Related papers: Ly{\alpha} irradiation of solid-state formamide

Ice mantles detected on the surface of dust grains toward the coldest regions of the interstellar medium can be photoprocessed by the secondary ultraviolet (UV) field present in dense cloud interiors. In this work, we present UV-irradiation…

Context. Deuterium in H-bearing species is enhanced during the early stages of star formation, however, only a small number of high spatial resolution deuteration studies exist towards protostellar objects, leaving the small-scale…

Hydroxylamine, NH2OH, is one of the already detected interstellar molecules with the highest prebiotic potential. Yet, the abundance of this molecule found by astronomical observations is rather low for a relatively simple molecule, $\sim$…

Ultraviolet photodesorption of molecules from icy interstellar grains can explain observations of cold gas in regions where thermal desorption is negligible. This non-thermal desorption mechanism should be especially important where UV…

Context. Time dependent gas-grain chemistry can help us understand the layered structure of species deposited onto the surface of grains during the lifetime of a protoplanetary disk. The history of trapping important quantities of carbon-…

UltraCompact HII regions are signposts of high mass star formation. Since high-mass star formation occurs in clusters, one expects to find even earlier phases of massive star formation in the vicinity of UltraCompact HII regions. Here, we…

Far-UV photons (E<13.6 eV) from hot massive stars regulate, or at least influence, the heating, ionization, and chemistry of most of the neutral interstellar medium. Investigating the interaction between FUV radiation and interstellar…

Sources of X-rays such as active galactic nuclei and X-ray binaries are often variable by orders of magnitude in luminosity over timescales of years. During and after these flares the surrounding gas is out of chemical and thermal…

The emergence of habitable conditions on the early Earth and on rocky exoplanets requires persistent energy sources that can drive both prebiotic chemistry and climate warming under magnetically active young G to M stars. To quantify the…

Ultracompact (UC) HII regions constitute one of the earliest phases in the formation of a massive star and are characterized by extreme physical conditions (Go>10^5 Habing field and n>10^6 cm^-3). The UC HII Mon R2 is the closest one and…

Solid-phase photo-processes involving icy dust grains greatly affect the chemical evolution of the interstellar medium by leading to the formation of complex organic molecules and by inducing photodesorption. So far, the focus of laboratory…

Formaldehyde is a key precursor in the formation routes of many complex organic molecules (COMs) in space. It is also an intermediate step in CO hydrogenation sequence that leads to methanol formation on the surface of interstellar grains…

We examine the absorption of cosmic microwave background (CMB) photons by formaldehyde (H2CO) over cosmic time. The K-doublet rotational transitions of H2CO become "refrigerated" - their excitation temperatures are driven below the CMB…

Icy interstellar dust grains are a source of complex organic molecule (COM) production, although their formation mechanisms are debated. Laboratory experiments show that atomic C deposited onto interstellar ice analogs can react with…

[Abridged] Observations of protoplanetary disks suggest that they are depleted in gas-phase CO. It has been posed that gas-phase CO is chemically consumed and converted into less volatile species through gas-grain processes. Observations of…

Deuterated molecules are good tracers of the evolutionary stage of star-forming cores. During the star formation process, deuterated molecules are expected to be enhanced in cold, dense pre-stellar cores and to deplete after protostellar…

Hydroxylamine (NH2OH) is one of the potential precursors of complex pre-biotic species in space. Here we present a detailed experimental study of hydroxylamine formation through nitric oxide (NO) surface hydrogenation for astronomically…

The chemical inventory of planets is determined by the physical and chemical processes that govern the early phases of star formation. The aim is to investigate N-bearing complex organic molecules towards two Class 0 protostars (B1-c and…

We present observations of molecular high-energy radiation probes and report the first detections of CO+ toward W3 IRS5, a source containing ultracompact HII regions. UV radiation and X-rays from the central objects may enhance molecules…

Complex organic molecules (COMs) have been identified in different environments in star- forming regions. Laboratory studies show that COMs form in the solid state, on icy grains, typically following a non-energetic (atom-addition) or…