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First principles based DFT calculations performed to insight structural and electronic properties of Boron doped Magnesium atom decorated graphene sheet for application of hydrogen storage. The four H2 molecules stably binds magnesium atom…

Materials Science · Physics 2020-03-31 Baliram Lone

Boron is the fifth element in the periodic table and possesses rich chemistry second only to carbon. A striking feature of boron is that B12 icosahedral cages occur as the building blocks in bulk boron and many boron compounds. This is in…

Mesoscale and Nanoscale Physics · Physics 2016-06-22 Baojie Feng , Jin Zhang , Qing Zhong , Wenbin Li , Shuai Li , Hui Li , Peng Cheng , Sheng Meng , Lan Chen , Kehui Wu

The recent progress in the field of hydrogen storage in carbon and boron nitride nanostructures has been summarized. Carbon and boron nitride nanostructures are considered advantageous in this prospect due to their lightweight and high…

Applied Physics · Physics 2021-07-29 Y. T. Singh , B. Chettri , A. Banik , K. O. Obodo , D. P. Rai

We study the hydrogen storage properties of planar boron sheets and compare them to those of graphene. The binding of molecular hydrogen to the boron sheet (0.05 eV) is stronger than that to graphene. We find that dispersion of alkali metal…

Materials Science · Physics 2009-10-27 Süleyman Er , Gilles A. de Wijs , Geert Brocks

In this work, we foresee the structure of a new class of borophenes with smaller 2D densities of atoms than those explored so far for 2D boron crystals. Boron atoms in the porous borophenes tend to be $5$-coordinated in contrast to commonly…

Materials Science · Physics 2021-11-25 T. Tarkowski , M. Marchwiany , N. Gonzalez Szwacki

We predict by first principles calculations that the recently prepared borophene is a pristine two-dimensional (2D) monolayer superconductor, in which the superconductivity can be significantly enhanced by strain and charge carrier doping.…

Superconductivity · Physics 2017-01-09 R. C. Xiao , D. F. Shao , W. J. Lu , H. Y. Lv , J. Y. Li , Y. P. Sun

As the novel topological states, the higher-order topological insulators have attracted great attentions in the past years. However, their realizations in realistic materials, in particular in two dimensional systems, remains the big…

Materials Science · Physics 2025-11-05 Licheng Wang , Ali Hamza Qureshi , Yi Sun , Xiaokang Xu , Xiaojing Yao , Xinli Zhao , Ai-Lei He , Yuan Zhou , Xiuyun Zhang

Bilayer borophene, very recently synthesized on Ag and Cu, possesses extremely flat large surface and excellent conductivity. Besides, the van der Waals gap of bilayer borophene can be intercalated by metal atoms, thereby tailoring the…

Materials Science · Physics 2023-09-07 Yuan Chang , Hongsheng Liu , Jiaxu Liu , Jijun Zhao , Yong-Wei Zhang , Junfeng Gao

By means of variable-composition evolutionary algorithm coupled with density functional theory and in combination with aberration-corrected high-resolution transmission electron microscopy experiments, we have studied and characterized the…

Carbon's versatility allows it to form diverse structures with unique properties, driven by its moderate electronegativity, small ionic radius, and ability to adopt \textit{sp}, \textit{sp\textsuperscript{2}}, and…

We study the effect of electron doping on the bonding character and stability of two-dimensional (2D) structures of elemental boron, called borophene, which is known to form many stable allotropes. Our {\em ab initio} calculations for the…

Materials Science · Physics 2019-03-27 Dan Liu , David Tomanek

Two-dimensional (2D) boron monolayers have been successfully synthesized on silver substrate very recently. Their potential application is thus of great significance. In this work, we explore the possibility of boron monolayers (BMs) as…

Chemical Physics · Physics 2016-11-24 Li Shi , Chongyi Ling , Yixin Ouyang , Jinlan Wang

We study the electronic transport properties of two-dimensional (2D) fully-hydrogenated borophene (namely, borophane), using the density functional theory and non-equilibrium Green's function approaches. Borophane shows a perfect electrical…

Materials Science · Physics 2018-10-17 Yipeng An , Jutao Jiao , Yusheng Hou , Hui Wang , Dapeng Wu , Tianxing Wang , Zhaoming Fu , Guoliang Xu , Ruqian Wu

The complex crystal chemistry of elemental boron has led to numerous proposed structures with distinctive motifs as well as contradictory findings. Herein, evolutionary structure searches performed at 100 GPa have uncovered a series of…

Materials Science · Physics 2021-05-19 Katerina P. Hilleke , Eva Zurek , Tadashi Ogitsu , Shuai Zhang

Exceptionally high energy density by mass, natural abundance, widespread applications, and environmental friendliness make hydrogen (H2) a front-runner among clean energy options. However, the transition toward clean and renewable energy…

Materials Science · Physics 2024-07-25 Wael Othman , Wadha Al Falasi , Tanveer Hussain , Nacir Tit

By performing density functional theory-based calculations, we investigate how hydrogen atom interacts with the surfaces of monolayer PbI2 and how one and two side hydrogenation modify its structural, electronic, and magnetic properties.…

Mesoscale and Nanoscale Physics · Physics 2016-07-22 C. Bacaksiz , H. Sahin

The search for topological semimetals is mainly focused on heavy-element compounds as following the footsteps of previous research on topological insulators, with less attention on light-element materials. However, the negligible spin orbit…

Materials Science · Physics 2019-01-24 Chengyong Zhong , Weikang Wu , Junjie He , Guangqian Ding , Yi Liu , Dengfeng Li , Shengyuan A. Yang , Gang Zhang

The search of new superhard materials has received a strong impulse by industrial demands for low-cost alternatives to diamond and $c$-BN, such as metal borides. In this Letter we introduce a new family of superhard materials, "fused…

Materials Science · Physics 2021-08-18 Santanu Saha , Wolfgang von der Linden , Lilia Boeri

Sodium-ion batteries (SIBs) have attracted a great deal of attention as potential low-cost energy storage alternatives to Lithium-ion batteries (LIBs) due to the intrinsic safety and great abundance of sodium on Earth. For developing…

Materials Science · Physics 2020-09-01 Yang Zhang , Er-Hu Zhang , Ming-Gang Xia , Sheng-Li Zhang

First-principles calculations on monolayer 8-{\it Pmmn} borophene are reported to reveal unprecedented electronic properties in a two-dimensional material. Based on a Born effective charge analysis, 8-{\it Pmmn} borophene is the first…

Materials Science · Physics 2016-08-18 Alejandro Lopez-Bezanilla , Peter B. Littlewood