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Ferroelectricity has a wide range of applications in functional electronics and is extremely important for the development of next-generation information storage technology, but it is difficult to achieve due to its special symmetry…

Materials Science · Physics 2023-07-24 Yuwen Zhang , Chunfeng Cui , Chaoyu He , Tao Ouyang , Jin Li , Mingxing Chen , Chao Tang

The ground-state structural and electronic properties of ferroelectric BiFeO$_3$ are calculated using density functional theory within the local spin-density approximation and the LSDA+U method. The crystal structure is computed to be…

Materials Science · Physics 2007-05-23 J. B. Neaton , C. Ederer , U. V. Waghmare , N. A. Spaldin , K. M. Rabe

Stacking ferroelectricity (SFE) has been discovered in a wide range of van der Waals materials and holds promise for applications, including photovoltaics and high-density memory devices. We show that the microscopic origin of out-of-plane…

Materials Science · Physics 2024-05-13 Benjamin T. Zhou , Vedangi Pathak , Marcel Franz

Recent theoretical and experimental advances in quantum ferroelectrics suggest that ferroelectricity can also emerge in non-polar space group, highlighting the limitations of conventional polar space group criteria in identifying…

Materials Science · Physics 2026-05-15 Wei Luo , Shihan Deng , Hongjun Xiang , Laurent Bellaiche

In solids, charge polarity can one-to-one correspond to spin polarity phenomenologically, e.g. ferroelectricity/ferromagnetism, antiferroelectricity/antiferromagnetism, and even dipole-vortex/magnetic-vortex, but…

Stacking nonpolar, monolayer materials has emerged as an effective strategy to harvest ferroelectricity in two-dimensional (2D) van de Waals (vdW) materials. At a particular stacking sequence, interlayer charge transfer allows for the…

Materials Science · Physics 2024-11-12 Lingyuan Gao , Laurent Bellaiche

The coexistence of metallicity and ferroelectricity has been an intriguing and controversial phenomenon as these two material properties are considered incompatible in bulk. We clarify the concept of ferroelectric metal by revisiting the…

Materials Science · Physics 2021-11-01 Changming Ke , Jiawei Huang , Shi Liu

The demand for renewable and environmentally friendly energy source has attracted extensive research on high performance catalysts. Ferroelectrics which are a class of materials with a switchable polarization are the unique and promising…

Materials Science · Physics 2021-11-30 Weitong Ding , Xiao Tang , Wei Li , Liangzhi Kou , Lei Liu

Stacking of two-dimensional (2D) materials has emerged as a facile strategy for realising exotic quantum states of matter and engineering electronic properties. Yet, developments beyond the proof-of-principle level are impeded by the vast…

Materials with ferroelectrically switchable topological properties are of interest for both fundamental physics and practical applications. Using first-principles calculations, we find that stacking ferroelectric $\alpha$-In$_2$Se$_3$…

Materials Science · Physics 2024-02-29 Zhiqiang Tian , Ziming Zhu , Jiang Zeng , Chao-Fei Liu , Yurong Yang , Anlian Pan , Mingxing Chen

We use a first-principles calculations approach to reveal the electronic and magnetic properties of chromium diiodide (CrI$_2$) bilayers and establish a hierarchy of magnetic interactions across stable registries. The monolayer presents a…

Materials Science · Physics 2025-12-23 B. Valdés-Toro , I. Ferreira-Araya , R. A. Gallardo , J. W. González

Employing density functional theory-based methods, we investigate monolayer and bilayer structures of hexagonal SnS$_{2}$, which is recently synthesized monolayer metal dichalcogenide. Comparison of 1H and 1T phases of monolayer SnS$_{2}$…

Mesoscale and Nanoscale Physics · Physics 2016-03-14 C. Bacaksiz , S. Cahangirov , A. Rubio , R. T. Senger , F. M. Peeters , H. Sahin

Sliding ferroelectricity may emerge in many van der Waals bilayers/multilayers and the low switching barriers render ultrafast data writing with low energy cost. We note that such barriers are still much higher compared with structural…

Materials Science · Physics 2025-07-24 Zihao Yang , Menghao Wu

Sliding ferroelectricity is a phenomenon that arises from the insurgence of spontaneous electronic polarization perpendicular to the layers of two-dimensional (2D) systems upon the relative sliding of the atomic layer constituents. Because…

Materials Science · Physics 2026-04-21 Matteo D'Alessio , Daniele Varsano , Elisa Molinari , Massimo Rontani

Two-dimensional (2D) van der Waals ferroelectrics are recognized for enabling many applications, from memory and logic to neuromorphic computing, as well as transforming other materials to control electronic phase transitions and…

Van der Waals (vdW) polytypes of broken inversion and mirror symmetries were recently shown to exhibit switchable electric polarization even at the ultimate two-layer thin limit. Their out-of-plane polarization was found to accumulate in a…

Despite progress in HfO2 thin-film ferroelectrics, issues like high coercive fields persist, and the dynamics of twisted ferroelectricity remain largely unexplored. Here, we explore how sliding and twisting in bilayer HfO2 enables low…

Materials Science · Physics 2025-12-05 Jie Sun , Yiheng Shen , Tengfei Cao , Li-Min Liu

Interfacial ferroelectricity emerges in heterostructures consisting of nonpolar van der Waals (vdW) layers, greatly expanding the scope of two dimensional ferroelectrics. In particular, the unconventional moire ferroelectricity observed in…

Ferroelectric materials with switchable electric polarization hold great promise for a plethora of emergent applications, such as post-Moore's law nanoelectronics, beyond-Boltzmann transistors, non-volatile memories, and above-bandgap…

Spontaneous polarization and bulk photovoltaic effect (BPVE) are two concomitant physical properties in ferroelectric materials. The flipping of ferroelectric order usually accompanies with the switching of BPVE as both of them are reversed…

Materials Science · Physics 2022-07-04 Rui-Chun Xiao , Yang Gao , Hua Jiang , Wei Gan , Changjin Zhang , Hui Li