A heavy-mass electron state is realized in a doped valence bond solid (Ti1-xVx)2O3. In this system, itinerant holes mediate the mainly ferromagnetic RKKY interaction between the localized magnetic moments and become readily spin-polarized under a magnetic field, while showing large negative magnetoresistance. In spite of the ferromagnetic interaction among the carriers, their effective mass is found to be 1 or 2 orders of magnitude larger than that of usual doped semiconductors. Such strong mass renormalization is ascribable to the polaron formation on the Ti-dimer, where the spin-singlet state is originally formed. Doping dependence of the electronic specific-heat coefficient implies that the dimeric lattice fluctuation or softening is responsible for the enhanced electron-phonon interaction.
@article{arxiv.1102.4259,
title = {Large Magnetoresistance and Spin-Polarized Heavy-Mass Electron State in a Doped Valence Bond Solid (Ti1-xVx)2O3},
author = {M. Uchida and Y. Onose and Y. Tokura},
journal= {arXiv preprint arXiv:1102.4259},
year = {2015}
}