Twisted stacked few layer black phosphorus heterostructures were successfully fabricated in this work. Abnormal blue shifts in their Ag1 and Ag2 Raman peaks and unique optical reflections were observed in these samples. The phonon behavior difference can be explained by our density functional theory calculations, which suggest that interlayer coupling has a significant effect in twisted bilayer black phosphorus. According to the calculations, the interlayer interactions are not simply van der Waals interactions. Additional interactions, such as weak valence bonding between the top and bottom flakes, are considered to be the cause of the blue shifts in their Raman spectra.
@article{arxiv.1805.01135,
title = {Interlayer coupling effect in twisted stacked few layer black phosphorus revealed by abnormal blue shifts in Raman spectra},
author = {Tao Fang and Teren Liu and Zenan Jiang and Rui Yang and Peyman Servati and Guangrui and Xia},
journal= {arXiv preprint arXiv:1805.01135},
year = {2018}
}