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We derive a thermodynamic uncertainty relation (TUR) for first-passage times (FPTs) on continuous time Markov chains. The TUR utilizes the entropy production coming from bidirectional transitions, and the net flux coming from unidirectional…

Statistical Mechanics · Physics 2021-08-11 Arnab Pal , Shlomi Reuveni , Saar Rahav

Fluctuation Theorems are statements about the entropy of systems far from thermal equilibrium. In this Letter relativistic Fluctuation Theorems for Brownian motion are presented and proven. Though there is a known discretization dilemma…

Statistical Mechanics · Physics 2007-05-23 Axel Fingerle

Fluctuation theorems impose constraints on the probability of observing negative entropy production in small systems driven out of equilibrium. The range of validity of fluctuation theorems has been extensively tested for transitions…

Statistical Mechanics · Physics 2015-04-21 Léo Granger , Jumna Mehlis , Édgar Roldán , Sergio Ciliberto , Holger Kantz

The thermodynamic uncertainty relation offers a universal energetic constraint on the relative magnitude of current fluctuations in nonequilibrium steady states. However, it has only been derived for long observation times. Here, we prove a…

Statistical Mechanics · Physics 2017-08-30 Jordan M. Horowitz , Todd R. Gingrich

Fluctuation theorems have elevated the second law of thermodynamics to a statistical realm by establishing a connection between time-forward and time-reversal probabilities, providing invaluable insight into nonequilibrium dynamics. While…

Quantum Physics · Physics 2025-06-05 Hui Li , Jie Xie , Hyukjoon Kwon , Yixin Zhao , M. S. Kim , Lijian Zhang

Thermodynamic uncertainty relations reveal a fundamental trade-off between the precision of a trajectory observable and entropy production, where the uncertainty of the observable is quantified by its variance. In information theory,…

Statistical Mechanics · Physics 2025-11-25 Yoshihiko Hasegawa , Tomohiro Nishiyama

In a finite system driven out of equilibrium by a constant external force the thermodynamic uncertainty relation (TUR) bounds the variance of the conjugate current variable by the thermodynamic cost of maintaining the non-equilibrium…

Statistical Mechanics · Physics 2021-08-17 David Hartich , Aljaz Godec

Entropy and the fluctuation-dissipation theorem are at the heart of statistical mechanics near equilibrium. Driving a system beyond the linear response regime leads to (i) the breakdown of the fluctuation-dissipation theorem and (ii) a…

Statistical Mechanics · Physics 2010-09-10 Thomas Speck

Thermodynamics is a science concerning the state of a system, whether it is stable, metastable, or unstable. The combined law of thermodynamics derived by Gibbs about 150 years ago laid the foundation of thermodynamics. In Gibbs combined…

Statistical Mechanics · Physics 2023-08-03 Zi-Kui Liu

Thermodynamic uncertainty relations (TURs) are a set of inequalities expressing a fundamental trade-off between precision and dissipation in non-equilibrium classical and quantum thermodynamic processes. TURs show that achieving low…

Quantum Physics · Physics 2025-03-07 Mario Motta , Antonio Mezzacapo , Giacomo Guarnieri

Thermodynamics provides a transparent definition of the free energy of density functional theory (DFT), and of its derivatives - the potentials, at finite temperatures T. By taking the T to 0 limit, it is shown here that both DFT and…

Materials Science · Physics 2016-08-31 Nathan Argaman , Guy Makov

We introduce a new technique to bound the fluctuations exhibited by a physical system, based on the Euclidean geometry of the space of observables. Through a simple unifying argument, we derive a sweeping generalization of so-called…

Statistical Mechanics · Physics 2020-06-24 Gianmaria Falasco , Massimiliano Esposito , Jean-Charles Delvenne

We extend the framework of forward and reverse processes commonly utilized in the derivation and analysis of the nonequilibrium work relations to thermodynamic processes with repeated discrete feedback. Within this framework, we derive a…

Statistical Mechanics · Physics 2010-12-16 Jordan M. Horowitz , Suriyanarayanan Vaikuntanathan

Materials that are constantly driven out of thermodynamic equilibrium, such as active and living systems, typically violate the Einstein relation. This may arise from active contributions to particle fluctuations which are unrelated to the…

Statistical Mechanics · Physics 2025-01-07 Benjamin Sorkin , Haim Diamant , Gil Ariel , Tomer Markovich

The Fluctuation Relation (FR) is an asymptotic result on the distribution of certain observables averaged over time intervals T as T goes to infinity and it is a generalization of the fluctuation--dissipation theorem to far from equilibrium…

Statistical Mechanics · Physics 2009-11-10 A. Giuliani , F. Zamponi , G. Gallavotti

Almost a century ago, Johnson and Nyquist presented evidence of fluctuating electrical current and the governing fluctuation dissipation theorem (FDT). Whether, likewise, temperature T can fluctuate is a controversial topic and has led to…

Mesoscale and Nanoscale Physics · Physics 2019-04-11 Bayan Karimi , Fredrik Brange , Peter Samuelsson , Jukka P. Pekola

There are only a very few known relations in statistical dynamics that are valid for systems driven arbitrarily far-from-equilibrium. One of these is the fluctuation theorem, which places conditions on the entropy production probability…

Statistical Mechanics · Physics 2009-09-25 Gavin E. Crooks

The fluctuation dissipation theorem (FDT) is the basis for a microscopic description of the interaction between electromagnetic radiation and matter.By assuming the electromagnetic radiation in thermal equilibrium and the interaction in the…

Statistical Mechanics · Physics 2018-05-22 Lino Reggiani , Eleonora Alfinito

The thermodynamic uncertainty relation (TUR) describes a trade-off relation between nonequilibrium currents and entropy production and serves as a fundamental principle of nonequilibrium thermodynamics. However, currently known TURs…

Statistical Mechanics · Physics 2020-09-30 Kangqiao Liu , Zongping Gong , Masahito Ueda

We study an arbitrary non-equilibrium dynamics of a quantum bipartite system coupled to a reservoir. For its characterization, we present a fluctuation theorem (FT) that explicitly addresses the quantum correlation of subsystems during the…

Quantum Physics · Physics 2020-05-22 Jung Jun Park , Hyunchul Nha , Sang Wook Kim , Vlatko Vedral