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We study the effects of electron doping in Mott insulators containing d^4 ions such as Ru4+, Os4+, Rh5+, and Ir5+ with J=0 singlet ground state. Depending on the strength of the spin-orbit coupling, the undoped systems are either…

Strongly Correlated Electrons · Physics 2016-01-12 Jiří Chaloupka , Giniyat Khaliullin

Fe3Si is a ferromagnetic material with possible applications in magnetic tunnel junctions. When doped with Mn, the material shows a complex magnetic behavior, as suggested by older experiments. We employed the Korringa-Kohn-Rostoker (KKR)…

Materials Science · Physics 2016-08-14 Marjana Ležaić , Phivos Mavropoulos , Stefan Blügel , Hubert Ebert

The doping series Eu1-xCaxCoO3-d provides a rather peculiar way to study the spin-state transition in cobalt-based complex oxides since partial substitution of Eu3+ ions by Ca2+ ions does not increase the mean valence state of cobalt but is…

We use neutron scattering to study magnetic order and spin excitations in BaFe$_{1.96}$Ni$_{0.04}$As$_{2}$. On cooling, the system first changes the lattice symmetry from tetragonal to orthoromhbic near $\sim$97 K, and then orders…

We have studied the magnetization process of the new insulating ferromagnetic semiconductor (Al,Fe)Sb by means of x-ray magnetic circular dichroism. For an optimally doped sample with 10% Fe, a magnetization was found to rapidly increase at…

The intrinsically hole-doped RbEuFe$_4$As$_4$ exhibits bulk superconductivity at $T_{\mathrm{sc}}=36.5$ K and ferromagnetic ordering in the Eu sublattice at $T_\mathrm{m}=15$ K. Here we present a hole-compensation study by introducing extra…

Superconductivity · Physics 2018-01-09 Yi Liu , Ya-Bin Liu , Ya-Long Yu , Qian Tao , Chun-Mu Feng , Guang-Han Cao

Fe-K$_{\beta}$ X-ray emission spectroscopy measurements reveal an asymmetric doping dependence of the magnetic moments $\mu_\text{bare}$ in electron- and hole-doped BaFe$_{2}$As$_{2}$. At low temperature, $\mu_\text{bare}$ is nearly…

In this work, compositions of CeFe11X and CeFe10X2 with all 3d, 4d, and 5d transition metal substitutions are considered. Since many previous studies have focused on the CeFe11Ti compound, this particular compound became the starting point…

Materials Science · Physics 2022-04-20 Justyn Snarski-Adamski , Mirosław Werwiński

We have developed a new magnetoelectric material based on Ga doped {\alpha}-Fe2O3 in rhombohedral phase. The material is a canted ferromagnet at room temperature and showing magneto-electric properties. The experimental results of electric…

Materials Science · Physics 2018-05-23 R. N. Bhowmik , Abdul Gaffar Lone

The mechanisms underlying the enhancement of magnetic anisotropies (MAs) of Sm ions, owing to valence electrons at the Sm site and the screened nuclear charges of ligands, are clarified using a detailed analysis of crystal fields (CF). In…

Materials Science · Physics 2022-01-12 Takuya Yoshioka , Hiroki Tsuchiura , Pavel Novák

The Au25(SR)18- cluster is a new member in the superatom family which features a centered icosahedral shell (Au13) protected by six RS(AuSR)2 motifs (RS- being a alkylthiolate group). Here we show that this superatom can be magnetically…

Materials Science · Physics 2019-02-05 De-en Jiang , Robert L. Whetten

We used a solid-state reaction method to prepare Sn$_{1-x}$Ni$_x$O$_2$ with $x$ = 0, 0.05, 0.1, 0.15 polycrystalline compounds. A rutile phase with tetragonal crystal structure was confirmed by X-ray diffraction. At room temperature, the…

Applied Physics · Physics 2022-06-06 Y. S. Worku , V. V. Srinivasu , Dipti R. Sahu

An investigation of La and Ca doped Sr4Ru3O10, featuring a coexistence of interlayer ferromagnetism and intralayer metamagnetism, is presented. La doping readily changes magnetism between ferromagnetism and metamagnetism by tuning the…

Strongly Correlated Electrons · Physics 2009-11-11 S. Chikara , V. Durairaj , W. H. Song , Y. P. Sun , X. N. Lin , A. Douglass , G. Cao , P. Schlottmann

We theoretically investigate the possibility of establishing ferromagnetism in the topological insulator Bi2Se3 via magnetic doping of 3d transition metal elements. The formation energies, charge states, band structures, and magnetic…

Materials Science · Physics 2013-01-08 Jian-Min Zhang , Wenguang Zhu , Ying Zhang , Di Xiao , Yugui Yao

A heavy-mass electron state is realized in a doped valence bond solid (Ti1-xVx)2O3. In this system, itinerant holes mediate the mainly ferromagnetic RKKY interaction between the localized magnetic moments and become readily spin-polarized…

Strongly Correlated Electrons · Physics 2015-05-27 M. Uchida , Y. Onose , Y. Tokura

Magnetic and transport properties of Ge(1-x-y)Mn(x)Eu(y)Te crystals with chemical compositions 0.041 < x < 0.092 and 0.010 < y < 0.043 are studied. Ferromagnetic order is observed at 150 < T < 160 K. Aggregation of magnetic ions into…

Monodisperse magnetite Fe3O4 nanoparticles of controlled size within 6 and 20 nm in diameter were synthesized by thermal decomposition of an iron organic precursor in an organic medium. Particles were coated with oleic acid. For all samples…

Materials Science · Physics 2011-11-09 P. Guardia , B. Batlle-Brugal , A. G. Roca , Oscar Iglesias , M. P. Morales , C. J. Serna , A. Labarta , X. Batlle

Effects of magnetic fields (applied along the c-axis) on static spin correlation were studied for the electron-doped superconductors Pr$_{1-x}$LaCe$_{x}$CuO$_4$ with $x$=0.11 ($T_c$=26 K) and $x$=0.15 ($T_c$=16 K) by neutron scattering…

Superconductivity · Physics 2009-11-10 M. Fujita , M. Matsuda , S. Katano , K. Yamada

Among iron 122 pnictide superconductors, the EuFe$_2$As$_2$ series draws particular interest because, in addition to superconductivity or the long-range spin-density-wave order in the Fe subsystem, the localized Eu$^{2+}$ magnetic moments…

Superconductivity · Physics 2011-03-15 Sina Zapf , Dan Wu , Lapo Bogani , Hirale S. Jeevan , Philipp Gegenwart , Martin Dressel

The magnetization and electric polarization of a polar antiferromagnet Fe$_2$Mo$_3$O$_8$ are studied up to 66 T for spin-saturation magnetic fields applied along the polar axis. The magnetization process at 1.4 K exhibited multistep…