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H$_2$CO ice on dust grains is an important precursor of complex organic molecules (COMs). H$_2$CO gas can be readily observed in protoplanetary disks and may be used to trace COM chemistry. However, its utility as a COM probe is currently…
We present results from three-dimensional hydrodynamic simulations of the high redshift collapse of pregalactic clouds including feedback effects from a soft H2 photodissociating UV radiation field. The simulations use an Eulerian adaptive…
The emergence of life on the Earth has required a prior organic chemistry leading to the formation of prebiotic molecules. The origin and the evolution of the organic matter on the early Earth is not yet firmly understood. Several…
Studying the physical and chemical properties of cold and dense molecular clouds is crucial for the understanding of how stars form. Under the typical conditions of infrared dark clouds, CO is removed from the gas phase and trapped on to…
(Abridged) Gas-phase complex organic molecules are commonly detected in the warm inner regions of protostellar envelopes. Recent models show that photochemistry in ices followed by desorption may explain the observed abundances. This study…
[abridged] The enhanced degrees of deuterium fractionation observed in envelopes around protostars demonstrate the importance of chemistry at low temperatures, relevant in pre- and protostellar cores. formaldehyde is an important species in…
At early times the Universe was filled up with an extremely dense and hot gas. Due to the expansion it cooled below the binding energies of atoms which led to the formation of the first nuclei. In the physical environment of the…
We present the observational result of a glycine precursor, methylamine (CH$_3$NH$_2$), together with methanol (CH$_3$OH) and methanimine (CH$_2$NH) towards high-mass star-forming regions, NGC6334I, G10.47+0.03, G31.41+0.3, and W51~e1/e2…
The 100% detection rate of Ly$\alpha$ emission in a sample of four luminous $z\sim8$ galaxies with red Spitzer/IRAC colors suggests objects with unusual ionizing capabilities that created early ionized bubbles in a neutral era. Whether such…
The hydrogen ionization and dissociation front around an ultraviolet radiation source should merge when the ratio of ionizing photon flux to gas density is sufficiently low and the spectrum is sufficiently hard. This regime is particularly…
In the search for life on Earth-like planets around other stars, the first (and likely only) information will come from the spectroscopic characterization of the planet's atmosphere. Of the countless number of chemical species terrestrial…
Snowlines of major volatiles regulate the gas and solid C/N/O ratios in the planet-forming midplanes of protoplanetary disks. Snow surfaces are the 2D extensions of snowlines in the outer disk regions, where radiative heating results in a…
We present a new high-resolution study of pre-protocluster regions in tracers exclusively probing the coldest and dense gas (NH_2D). The data are used to constrain the chemical, thermal, kinematic, and physical conditions (i.e., densities)…
The detection of complex organic molecules (COMs) toward cold sources such as pre-stellar cores (with T<10 K), has challenged our understanding of the formation processes of COMs in the interstellar medium. Recent modelling on COM chemistry…
Here we aim to explore the origin of the strong C2H lines to reimagine the chemistry of protoplanetary disks. There are a few key aspects that drive our analysis. First, C2H is detected in young and old systems, hinting at a long-lived…
(abridged) We use large cosmological simulations to study the origin of primordial star-forming clouds in a Lambda CDM universe, by following the formation of dark matter halos and the cooling of gas within them. To model the physics of…
Hypervolatile species such as carbon monoxide (CO) and molecular nitrogen (N2) have been detected in comets, and could be used to constrain comet formation temperature conditions if their presence is due to freeze-out and/or entrapment.…
Submillimeter lines of CN, NO, CO+ and SO+, and upper limits on SH+ and N2O are observed with the James Clerk Maxwell Telescope in two high-mass and up to nine low-mass young stellar objects and compared with chemical models. Constant…
It has been a long-standing problem to detect interstellar glycine (NH$_2$CH$_2$COOH), the simplest amino acid, in studying a possible relation between the Universe and origin of life. In the last about 40 years all surveys of glycine…
Isolated dense molecular cores are investigated to study the onset of complex organic molecule formation in interstellar ice. Sampling three cores with ongoing formation of low-mass stars (B59, B335, and L483) and one starless core (L694-2)…