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The Raman spectrum of monolayer (ML) MoS$_2$ is remarkably affected by the interaction with metals. In this work we studied ML-MoS$_2$ supported by the Ag(111) and Ag(110) surfaces by using a combined experimental and theoretical approach.…

Molybdenum disulfide (MoS2) of single and few-layer thickness was exfoliated on SiO2/Si substrate and characterized by Raman spectroscopy. The number of S-Mo-S layers of the samples was independently determined by contact-mode atomic-force…

Materials Science · Physics 2010-11-16 Changgu Lee , Hugen Yan , Louis E. Brus , Tony F. Heinz , James Hone , Sunmin Ryu

Single- and few-layer MoS2 has recently gained attention as an interesting new material system for opto-electronics. Here, we report on scanning Raman measurements on few-layer MoS2 flakes prepared by exfoliation. We observe a Raman mode…

Materials Science · Physics 2012-09-19 G. Plechinger , S. Heydrich , J. Eroms , D. Weiss , Schüller , T. Korn

Intercalation offers a promising way to alter the physical properties of two-dimensional (2D) layered materials. Here we investigate the electronic and vibrational properties of 2D layered MoSe$_2$ intercalated with atomic manganese at…

Materials Science · Physics 2020-09-28 Shunda Chen , Virginia L. Johnson , Davide Donadio , Kristie J. Koski

We investigated interlayer phonon modes of mechanically exfoliated few-layer 2H-SnS2 samples by using room temperature low-frequency micro-Raman spectroscopy. Raman measurements were performed using laser wavelength of 441.6, 514.4, 532 and…

Materials Science · Physics 2018-07-16 Tharith Sriv , Kangwon Kim , Hyeonsik Cheong

We have investigated the vibrational properties of van der Waals heterostructures of monolayer transition metal dichalcogenides (TMDs), specifically MoS2/WSe2 and MoSe2/MoS2 heterobilayers as well as twisted MoS2 bilayers, by means of…

We review vibrational and electronic properties of single and a few layer MoS$_2$ relevant to understand their resonant and non-resonant Raman scattering results. In particular, the optical modes and low frequency shear and layer breathing…

Mesoscale and Nanoscale Physics · Physics 2015-02-13 Achintya Bera , A. K. Sood

Atomically thin MoS$_{2}$ crystals have been recognized as a quasi-2D semiconductor with remarkable physics properties. This letter reports our Raman scattering measurements on multilayer and monolayer MoS$_{2}$, especially in the…

Mesoscale and Nanoscale Physics · Physics 2015-06-11 Hualing Zeng , Bairen Zhu , Kai Liu , Jiahe Fan , Xiaodong Cui , Q. M. Zhang

Gold-mediated exfoliation of MoS2 has attracted considerable interest in the recent years. A strong interaction between MoS2 and Au facilitates preferential production of centimeter-sized monolayer MoS2 with near-unity yield and provides a…

When combined into van der Waals heterostructures, transition metal dichalcogenide monolayers enable the exploration of novel physics beyond their unique individual properties. However, for interesting phenomena such as interlayer charge…

The van der Waals coefficients and the separation dependent retardation functions of the interactions between the atomically thin films of the multi-layered transition metal molybdenum disulfide (MoS$_2$) dichalcogenides with the alkali…

Materials Science · Physics 2020-08-12 Shankar Dutt , Sukhjit Singh , A. Mahajan , Bindiya Arora , B. K. Sahoo

Two-dimensional (2D) layered materials have been extensively studied owing to their fascinating and technologically relevant properties. Their functionalities can be often tailored by the interlayer stacking pattern. Low-frequency (LF)…

Mesoscale and Nanoscale Physics · Physics 2017-10-06 Liangbo Liang , Alexander A. Puretzky , Bobby G. Sumpter , Vincent Meunier

Two-dimensional (2D) layered transition metal dichalcogenides (TMDs) have recently attracted tremendous interest as potential valleytronic and nano-electronic materials, in addition to being well-known as excellent lubricants in the bulk.…

Lattice structure and symmetry of two-dimensional (2D) layered materials are of key importance to their fundamental mechanical, thermal, electronic and optical properties. Raman spectroscopy, as a convenient and nondestructive tool, however…

Mesoscale and Nanoscale Physics · Physics 2015-08-28 Yanqing Feng , Wei Zhou , Yaojia Wang , Jian Zhou , Erfu Liu , Yajun Fu , Zhenhua Ni , Xinglong Wu , Hongtao Yuan , Feng Miao , Baigeng Wang , Xiangang Wan , Dingyu Xing

Twisted stacked few layer black phosphorus heterostructures were successfully fabricated in this work. Abnormal blue shifts in their Ag1 and Ag2 Raman peaks and unique optical reflections were observed in these samples. The phonon behavior…

Materials Science · Physics 2018-05-04 Tao Fang , Teren Liu , Zenan Jiang , Rui Yang , Peyman Servati , Guangrui , Xia

As a new two-dimensional layered material, black phosphorus (BP) is a promising material for nanoelectronics and nano-optoelectronics. We use Raman spectroscopy and first-principles theory to report our findings related to low-frequency…

Twisted van der Waals heterostructures unravel a new platform to study strongly correlated quantum phases. The interlayer coupling in these heterostructures is sensitive to twist angles ($\theta$) and key to controllably tune several exotic…

Materials Science · Physics 2019-12-03 Rahul Debnath , Indrajit Maity , Manish Jain , Arindam Ghosh

Stimulated low-frequency Raman scattering can give essential information about the elastic properties of different nanoparticles systems, in particular, biological nanostructures. In the present study, low-frequency vibrational modes in…

We explore the adsorption of MoS2 on a range of metal substrates by means of first-principles density functional theory calculations. Including van der Waals forces in the density functional is essential to capture the interaction between…

Materials Science · Physics 2016-02-03 M. Farmanbar , G. Brocks

Accessing the terahertz (THz) spectral domain through surface-enhanced Raman spectroscopy (SERS) is challenging and opens up the study of low-frequency molecular and electronic excitations. Compared to direct THz probing of heterogenous…

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