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Vertically stacked layers derived from non-ferroelectric monolayers offer a promising route to two-dimensional (2D) ferroelectrics, where polarization switching occurs via interlayer sliding at sub-unit cell scales. Here, we develop a…

Materials Science · Physics 2025-03-03 Byeoksong Lee , Minki Lee , Joongoo Kang

Two-dimensional (2D) ferroelectric semiconductors present opportunities for integrating ferroelectrics into high-density ultrathin nanoelectronics. Among the few synthesized 2D ferroelectrics, $\alpha$-In$_2$Se$_3$, known for its…

Materials Science · Physics 2024-02-29 Liyi Bai , Changming Ke , Zhongshen Luo , Tianyuan Zhu , Lu You , Shi Liu

The control of unconventional magnetism, which displays ferromagnetism-like properties with compensated magnetization, has drawn intense attention for advancing antiferromagnetic spintronics. Here, through symmetry analysis, we propose a…

Materials Science · Physics 2025-07-15 Yongqian Zhu , Mingqiang Gu , Yuntian Liu , Xiaobing Chen , Yuhui Li , Shixuan Du , Qihang Liu

When the atomic layers in a non-centrosymmetric van der Waals structure slide against each other, the interfacial charge transfer results in a reversal of the structures spontaneous polarization. This phenomenon is known as sliding…

Ferroelectricity and metallicity are usually believed not to coexist because conducting electrons would screen out static internal electric fields. In 1965, Anderson and Blount proposed the concept of 'ferroelectric metal', however, it is…

Materials Science · Physics 2020-09-22 Xing-Yu Ma , Hou-Yi Lyu , Kuan-Rong Hao , Yi-Ming Zhao , Xiaofeng Qian , Qing-Bo Yan , Gang Su

The bistability of charge polarization in ferroelectric materials has long been the basis of ferroelectric devices. However, the ferroelectricity tends to be vanishing as the thickness of materials is reduced to a few nanometers or thinner…

Materials Science · Physics 2023-12-22 Guoliang Yu , Shengxian Li , Anlian Pan , Mingxing Chen , Zhenyu Zhang

The realization of multiferroics in nanostructures, combined with a large electric dipole and ferromagnetic ordering, could lead to new applications, such as high-density multi-state data storage. Although multiferroics have been broadly…

Materials Science · Physics 2018-04-18 Chengxi Huang , Yongping Du , Haiping Wu , Hongjun Xiang , Kaiming Deng , Erjun Kan

Ferroelectric HfO2 is a promising candidate for next-generation memory devices due to its CMOS compatibility and ability to retain polarization at nanometer scales. However, the polar orthorhombic phase (Pca2_1) responsible for…

Materials Science · Physics 2026-03-27 Jian Huang , Gwan Yeong Jung , Pravan Omprakash , Guodong Ren , Xin Li , Du Li , Xiaoshan Xu , Li Yang , Rohan Mishra

Ferroelectricity can exist in elemental phases as a result of charge transfers between atoms occupying inequivalent Wyckoff positions. We investigate the emergence of ferroelectricity in two-dimensional elemental materials with buckled…

Two-dimensional (2D) altermagnetism was recently proposed to be attainable in twisted antiferromagnetic bilayers providing an experimentally feasible approach to realize it in 2D materials. Nevertheless, a comprehensive understanding of the…

Materials Science · Physics 2024-09-17 Baoru Pan , Pan Zhou , Pengbo Lyu , Huaping Xiao , Xuejuan Yang , Lizhong Sun

Ferroelectricity is usually found in compound materials composed by different elements. Here, based on first-principles calculations, we reveal the first example of spontaneous electrical polarization and ferroelectricity in stable…

Materials Science · Physics 2017-06-20 Chengcheng Xiao , Fang Wang , Shengyuan A. Yang , Yunhao Lu

The discovery of two-dimensional (2D) ferroelectrics with switchable out-of-plane polarization such as monolayer $\alpha$-In$_2$Se$_3$ offers a new avenue for ultrathin high-density ferroelectric-based nanoelectronics such as ferroelectric…

Materials Science · Physics 2021-12-01 Jing Wu , Liyi Bai , Jiawei Huang , Liyang Ma , Jian Liu , Shi Liu

Ferroelectricity (Valasek, J. Phys. Rev. 1921, 17, 475) - a spontaneous formation of electric polarisation - is a solid state phenomenon, usually, associated with ionic compounds or complex materials. Here we show that, atypically for…

Materials Science · Physics 2023-05-29 Aitor Garcia-Ruiz , Vladimir Enaldiev , Andrew McEllistrim , Vladimir I. Fal'ko

Diverse interlayer tunability of physical properties of two-dimensional layers mostly lies in the covalent-like quasi-bonding that is significant in electronic structures but rather weak for energetics. Such characteristics result in…

Materials Science · Physics 2019-04-03 Peiheng Jiang , Cong Wang , Dachuan Chen , Zhicheng Zhong , Zhe Yuan , Zhong-Yi Lu , Wei Ji

Proximity ferroelectricity has recently been reported as a new design paradigm for inducing ferroelectricity, where a non-ferroelectric polar material becomes a ferroelectric by interfacing with a thin ferroelectric layer. Strongly polar…

Ferroelectric films usually have phase states and physical properties very different from those of bulk ferroelectrics. Here we propose free-standing ferroelectric-elastic multilayers as a bridge between these two material systems. Using a…

Materials Science · Physics 2011-10-18 S. Prokhorenko , N. A. Pertsev

The coexistence of ferroelectric and topological orders in two-dimensional (2D) atomic crystals allows non-volatile and switchable quantum spin Hall states. Here we offer a general design principle for 2D bilayer heterostructures that can…

Materials Science · Physics 2021-05-04 Jiawei Huang , Xu Duan , Sunam Jeon , Youngkuk Kim , Jian Zhou , Jian Li , Shi Liu

Ferroelectric materials can switch their polarization in response to an applied electric field. In this work, ferroelectricity at the single molecule level is proposed and investigated using density functional theory (DFT) calculations.…

Applied Physics · Physics 2017-05-30 Xinfeng Quan , Geoffrey R. Hutchison

The equilibrium domain structure and its evolution under an electric field in ferroelectric bilayers and graded multilayers are considered. The equilibrium bilayer is self-poled and contains a single-domain and a polydomain (with 180…

Materials Science · Physics 2009-11-11 A. L. Roytburd , J. Slutsker

The bulk photovoltaic effect that is intimately associated with crystalline symmetry has been extensively studied in various nonmagnetic materials, especially ferroelectrics with a switchable electric polarization. In order to further…

Materials Science · Physics 2022-12-28 Chunmei Zhang , Ping Guo , Jian Zhou