Related papers: Ionise hard: interstellar PO$^{+}$ detection
We present numerical computations and analytic scaling relations for interstellar ion-molecule gas phase chemistry down to very low metallicities ($ 10^{-3} \times$ solar), and/or up to high driving ionization rates. Relevant environments…
Studies measuring the chemical abundances of the neutral gas in star-forming galaxies (SFGs) require ionization correction factors (ICFs) to accurately measure their metal contents. In the work presented here we calculate newly improved…
Surprisingly large column densities of H3+ have been detected using infrared absorption spectroscopy in seven diffuse cloud sightlines (Cygnus OB2 12, Cygnus OB2 5, HD 183143, HD 20041, WR 104, WR 118, and WR 121), demonstrating that H3+ is…
In this paper we use a number of observations to construct an integrated picture of the ionisation in the interiors of quiescent warm opaque interstellar clouds and in the intercloud medium (ICM) outside dense HII regions and hot dilute…
Phosphorus is a necessary element for life on Earth, but at present we have limited constraints on its chemistry in star- and planet-forming regions: to date, phosphorus carriers have only been detected towards a few low-mass protostars.…
When the neutral interstellar medium is exposed to EUV and soft X ray radiation, the argon atoms in it are far more susceptible to being ionized than the hydrogen atoms. We make use of this fact to determine the level of ionization in the…
We study the ionised ISM in NGC 7793 with MUSE/AO, at a spatial resolution of $\sim$ 10 pc. The data are complemented with young star clusters (YSCs), O stars and GMCs observed with HST and ALMA. Using a strong-line method, we find a median…
The rotational transitions of carbon monoxide (CO) are the primary means of investigating the density and velocity structure of the molecular interstellar medium. Here we study the lowest four rotational transitions of CO towards…
We report the detection in space of a new molecular species which has been characterized spectroscopically and fully identified from astrophysical data. The observations were carried out with the 30m IRAM telescope. The molecule is…
The molecular gas composition in the inner 1 kpc disk of the starburst galaxy M82 resembles that of Galactic Photon Dominated Regions (PDRs). In particular, large abundances of the reactive ions HOC+ and CO+ have been measured in the…
Nitrogen oxides are thought to play a significant role as a nitrogen reservoir and to potentially participate in the formation of more complex species. Until now, only NO, N$_2$O and HNO have been detected in the interstellar medium. We…
Cosmic rays are an essential ingredient in the evolution of the interstellar medium, as they dominate the ionisation of the dense molecular gas, where stars and planets form. However, since they are efficiently scattered by the galactic…
We present the first detection in space of thionylimide (HNSO) toward the Galactic Center molecular cloud G+0.693-0.027, thanks to the superb sensitivity of an ultradeep molecular line survey carried out with the Yebes 40$\,$m and IRAM…
Sulfur-bearing molecules are central to interstellar chemistry, yet their observed abundances in the gas phase remain far below cosmic expectations in dense interstellar regions. Mixed N-S-O species such as thionylimide (HNSO) are…
Phosphorus (P) is considered to be one of the key elements for life, making it an important element to look for in the abundance analysis of spectra of stellar systems. Yet, there exists only a handful of spectroscopic studies to estimate…
Deuterium fractionation in molecular ions, in particular HCO+, has been extensively used to estimate the degree of ionization in molecular clouds. This paper reviews recent work on ionization degree in homogeneous clouds. We will show that…
We present direct measures of the ionization fractions of several sulfur ions in the Galactic warm ionized medium (WIM). We obtained high resolution ultraviolet absorption line spectroscopy of post-asymptotic giant branch stars in the the…
In light of its ubiquitous presence in the interstellar gas, the chemistry and reactivity of the HCO+ ion requires special attention. The availability of up-to-date collisional data between this ion and the most abundant perturbing species…
This paper provides a general reference for deriving the ionizations and metal abundances for absorption-line clouds in photoionization equilibrium with a QSO spectrum. The results include a quantitative assessment of the theoretical…
We report the detection of the protonated form of HC7N in TMC-1. The discovery of the cation HC7NH+ was carried out via the observation of nine harmonically related lines in the Q-band using the Yebes 40m radiotelescope. The observed…