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In thermodynamics, entropy production and work quantify irreversibility and the consumption of useful energy, respectively, when a system is driven out of equilibrium. For quantum systems, these quantities can be identified at the…

In equilibrium, the fluctuation-dissipation theorem (FDT) expresses the response of an observable to a small perturbation by a correlation function of this variable with another one that is conjugate to the perturbation with respect to…

Statistical Mechanics · Physics 2010-10-13 Udo Seifert , Thomas Speck

The fluctuation theorem for entropy production is a remarkable symmetry of the distribution of produced entropy that holds universally in non-equilibrium steady states with Markovian dynamics. However, in systems with slow degrees of…

Statistical Mechanics · Physics 2018-02-21 Matthias Uhl , Patrick Pietzonka , Udo Seifert

Fluctuation theorems are key to understanding both fundamental and applied aspects of non-equilibrium thermodynamics of small systems. We study the non-Markovian entropy production fluctuation theorem for the diffusion process of charged…

Statistical Mechanics · Physics 2026-05-06 K. S. Rodríguez-Vigil , M. A. Bastarrachea-Magnani , J. I. Jiménez-Aquino

Based on trajectory dependent path probability formalism in state space, we derive generalized entropy production fluctuation relations for a quantum system in the presence of measurement and feedback. We have obtained these results for…

Statistical Mechanics · Physics 2015-06-04 Shubhashis Rana , Sourabh Lahiri , A. M. Jayannavar

We use quantum estimation theory to derive a thermodynamic uncertainty relation in Markovian open quantum systems, which bounds the fluctuation of continuous measurements. The derived quantum thermodynamic uncertainty relation holds for…

Statistical Mechanics · Physics 2020-07-30 Yoshihiko Hasegawa

Small systems in contact with a heat bath evolve by stochastic dynamics. Here we show that, when one such small system is weakly coupled to another one, it is possible to infer the presence of such weak coupling by observing the violation…

Statistical Mechanics · Physics 2016-11-07 Deepak Gupta , Sanjib Sabhapandit

The driving force of the dynamical system can be decomposed into the gradient of a potential landscape and curl flux (current). The fluctuation-dissipation theorem (FDT) is often applied to near equilibrium systems with detailed balance.…

Statistical Mechanics · Physics 2015-05-30 Haidong Feng , Jin Wang

The thermodynamic uncertainty relation is a prominent result in stochastic thermodynamics that provides a bound on the fluctuations of any thermodynamic flux, also known as current, in terms of the average rate of entropy production. Such…

Statistical Mechanics · Physics 2021-12-22 Taylor Wampler , Andre C Barato

The postulational basis of classical thermodynamics has been expanded to incorporate equilibrium fluctuations. The main additional elements of the proposed thermodynamic theory are the concept of quasi-equilibrium states, a definition of…

Statistical Mechanics · Physics 2019-06-11 Y. Mishin

A famous consequence of the detailed fluctuation theorem (FT), $p(\Sigma)/p(-\Sigma)=\exp{(\Sigma)}$, is the integral FT $\langle \exp(-\Sigma)\rangle =1$ for a random variable $\Sigma$ and a distribution $p(\Sigma)$. When $\Sigma$…

Statistical Mechanics · Physics 2023-07-05 Domingos S. P. Salazar

The Fluctuation Theorem describes the probability ratio of observing trajectories that satisfy or violate the second law of thermodynamics. It has been proved in a number of different ways for thermostatted deterministic nonequilibrium…

Statistical Mechanics · Physics 2009-10-31 Debra J. Searles , Denis J. Evans

Thermodynamic uncertainty relations (TURs) are general lower bounds on the size of fluctutations of dynamical observables. They have important consequences, one being that the precision of estimation of a current is limited by the amount of…

Statistical Mechanics · Physics 2022-10-12 George Bakewell-Smith , Federico Girotti , Mădălin Guţă , Juan P. Garrahan

We establish the general framework of quantum fluctuation theorems by finding the symmetry between the forward and backward transitions of any given quantum channel. The Petz recovery map is adopted as the reverse quantum channel, and the…

Quantum Physics · Physics 2019-08-23 Hyukjoon Kwon , M. S. Kim

The Integral Fluctuation Theorem for entropy production (IFT) is among the few equalities that are known to be valid for physical systems arbitrarily driven far from equilibrium. Microscopically, it can be understood as an inherent symmetry…

Statistical Mechanics · Physics 2023-06-21 Francesco Coghi , Lorenzo Buffoni , Stefano Gherardini

The authors of Ref. [1] claim to have experimental verification of violations of the second law of thermodynamics based on the assertions: (i) "for large systems and over long times the entropy production rate is necessarily positive"; (ii)…

Quantum Physics · Physics 2007-06-20 Elias P. Gyftopoulos

For fluctuating currents in non-equilibrium steady states, the recently discovered thermodynamic uncertainty relation expresses a fundamental relation between their variance and the overall entropic cost associated with the driving. We show…

Statistical Mechanics · Physics 2017-07-12 Patrick Pietzonka , Felix Ritort , Udo Seifert

In systems far from equilibrium, the statistics of observables are connected to entropy production, leading to the Thermodynamic Uncertainty Relation (TUR). However, the derivation of TURs often involves constraining the parity of…

Statistical Mechanics · Physics 2023-05-17 Domingos S. P. Salazar

The relationships between reversible Carnot cycles, the absence of perpetual motion machines and the existence of a non-decreasing, globally unique entropy function forms the starting point of many textbook presentations of the foundations…

Statistical Mechanics · Physics 2015-05-14 O. J. E. Maroney

Fluctuation theorems allow one to make generalised statements about the behaviour of thermodynamic quantities in systems that are driven far from thermal equilibrium. In this article we use Crooks' fluctuation theorem to understand the…

Quantum Physics · Physics 2022-08-24 M. J. Kewming , S. Shrapnel