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We study the electrical behavior of multiferroic BiFeO$_3$ by means of first-principles calculations. We do so by constraining a specific component of the electric displacement field along a variety of structural paths, and by monitoring…

Materials Science · Physics 2016-01-20 Massimiliano Stengel , Jorge Íñiguez

The Ba0.85Ca0.15Zr0.1Ti0.9O3 (BCZT) ceramics were successfully prepared by sol-gel process, and sintered at 1420 degree. The effect of sintering times (2, 4 and 6 h) on structural, microstructural, electric properties, energy storage, and…

Materials Science · Physics 2021-02-03 H. Mezzourh , S. Belkhadir , D. Mezzane , M. Amjoud , E. Choukri , A. Lahmar , Y. Gagou , Z. Kutnjak , M. El Marssi

In this work we present a detailed study of the structural and lattice dynamic properties of Y-doped EuMnO3 ceramics (Eu1-xYxMnO3, with 0<x<0.55). A thorough analysis towards the correlation between both structural and Raman modes…

Magnetically-driven ferroelectric atomic displacements of the order of 10$^{-3} Angstrom have been observed in orthorhombic (perovskite like) YMnO$_3$ by a single-crystal synchrotron x-ray diffraction. The refined polar structure shows the…

Strongly Correlated Electrons · Physics 2011-08-12 D. Okuyama , S. Ishiwata , Y. Takahashi , K. Yamauchi , S. Picozzi , K. Sugimoto , H. Sakai , M. Takata , R. Shimano , Y. Taguchi , T. Arima , Y. Tokura

We have investigated the temperature-dependent Raman-active phonons and the magnetic properties of Gd(Co1/2Mn1/2)O3 perovskite ceramics in the temperature range from 40 K to 300 K. The samples crystallized in an orthorhombic distorted…

Materials Science · Physics 2015-06-17 R. X. Silva , H. Reichlova , X. Marti , D. A. B. Barbosa , M. W. Lufaso , A. P. Ayala , C. W. A. Paschoal

This work reports an experimental investigation of the magneto-elastic coupling and polarization character of magnetic phases of the orthorhombic Eu1-xYxMnO3 system at low temperatures. The temperature dependence of the polarization…

Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$ is one of the simplest representatives of the class of lead relaxors and often serves as a model system for more complicated compounds. In this paper we analyse both polarized and depolarized Raman scattering…

Materials Science · Physics 2009-11-10 Oleksiy Svitelskiy , Jean Toulouse , Z. -G. Ye

Ferroelectric materials embedded with dielectric inclusions offer a unique platform for exploring novel topological polar textures. Using first-principles-based atomistic simulations, we investigate the polarization behavior of a BaTiO$_3$…

Materials Science · Physics 2026-03-12 R. Machado , F. Di Rino , M. Sepliarsky , M. G. Stachiotti

High-temperature phase behavior in the system LixNa1-xNbO3 has been studied by using high-resolution powder neutron diffraction. Each of the three compositions studied in the Na-rich part of the phase diagram (x = 0.03, 0.08 and 0.12) shows…

Materials Science · Physics 2018-06-27 Charlotte Dixon , Philip Lightfoot

Multiferroic BiFeO3 (BFO) / La0.7Sr0.3MnO3 heterostructured thin films were grown by pulsed laser deposition on polished spark plasma sintered LaAlO3 (LAO) polycrystalline substrates. Both polycrystalline LAO substrates and BFO films were…

Materials Science · Physics 2014-03-03 D. Pravarthana , M. Trassin , Jiun Haw Chu , M. Lacotte , A. David , R. Ramesh , P. A. Salvador , W. Prellier

Ferroelectric ceramics (Ba0.85Ca0.15)(Ti0.9Zr0.1-xSnx)O3 (x=0.00, 0.02, 0.04, 0.06) were prepared by a sol-gel method. Structural investigation revealed the co-existence of tetragonal (P4mm) and orthorhombic (Pmm2) symmetries at room…

In this study, we determined the different physical characteristics of nanoscale layered mixed Fe-Co layers of orthoferrite SmFe0.5Co0.5O3 based on magnetic and dielectric measurements.Magnetization analyzes showed that the system was…

Materials Science · Physics 2018-12-27 Ashish Shukla , Akash Singh , Md. Motin Seikh , Asish K Kundu

We have investigated the effects of substituting In for Mn on the antiferromagnetic phase transition in YMnO3 using magnetic, dielectric, and specific heat measurements. We prepared a set of isostructural phase pure hexagonal…

Materials Science · Physics 2015-05-14 A. Dixit , Andrew E. Smith , M. A. Subramanian , G. Lawes

From an experimental point of view, room temperature ferroelectricity in BiFeO3 is raising many questions. Electric measurements made a long time ago on solid-solutions of BiFeO3 with Pb(Ti,Zr)O3 indicate that a spontaneous electric…

Simultaneous occurrence of big ferroelectricity and strong ferromagnetism has been observed in Barium Hexaferrite ceramics. Barium hexaferrite (BaFe12O19) powders with hexagonal crystal structure have been successfully synthesized by…

Materials Science · Physics 2012-01-20 Xiuna Chen , Guolong Tan

Noncollinear spin systems with magnetically induced ferroelectricity from changes in spiral magnetic ordering have attracted significant interest in recent research due to their remarkable magnetoelectric effects with promising…

Materials Science · Physics 2024-02-14 P. Hernández-Gómez , D. Martín-González , C. Torres , J. M. Muñoz

Samarium substituted bismuth ferrite (BiFeO3) ceramics prepared by sol-gel synthesis method were studied using both local scale and microscopic measurement techniques in order to clarify an evolution of the crystal structure of the…

In bismuth ferrite (BiFeO3), antiferromagnetic and ferroelectric order coexist at room temperature, making it of particular interest for studying magnetoelectric coupling. The mutual control of magnetic and electric properties is very…

Materials Science · Physics 2012-07-23 C. Beekman , A. A. Reijnders , Y. S. Oh , S. W. Cheong , K. S. Burch

We present a study based on several advanced First-Principles methods, of the recently synthesized PbNiO3 [J. Am. Chem. Soc 133, 16920 (2011)], a rhombohedral antiferromagnetic insulator which crystallizes in the highly distorted R3c…

Strongly Correlated Electrons · Physics 2015-06-05 X. F. Hao , A. Stroppa , S. Picozzi , A. Filippetti , C. Franchini

For disordered Heisenberg systems with small single ion anisotropy, two spin glass transitions below the long range ordered phase transition temperature has been predicted theoretically for compositions close to the percolation threshold.…

Materials Science · Physics 2018-03-13 Arun Kumar , S. D. Kaushik , V. Siruguri , Dhananjai Pandey