Related papers: Ly{\alpha} irradiation of solid-state formamide
Galactic cosmic rays (CRs) play a crucial role in ionisation, dissociation, and excitation processes within dense cloud regions where UV radiation is absorbed by dust grains and gas species. CRs regulate the abundance of ions and radicals,…
Context. We present a method for including gas extinction of cosmic-ray-generated UV photons in chemical models of the midplane of protoplanetary disks, focusing on its implications on ice formation and chemical evolution. Aims. Our goal is…
We report the detection of diffuse Ly$\alpha$ emission, or Ly$\alpha$ halos (LAHs), around star-forming galaxies at $z\approx3.78$ and $2.66$ in the NOAO Deep Wide-Field Survey Bo\"otes field. Our samples consist of a total of $\sim$1400…
We present models for the chemistry in gas moving towards the ionization front of an HII region. When it is far from the ionization front, the gas is highly depleted of elements more massive than helium. However, as it approaches the…
Ultraviolet (UV) light plays a key role in surficial theories of the origin of life, and numerous studies have focused on constraining the atmospheric transmission of UV radiation on early Earth. However, the UV transmission of the natural…
The solid-state C$_2$H$_2$ chemistry in interstellar H$_2$O-rich ice has been proposed to explain astronomically observed complex organic molecules (COMs), including ketene (CH$_2$CO), acetaldehyde (CH$_3$CHO), and ethanol (CH$_3$CH$_2$OH),…
To elucidate the underlying nature of the hidden order (HO) state in heavy-fermion compound URu2Si2, we measure electrical transport properties of ultraclean crystals in a high field/low temperature regime. Unlike previous studies, the…
We present maps of the 6 cm and 1.3 mm transitions of formaldehyde toward three cold, dense pre-protostellar cores: L1498, L1512, and L1544. The 6 cm transition is a unique probe of high density gas at low temperature. However, our models…
We study the chemical evolution of H2O:CO:NH3 ice mixtures irradiated with soft X-rays, in the range 250-1250 eV. We identify many nitrogen-bearing molecules such as e.g., OCN-, NH4+ , HNCO, CH3CN, HCONH2, and NH2COCONH2. Several infrared…
Ultraviolet absorption from interstellar 12CO and 13CO was detected toward rho Oph A and chi Oph. The measurements were obtained at medium resolution with the Goddard High Resolution Spectrograph on the Hubble Space Telescope. Column…
Ice mantles that formed on top of dust grains are photoprocessed by the secondary ultraviolet (UV) field in cold and dense molecular clouds. UV photons induce photochemistry and desorption of ice molecules. Experimental simulations…
In cold molecular clouds, UV photolysis of icy grain mantles generates radicals that lead to new molecule formation. When radical diffusion is limited by low temperatures, oxygen atom addition and insertion reactions, enabled by photolysis…
After hydrogen, oxygen, and carbon, nitrogen is one of the most chemically active species in the interstellar medium (ISM). Nitrogen bearing molecules have great importance as they are actively involved in the formation of biomolecules.…
H$_2$CO is one of the most abundant organic molecules in protoplanetary disks and can serve as a precursor to more complex organic chemistry. We present an ALMA survey of H$_2$CO towards 15 disks covering a range of stellar spectral types,…
Branching ratios for fragmentation channels of important meta- and unstable species are essential for a molecular-level characterization of atmospheric chemistry. Here, the molecular product channels for the decomposition dynamics of the…
We use three-dimensional hydrodynamic simulations to investigate the effects of a transient photoionizing ultraviolet (UV) flux on the collapse and cooling of pregalactic clouds. These clouds have masses in the range 10^5 -10^7 M_sun, form…
The solid-state reaction C + H$_2$O $\rightarrow$ H$_2$CO was studied experimentally following the codeposition of C atoms and H$_2$O molecules at low temperatures. In spite of the reaction barrier and absence of energetic triggering, the…
Ices are an important constituent of protoplanetary disks. New observational facilities, notably the James Webb Space Telescope (JWST), will greatly enhance our view of disk ices by measuring their infrared spectral features. We present a…
The initial stage of star formation is a complex area study because of its high density and low temperature. Under such conditions, many molecules become depleted from the gas phase by freezing out onto dust grains. However, the deuterated…
Understanding the processes that can destroy H$_2$ and H$^-$ species is quintessential in governing the formation of the first stars, black holes and galaxies. In this study we compute the reaction rate coefficients for H$_2$…