade , F. Culfaz , L. Eligal , T. Ritman-Meer , F-M. Huang , F. Festy , D. Richards

We couple photoluminescent semiconducting 7-atom wide armchair edge graphene nanoribbons to plasmonic nanoantenna arrays and demonstrate an enhancement of the photoluminescence and Raman scattering intensity of the nanoribbons by more than…

A plasmonic nanostructure-based substrate, serving as a surface-enhanced Raman scattering (SERS) substrate, enhances the Raman scattering of molecules. By employing an electron beam lithography followed by our recently developed…

We report an investigation of perovskite-type LaNiO3 thin films by Raman scattering in both various scattering configurations and as a function of temperature. The room-temperature Raman spectra and the associated phonon mode assignment…

Materials Science · Physics 2010-07-30 N. Chaban , M. Weber , S. Pignard , J. Kreisel

Surface enhanced Raman scattering (SERS) effects on tin dioxide in the form of bulk material, nanostructured thin films and colloidal solutions were investigated. Raman spectra are characterized by the three Raman scattering peaks at 478,…

Materials Science · Physics 2015-06-03 Enza Fazio , Fortunato Neri , Salvatore Savasta , Salvatore Spadaro , Sebastiano Trusso