Related papers: Ionise hard: interstellar PO$^{+}$ detection
OH 231.8+4.2, a bipolar outflow around a Mira-type variable star, displays a unique molecular richness amongst circumstellar envelopes (CSEs) around O-rich AGB and post-AGB stars. We report line observations of the HCO+ and H13CO+ molecular…
We present three-dimensional astrochemical simulations and synthetic observations of magnetised, turbulent, self-gravitating molecular clouds. We explore various galactic interstellar medium environments, including cosmic-ray ionization…
Recent measurements carried out at comet 67P/C-G with the ${\it Rosetta}$ probe revealed that molecular oxygen, O$_2$, is the fourth most abundant molecule in comets. Models show that O$_2$ is likely of primordial nature, coming from the…
We report the derivation of rate coefficients for the rotational (de-)excitation of PO$^+$ induced by collisions with H$_2$. The calculations were performed on a four-dimensional potential energy surface, obtained on top of highly accurate…
Isomerism in complex organic molecules provides key insights into the formation mechanisms and physical conditions of the interstellar medium (ISM). Among the C$_2$H$_5$NO isomers, only acetamide and trans-N-methylformamide (trans-NMF) have…
$Aims$: We revisit with new augmented accuracy the theoretical dynamics of basic isotope exchange reactions involved in the $^{12}$C/$^{13}$C, $^{16}$O/$^{18}$O, and $^{14}$N/$^{15}$N balance because these reactions have already been…
Sulphur-bearing species play crucial roles in interstellar chemistry, yet their precise characterisation remains challenging. Here, we present laboratory experiments aimed at extending the high-resolution spectroscopy of protonated carbonyl…
The Infrared Space Observatory (ISO) has shown the complexity of the Galactic center (GC) Interstellar medium (ISM) detecting, not only large column densities of warm molecular gas (H2), but the emission of neutral atoms and ions of low…
We provide the first direct observations of interstellar H+ and He+ pickup ions in the solar wind from 22 AU to 38 AU. We use the Vasyliunas and Siscoe model functional form to quantify the pickup ion distributions, and while the fit…
Diffuse interstellar clouds show large abundances of H_3^+ which can be maintained only by a high ionization rate of H_2. Cosmic rays are the dominant ionization mechanism in this environment, so the large ionization rate implies a high…
We report the first detection of PDR molecular tracers, namely HOC+, and CO+, and confirm the detection of the also PDR tracer HCO towards the starburst galaxy NGC 253, claimed to be mainly dominated by shock heating and in an earlier stage…
Phosphorus plays an essential role in the chemistry of living organisms, being present in several fundamental biomolecules. The investigation of chemical reactions taking place in different astronomical environments involving…
We used the Plateau de Bure Interferometer to search for $\lambda$3mm absorption lines of HOC+ from local diffuse and translucent clouds occulting compact extragalactic mm-wave continuum sources. We detected HOC+ in three directions with…
Carbon monoxide (CO) is the second most abundant molecule in the gas-phase of the interstellar medium. In dense molecular clouds, it is also present in the solid-phase as a constituent of the mixed water-dominated ices covering dust grains.…
Ionization is a major driver of both physical and chemical evolution in protostellar systems. Recent observations reveal substantial chemical processing in protoplanetary disks by the time the surrounding envelope has cleared. Thus,…
The chemistry of the diffuse interstellar medium is driven by the combined influences of cosmic rays, ultraviolet (UV) radiation, and turbulence. Previously detected at the outer edges of photodissociation regions (PDRs) and formed from the…
Carbon monoxide (CO) is a poor tracer of H$_{2}$ in the diffuse interstellar medium (ISM), where most of the carbon is not incorporated into CO molecules unlike the situation at higher extinctions. We present a novel, indirect method to…
We describe a new method for determining total gas-phase abundances for the Galactic ISM with minimal ionization uncertainties. For sight lines toward globular clusters containing both UV-bright stars and radio pulsars, one can measure…
We present a comprehensive survey of boron abundances in diffuse interstellar clouds from observations made with the Space Telescope Imaging Spectrograph (STIS) of the Hubble Space Telescope. Our sample of 56 Galactic sight lines is the…
We have detected CO+ toward the photon-dominated region (PDR) associated with the reflection nebula NGC 7023. This is the first detection of CO+ in the vicinity of a Be star. A CO+ column density of ~ 3E11 cm-2 has been derived toward the…