Related papers: Ionise hard: interstellar PO$^{+}$ detection

We study the effect that non-equilibrium chemistry in dynamical models of collapsing molecular cloud cores has on measurements of the magnetic field in these cores, the degree of ionization, and the mean molecular weight of ions. We find…

The interstellar medium (ISM) has a multiphase structure characterized by gas, dust and molecules. The gas can be found in different charge states: neutral, low-ionized (warm) and high-ionized (hot). It is possible to probe the multiphase…

The chemical properties of protoplanetary disks are especially sensitive to their ionization environment. Sources of molecular gas ionization include cosmic rays, stellar X-rays and short-lived radionuclides, each of which varies with…

Studying the molecular component of the interstellar medium in metal-poor galaxies has been challenging because of the faintness of carbon monoxide emission, the most common proxy of H2. Here we present new detections of molecular gas at…

Protonated molecular species have been proven to be abundant in the interstellar gas. This class of molecules is also pivotal for the determination of important physical parameters for the ISM evolution (e.g. gas ionisation fraction) or as…

Using the Cosmic Origins Spectrograph aboard the Hubble Space Telescope, we measured the abundances of six ions (C III, C IV, Si III, Si IV, N V, O VI) in the low-redshift (z < 0.4) intergalactic medium and explored C and Si ionization…

We investigate the chemistry of ion molecules in protoplanetary disks, motivated by the detection of N$_2$H$^+$ ring around TW Hya. While the ring inner radius coincides with the CO snow line, it is not apparent why N$_2$H$^+$ is abundant…

Theoretical models and observations suggest that the abundances of molecular ions in protoplanetary disks should be highly sensitive to the variable ionization conditions set by the young central star. We present a search for temporal flux…

Absorption lines from the molecules OH+, H2O+, and H3+ have been observed in a diffuse molecular cloud along a line of sight near W51 IRS2. We present the first chemical analysis that combines the information provided by all three of these…

We used archival data acquired with the Copernicus satellite to reexamine CO column densities because self-consistent oscillator strengths are now available. Our focus is on lines of sight containing modest amounts of molecular species. Our…

We report the first detection of SiC$_2$ in the interstellar medium. The molecule was identified through six rotational transitions toward G\,+0.693$-$0.027, a molecular cloud located in the Galactic center. The detection is based on a line…

We investigate the role of carbon monoxide ice in the chemical evolution of prestellar cores using astrochemical rate equation models. We constrain the ratios of the binding energies on CO ice and H$_{2}$O ice for a series of adsorbates…

The millimeter-wave rotational emission lines (4(04)-3(03) and 5(05)-4(04)) of protonated carbon dioxide, HCO2+(HOCO+), has been detected toward the low-mass class 0 protostar IRAS 04368+2557 in L1527 with the IRAM 30 m telescope. This is…

Context. The chemistry of the diffuse interstellar medium rests upon three pillars: exothermic ion-neutral reactions (" cold chemistry "), endothermic neutral-neutral reactions with significant activation barriers (" warm chemistry "), and…

We present an observational and theoretical study of the ionization fraction in several massive cores located in regions that are currently forming stellar clusters. Maps of the emission from the J = 1-> O transitions of C18O, DCO+, N2H+,…

$\textit{Herschel}$ observations of far infrared N$^+$ emission lines have demonstrated that dense plasma, with $n_e\sim30\,{\rm cm^{-3}}$, is ubiquitous in the inner Galactic plane. By combining the information from $\textit{Herschel}$…

Cold ($\sim$10 K) and dense ($\sim$10$^{5}$ cm$^{-3}$) cores of gas and dust within molecular clouds, known as starless and dynamically evolved prestellar cores, are the birthplaces of low-mass ($M$ $\leq$ few M$_\odot$) stars. As…

According to traditional gas-phase chemical models, O2 should be abundant in molecular clouds, but until recently, attempts to detect interstellar O2 line emission with ground- and space-based observatories have failed. Following the…

We report the results of initial FUSE observations of molecular hydrogen (H2) in translucent clouds. These clouds have greater optical depth than any of the diffuse clouds previously observed for far-UV H2 absorption, and provide new…

Phosphorus (P) is a crucial element for life given its central role in several biomolecules. P-bearing molecules have been discovered in different regions of the Milky Way, but not yet towards an extragalactic environment. We have searched…