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We have used a shell model to study the phonon dynamics of multiferroic manganites RMnO3 (R= Tb, Dy, Ho). The calculated phonon dynamical properties, crystal structure, Raman frequencies and specific heat are found to be in good agreement…

Materials Science · Physics 2010-04-06 Renu Choithrani , Mala N. Rao , S. L. Chaplot , N. K. Gaur , R. K. Singh

A series of Pb-free ferroelectric materials Ba0.9Sr0.1Ti1-xSnxO3 (BSTS-x) with 0 < x < 0.15 was successfully prepared via solid-state reaction method. The effect of Sn substitution on the crystal structure, microstructure, dielectric…

ABO3 oxides with the perovskite-related structures are attracting significant interest due to their promising physical and chemical properties for many applications requiring tunable chemistry, including fuel cells, catalysis, and…

Materials Science · Physics 2021-07-13 Su Jeong Heo , Andriy Zakutayev

The symmetry was examined using neutron diffraction method on Pb(Zn1/3Nb2/3)O3 -9%PbTiO3 (PZN/9PT) which has a composition at the morphotropic phase boundary (MPB) between Pb(Zn1/3Nb2/3)O3 and PbTiO3. The results were compared with those of…

Information about the crystal structures in the range of morphotropic phase boundary of ferroelectric perovskite solid solutions is important for understanding their intricate properties which result in wide opportunities for practical…

Materials Science · Physics 2025-11-04 Alexei A. Bokov , Haiyan Guo , Zuo-Guang Ye

Multiferroic composites with the composition (1-x) BaTi0.8Sn0.2O3 - (x) La0.5Ca0.5MnO3 (x =0, 0.3, 0.5, 0.7, 0.9 and 1) were prepared by sol-gel techniques. Rietveld refinements of the composites with 0-3 and 3-0 type connectivities exhibit…

In this paper, we reported the preparation of YFe$_{0.5}$Cr$_{0.5}$O$_3$ by the sol-gel method and studied its structure and M\"ossbauer spectrum at variable temperatures. X-ray diffraction(XRD) analysis exhibits that the sample has the…

Materials Science · Physics 2022-08-09 Jingzhi Liu , Kai Wang , Lebin Liu , Jiajun Mo , Shiyu Xu , Haiqi Yang , Min Liu

We report on near normal far- and mid-infrared emission and reflectivity of NdMnO3 perovskite from room temperature to sample decomposition above 1800 K. At 300 K the number infrared active phonons is in close agreement with the 25…

The ground-state structural and electronic properties of ferroelectric BiFeO$_3$ are calculated using density functional theory within the local spin-density approximation and the LSDA+U method. The crystal structure is computed to be…

Materials Science · Physics 2007-05-23 J. B. Neaton , C. Ederer , U. V. Waghmare , N. A. Spaldin , K. M. Rabe

The (H,T)-phase diagram of the multiferroic perovskite TbMnO$_3$ was studied by high-resolution thermal expansion $\alpha(T)$ and magnetostriction $\Delta L(H)/L$ measurements. Below $T_{N}\simeq 42$ K, TbMnO$_3$ shows antiferromagnetic…

Strongly Correlated Electrons · Physics 2009-11-13 D. Meier , N. Aliouane , D. N. Argyriou , J. A. Mydosh , T. Lorenz

The complex perovskite Ba2CoTeO6 (BCTO) has been synthesised, and the crystal structure and magnetic properties have been investigated using a combination of X-ray and neutron powder diffraction, electron microscopy and dielectric,…

Materials Science · Physics 2010-12-01 S. A. Ivanov , P. Nordblad , R. Mathieu , R. Tellgren , C. Ritter

Sr_(9-x)PbxCe2Ti12O36 system is derived from the perovskite SrTiO3 and its chemical formula can be written as (Sr_(1-y)Pby)0.75Ce0.167TiO3. We investigated dielectric response of Sr_(9-x)PbxCe2Ti12O36 ceramics (x = 0-9) between 100 Hz and…

Up to now the crystallographic structure of the magnetoelectric perovskite EuTiO3 was considered to remain cubic down to low temperature. Here we present high resolution synchrotron X-ray powder diffraction data showing the existence of a…

We discuss relative roles played by the magnetic inversion symmetry breaking and the ferroelectric (FE) atomic displacements in the multiferroic state of YMnO3. For these purposes we derive a realistic low-energy model, using results of…

Materials Science · Physics 2012-10-12 I. V. Solovyev , M. V. Valentyuk , V. V. Mazurenko

The structure of dielectric perovskite BaZrO$_3$, long known to be cubic at room temperature without any structural phase transition with variation of temperature, has been recently disputed to have different ground state structures with…

Materials Science · Physics 2022-06-29 Dong-Hyeon Gim , Yeahan Sur , Yoon Han Lee , Jeong Hyuk Lee , Soonjae Moon , Yoon Seok Oh , Kee Hoon Kim

The phase purity and the lattice dynamics in bulk EuTiO3 were investigated both microscopically, using X-ray and neutron diffraction, 151-Eu-M\"ossbauer spectroscopy, and 151-Eu nuclear inelastic scattering, and macroscopically using…

Strongly Correlated Electrons · Physics 2013-10-30 D. Bessas , K. Z. Rushchanskii , M. Kachlik , S. Disch , O. Gourdon , J. Bednarcik , K. Maca , I. Sergueev , S. Kamba , M. Ležaíc , R. P. Hermann

Thin films of (1-x)BiFeO<sub>3</sub>-xPbTiO<sub>3</sub> (BF-xPT) with x ~ 0.60 were fabricated on Pt/Si substrates by chemical solution deposition of precursor BF and PT layers alternately in three different multilayer configurations. These…

The interaction of coexisting structural instabilities in multiferroic materials gives rise to intriguing coupling phenomena and extraordinarily rich phase diagrams, both in bulk materials and strained thin films. Here we investigate the…

The low-energy part of the vibration spectrum in KNbO$_3$ was studied by cold neutron inelastic scattering in the cubic phase. In addition to acoustic phonons, we observe strong diffuse scattering, which consists of two components. The…

Materials Science · Physics 2007-05-23 S. N. Gvasaliya , B. Roessli , R. A. Cowley , S. G. Lushnikov , A. Choubey , P. Gunter

Perovskite oxides hetero-structures are host to a large number of interesting phenomena such as ferroelectricity and 2D-superconductivity. Ferroelectric perovskite oxides have been of significant interest due to their possible use in…